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Towards stable nick...
Towards stable nickel catalysts for selective hydrogenation of biomass-based BHMF into THFDM
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- Achour, Abdenour, 1980 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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Ojagh, Houman, 1976 (author)
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- Ho, Hoang Phuoc, 1983 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Creaser, Derek, 1966 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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Pajalic, Oleg, 1964 (author)
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Holmberg, Johan (author)
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- Olsson, Louise, 1974 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- Elsevier BV, 2023
- 2023
- English.
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In: Journal of Environmental Chemical Engineering. - : Elsevier BV. - 2213-3437 .- 2213-2929. ; 11:2
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https://doi.org/10.1...
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Abstract
Subject headings
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- Selective transformation of BHMF (2,5-bis(hydroxymethyl)furan) to THFDM (tetrahydrofuran-2,5-dimethanol) over a variety of structured Ni/Sx-Z1−x catalysts was investigated. The effects of support, Ni loading, solvent, temperature, pressure, and particle size on the conversion and selectivity were studied. Among them, the 10 wt% Ni catalyst supported on the SiO2:ZrO2 weight ratio of 90:10 (10NiS90Z10) exhibits the best performance in terms of BHMF conversion and THFDM selectivity. Its good performance was attributed to its well-balanced properties, that depend upon the ZrO2 content of the support in combination with SiO2, the active Ni sites-support interaction, and acidity/basicity ratio of each catalyst resulting in different Ni dispersions. Importantly, the 10NiS90Z10 catalyst showed a stable selectivity to THFDM (>94%), with 99.4% conversion of BHMF during 2 h reaction time. Poor catalytic activity resulted from excessive ZrO2 content (>10 wt%). The structural, textural, and acidity properties of NiSi100−y-Zry catalysts, tuned by selectively varying the Ni amount from 5 to 15 wt%, were critically investigated using numerous material characterization techniques. Catalyst recycling experiments revealed that the catalyst could be recycled several times without any measurable loss of catalytic activity.
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Kemiska processer (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Chemical Process Engineering (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Annan kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Other Chemical Engineering (hsv//eng)
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Keyword
- Hydrogenation
- Biomass
- THFDM
- SiO -ZrO composite 2 2
- Ni
- BHMF
Publication and Content Type
- art (subject category)
- ref (subject category)
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Achour, Abdenour ...
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Ojagh, Houman, 1 ...
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Ho, Hoang Phuoc, ...
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Creaser, Derek, ...
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Pajalic, Oleg, 1 ...
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Holmberg, Johan
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show more...
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Olsson, Louise, ...
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- ENGINEERING AND TECHNOLOGY
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ENGINEERING AND ...
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and Chemical Enginee ...
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and Chemical Process ...
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- ENGINEERING AND TECHNOLOGY
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ENGINEERING AND ...
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and Chemical Enginee ...
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and Other Chemical E ...
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Organic Chemistr ...
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Chalmers University of Technology