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  • Pal, S. K.Lunds universitet,Lund University,Bowling Green State University,Chemical Physics, Lund University (author)

Geminate Charge Recombination in Polymer/Fullerene Bulk Heterojunction Films and Implications for Solar Cell Function

  • Article/chapterEnglish2010

Publisher, publication year, extent ...

  • 2010-08-12
  • American Chemical Society (ACS),2010

Numbers

  • LIBRIS-ID:oai:research.chalmers.se:d55ecab9-2b81-4783-abf6-3c8ac4c61436
  • https://research.chalmers.se/publication/126586URI
  • https://doi.org/10.1021/ja104786xDOI
  • https://lup.lub.lu.se/record/1665316URI
  • https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-59066URI

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  • Language:English
  • Summary in:English

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  • Subject category:art swepub-publicationtype
  • Subject category:ref swepub-contenttype

Notes

  • We have studied the influence of three different fullerene derivatives on the charge generation and recombination dynamics of polymer/fullerene bulk heterojunction (BHJ) solar cell blends. Charge generation in APFO3/[70]PCBM and APFO3/[60]PCBM is very similar and somewhat slower than charge generation in APFO3/[70]BTPF. This difference qualitatively matches the trend in free energy change of electron transfer estimated from the LUMO energies of the polymer and fullerene derivatives. The first order (geminate) charge recombination rate is significantly different for the three fullerene derivatives studied and increases in the order APFO3/[70]PCBM

Subject headings and genre

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  • Kesti, T.Oulun Yliopisto,University of Oulu,University of Oulu, Finland (author)
  • Maiti, ManisankarLund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH,Chemical Physics, Lund University(Swepub:lu)chem-mrm (author)
  • Zhang, FenglingLinköpings universitet,Biomolekylär och Organisk Elektronik,Tekniska högskolan(Swepub:liu)fenzh60 (author)
  • Inganäs, OlleLinköpings universitet,Biomolekylär och Organisk Elektronik,Tekniska högskolan(Swepub:liu)ollin59 (author)
  • Hellström, Stefan,1978Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)k98hest (author)
  • Andersson, Mats,1966Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)matsand (author)
  • Oswald, F.Universidad de Castilla, La Mancha,University of Castilla, La Mancha,Universidad de Castilla-La Mancha (author)
  • Langa, F.Universidad de Castilla, La Mancha,University of Castilla, La Mancha,Universidad de Castilla-La Mancha (author)
  • Österman, TomasLund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH,Chemical Physics, Lund University:(Swepub:lu)chem-toe (author)
  • Pascher, TorbjörnLund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH,Chemical Physics, Lund University(Swepub:lu)chph-tpa (author)
  • Yartsev, ArkadyLund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH,Chemical Physics, Lund University(Swepub:lu)chph-ay (author)
  • Sundström, VillyLund University,Lunds universitet,Kemisk fysik,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Chemical Physics,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH,Chemical Physics, Lund University(Swepub:lu)chph-vs (author)
  • Lunds universitetBowling Green State University (creator_code:org_t)

Related titles

  • In:Journal of the American Chemical Society: American Chemical Society (ACS)132:35, s. 12440-124511520-51260002-7863

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