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Multi-component sel...
Multi-component self-assembly of molecule based materials by coordination networks and weak intermolecular synthons
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Ghazzali, Mohamed I D M, 1974 (author)
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- Langer, Vratislav, 1949 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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Larsson, Krister (author)
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- Öhrström, Lars, 1963 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- Royal Society of Chemistry (RSC), 2011
- 2011
- English.
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In: CrystEngComm. - : Royal Society of Chemistry (RSC). - 1466-8033. ; 13:19, s. 5813-5817
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Abstract
Subject headings
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- The coordination polymer [Fe(SCN)2(1,2-bis(4-pyridylmethylene)hydrazine)2]n [Fe(phenanthroline)3]2n(ClO4)2n·n1,2-bis(4-pyridylmethylene)hydrazine·4nH2O 1 was crystallised from a MeOH/MeCN solution and the structure consists of layered (4,4) 2D-nets with supramolecular ([Fe(phen)3]2bphz)4+ units in the pores and disordered water and perchlorate anions. The same supramolecular motif could be independently prepared as [Fe(phen)3]2·bphz(ClO4)4·xMeOH 2, and the [Ru(phenanthroline)3]2+ compound 3, isostructural to 1, was also prepared although a complete structure determination was prevented by low crystal quality. Compounds 1 and 3 are rare examples of how several large and different components can be assembled inside a 2D coordination network and provide a concept for multi-component self-assembly.
Subject headings
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Annan kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Other Chemistry Topics (hsv//eng)
Keyword
- X-ray diffraction
- crystal structure
- framework system
- MOF
Publication and Content Type
- art (subject category)
- ref (subject category)
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