Enhancing the bioactivity of zirconia and zirconia composites by surface modification

• Among bioceramics, zirconia (ZrO2) and alumina (Al2O3) possess exceptional mechanical properties suitable for load-bearing and wear-resistant applications but the poor bioactivity of these materials is the major concern when bonding and integration to the living bone are desired. This article investigates two different approaches and their underlying mechanisms to improve the bioactivity of zirconia (3Y-TZP) and a zirconia composite with alumina (10Ce-TZP/Al2O3). Chemical treatment approach applied on 3Y-TZP where the substrates were soaked in 5M H3PO4 to create chemically functional groups on the surface for inducing apatite nucleation. X-ray photoelectron spectroscopy (XPS) was used to detect chemical changes and X-ray diffraction (XRD) to monitor phase changes on the surface before and after acid treatment. Alternate soaking approach applied on 10Ce-TZP/Al2O3 consisted of soaking the composite substrates in CaCl2 and Na2HPO4 solutions alternately to make a precursor for apatite formation. The bioactivity was evaluated by apatite-forming ability of surface-treated materials in simulated body fluid (SBF). Both methods resulted in the formation of hydroxyapatite on the surface of materials; however, alternate soaking approach showed to be a simpler, faster, and more effective method than the chemical treatment approach for enhancing the bioactivity of zirconia materials.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Materialteknik (hsv//swe)

ENGINEERING AND TECHNOLOGY  -- Materials Engineering (hsv//eng)

NATURVETENSKAP  -- Fysik (hsv//swe)

NATURAL SCIENCES  -- Physical Sciences (hsv//eng)

Keyword

soaking

apatite-forming ability

surface modification

alumina

alternate

y-tzp

simulated

organic polymers

in-vitro

alternate soaking process

zirconia

hydroxyapatite

bioactivity

coated implants

body-fluid

aging

ceramics

biomimetic process

Publication and Content Type

art (subject category)

ref (subject category)