onr:"swepub:oai:research.chalmers.se:e53ca43a-a69c-4733-ae87-b458938dfd0c"
Search: onr:"swepub:oai:research.chalmers.se:e53ca43a-a69c-4733-ae87-b458938dfd0c" > Cyanohydrins from m...
- 1 of 1
- Previous record
- Next record
- To hitlist
Cyanohydrins from methyl 6-deoxy-2,3-O-isopropylidene-alpha-L-lyxo-hexofuranosid-4-ulose via Bucherer-Bergs and Strecker reactions
-
- Steiner, Bohumil (author)
- Slovak Academy of Sciences
-
- Langer, Vratislav, 1949 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
-
- Bella, M. (author)
- Slovak Academy of Sciences
- show more...
- show less...
- (creator_code:org_t)
- Elsevier BV, 2013
- 2013
- English.
- In: Carbohydrate Research. - : Elsevier BV. - 0008-6215 .- 1873-426X. ; 369, s. 31-37
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- The formation of methyl 4-cyano-6-deoxy-2,3-O-isopropylidene-alpha-L-talopyranoside (3), methyl 4-cyano-6-deoxy-2,3-O-isopropylidene-alpha-L-mannopyranoside (4), methyl 4-cyano-6-deoxy-2,3-O-isopropylidene-beta-D-allopyranoside (5), and methyl 4-cyano-6-deoxy-2,3-O-isopropylidene-beta-D-gulopyranoside (7) from methyl 6-deoxy-2,3-O-isopropylidene-alpha-L-lyxo-hexopyranosid-4-ulose (1) under Strecker amino nitrile synthesis and Bucherer-Bergs hydantoin synthesis reaction conditions, respectively, is reported. Their structures were determined on the basis of NMR and mass spectral data. The configurations of free cyanohydrins 3 and 4 and 4-O-acetylated cyanohydrins 6 and 8 (obtained by acetylation of 5 and 7, respectively) were established by single-crystal X-ray analysis. The conformations of the six-membered pyranose ring and five-membered 1,3-dioxolane ring in compounds 3, 4, 6, and 8 are also reported.
Subject headings
- NATURVETENSKAP -- Biologi -- Biokemi och molekylärbiologi (hsv//swe)
- NATURAL SCIENCES -- Biological Sciences -- Biochemistry and Molecular Biology (hsv//eng)
Keyword
- crystal
- molecular-structure
- derivatives
- conformation
- Bucherer-Bergs hydantoin synthesis
- Cyanohydrins
- sugar amino-acids
- Kiliani
- biology
- Strecker synthesis
- Carbohydrates
- lewis-acid
Publication and Content Type
- art (subject category)
- ref (subject category)
Find in a library
- Carbohydrate Research (Search for host publication in LIBRIS)
To the university's database
- 1 of 1
- Previous record
- Next record
- To hitlist
Find more in SwePub
- By the author/editor
- Steiner, Bohumil
- Langer, Vratisla ...
- Bella, M.
- Koos, Miroslav
- About the subject
-
- NATURAL SCIENCES
- NATURAL SCIENCES
- and Biological Scien ...
- and Biochemistry and ...
- Articles in the publication
- Carbohydrate Res ...
- By the university
- Chalmers University of Technology
Search outside SwePub
- Extend your search to:
- Google Book Search
- Google Scholar
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
- Copyright © LIBRIS - National Library Systems
- LIBRIS.kb.se
