Search: onr:"swepub:oai:research.chalmers.se:fd5b7463-37d2-42f9-b158-33b98b3d535a" > Near-Infrared Lumin...
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000 | 04401naa a2200577 4500 | |
001 | oai:research.chalmers.se:fd5b7463-37d2-42f9-b158-33b98b3d535a | |
003 | SwePub | |
008 | 200430s2020 | |||||||||||000 ||eng| | |
024 | 7 | a https://research.chalmers.se/publication/5161602 URI |
024 | 7 | a https://doi.org/10.21577/0103-5053.201902332 DOI |
024 | 7 | a https://research.chalmers.se/publication/5166942 URI |
024 | 7 | a https://research.chalmers.se/publication/5161672 URI |
040 | a (SwePub)cth | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a art2 swepub-publicationtype |
072 | 7 | a ref2 swepub-contenttype |
100 | 1 | a Sábio, Rafael M.u Universidade Estadual Paulista (UNESP),São Paulo State University (UNESP)4 aut |
245 | 1 0 | a Near-Infrared Luminescence from Visible-Light-Sensitized Ruthenium(II)-Neodymium(III) Heterobimetallic Bridged Complexes Containing Alkoxy(silyl) Functional Groups |
264 | c 2020 | |
264 | 1 | b Sociedade Brasileira de Quimica (SBQ),c 2020 |
338 | a electronic2 rdacarrier | |
520 | a New infrared emitting d-f (ruthenium(II)–neodymium(III)) heterobimetallic complexes with alkoxy(silyl) functional groups have been prepared. Visible excitation evidenced energy transfer processes from the ruthenium(II) donor to neodymium(III) acceptors leading to infrared emission. Energy transfer rates (kEnT) and efficiency of energy transfer (ηEnT) are, respectively, 0.61 × 107 s-1 and 44% for RuL1–NdL3 complex. Larger values of kEnT (3.04 × 107 s-1) and ηEnT (84%) were detected for RuL2–NdL4 complex. RuL1–NdL3 and RuL2–NdL4 complexes were fully characterized by elementary analysis (EA), mass spectrometry (MS), Fourier transform infrared spectroscopy (FTIR) and Fourier transform Raman spectroscopy (FT-Raman). Total correlation spectroscopy (TOCSY1D), 1H{13C} heteronuclear single quantum correlation (HSQC) and 1H{13C} heteronuclear multiple bond correlation (HMBC) nuclear magnetic resonance (NMR) analyses were also carried out to characterize NdL3 and RuL1–NdL3 complexes. The presence of trialkoxysilyl-substituted ligands would allow further grafting onto any silica or silicated surface aiming at applications as new luminescent near infrared (NIR)-emitting biosensors or biomarkers. | |
650 | 7 | a NATURVETENSKAPx Fysikx Atom- och molekylfysik och optik0 (SwePub)103022 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Physical Sciencesx Atom and Molecular Physics and Optics0 (SwePub)103022 hsv//eng |
650 | 7 | a NATURVETENSKAPx Fysikx Annan fysik0 (SwePub)103992 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Physical Sciencesx Other Physics Topics0 (SwePub)103992 hsv//eng |
650 | 7 | a NATURVETENSKAPx Kemix Organisk kemi0 (SwePub)104052 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Organic Chemistry0 (SwePub)104052 hsv//eng |
653 | a D-f energy transfer | |
653 | a Neodymium(III) | |
653 | a Ruthenium(II) | |
653 | a Grafting trialkoxysilyl group | |
653 | a NIR luminescent complexes | |
653 | a Silylated heterobimetallic complexes | |
653 | a Visible | |
700 | 1 | a Santagneli, Silvia H.u Universidade Estadual Paulista (UNESP),São Paulo State University (UNESP)4 aut |
700 | 1 | a Gressier, Marie4 aut |
700 | 1 | a Caiut, José M.A.u Universidade de Sao Paulo (USP),University of Sao Paulo (USP)4 aut |
700 | 1 | a Pazin, Wallance M.u Universidade de Sao Paulo (USP),University of Sao Paulo (USP)4 aut |
700 | 1 | a Rosa Da Silva, Robson,d 1988u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)rosa |
700 | 1 | a Ribeiro, Sidney J.L.u Universidade Estadual Paulista (UNESP),São Paulo State University (UNESP)4 aut |
700 | 1 | a Menu, Marie Joëlle4 aut |
710 | 2 | a Universidade Estadual Paulista (UNESP)b Universidade de Sao Paulo (USP)4 org |
773 | 0 | t Journal of the Brazilian Chemical Societyd : Sociedade Brasileira de Quimica (SBQ)g 31:4, s. 694-702q 31:4<694-702x 0103-5053x 1678-4790 |
856 | 4 | u https://research.chalmers.se/publication/516694/file/516694_Fulltext.pdfx primaryx freey FULLTEXT |
856 | 4 | u https://doi.org/10.21577/0103-5053.20190233 |
856 | 4 8 | u https://research.chalmers.se/publication/516160 |
856 | 4 8 | u https://doi.org/10.21577/0103-5053.20190233 |
856 | 4 8 | u https://research.chalmers.se/publication/516694 |
856 | 4 8 | u https://research.chalmers.se/publication/516167 |
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