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Catalysed low tempe...
Catalysed low temperature H-2 release from nitrogen heterocycles
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Moores, Audrey (författare)
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Poyatos, Macarena (författare)
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- Luo, Yi (författare)
- KTH,Teoretisk kemi
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Crabtree, Robert H. (författare)
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(creator_code:org_t)
- Royal Society of Chemistry (RSC), 2006
- 2006
- Engelska.
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Ingår i: New Journal of Chemistry. - : Royal Society of Chemistry (RSC). - 1144-0546 .- 1369-9261. ; 30:11, s. 1675-1678
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- In an experimental and computational study, nitrogen- and oxygen-containing heterocycles were compared with carbocycles as liquid substrates for hydrogen release with heterogeneous catalysts. Heteroatom substitution, particularly by nitrogen, favours low temperature H-2 release; indoline was fully dehydrogenated in less than 30 min with Pd/C at 110 degrees C.
Nyckelord
- molecular-orbital methods
- noble-metal catalysts
- carbon nanotubes
- dehydrogenation
- hydrogen
- storage
- complexes
- evolution
- energies
- alcohols
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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