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Formation of enviro...
Formation of environmentally relevant brominated dioxins from 2,4,6-tribromophenol via bromoperoxidase-catalyzed dimerisation
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- Arnoldsson, Kristina, 1961- (författare)
- Umeå universitet,Kemiska institutionen,Environmental analytical chemistry using hyphenated and bioanalytical techniques
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- Andersson, Patrik (författare)
- Umeå universitet,Kemiska institutionen
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- Haglund, Peter (författare)
- Umeå universitet,Kemiska institutionen,Environmental analytical chemistry using hyphenated and bioanalytical techniques
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(creator_code:org_t)
- Engelska.
- Relaterad länk:
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https://urn.kb.se/re...
Abstract
Ämnesord
Stäng
- Polybrominated dibenzo-p-dioxins (PBDD) are emerging environmental pollutants with structural similarities to the highly characterized toxicants polychlorinated dibenzo-p-dioxins. The geographical and temporal variations of PBDD in biota samples from the Baltic Sea do not display features that are normally related to anthropogenic sources, and therefore the natural formation of PBDDs has been suggested. This study of the bromoperoxidase mediated oxidative coupling of 2,4,6-tribromophenol (an abundant substance that is naturally formed in marine systems) identified the formation of ppb-level yields of 1,3,6,8-tetrabromodibenzo-p-dioxin (1,3,6,8-TeBDD) through direct condensation. Additional TeBDDs (1,3,7,9-TeBDD, 1,2,4,7-TeBDD and/or 1,2,4,8-TeBDD) and tri-BDDs (1,3,7-TrBDD and 1,3,8-TrBDD) were frequently formed, but at lower yields. The formation of these TeBDDs probably proceeds via bromine shifts or Smiles rearrangements, while the TrBDDs may result from subsequent debromination processes. Since all of the congeners formed by oxidative coupling and subsequent reactions are also found in Baltic Sea biota, the results support the theory that PBDDs are formed from natural precursors.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- bromoperoxidase
- enzymatic coupling
- 2
- 4
- 6-tribromophenol
- polybrominated dibenzo-p-dioxins
- oxidative coupling
- Baltic Sea
- analytisk kemi
- Analytical Chemistry
Publikations- och innehållstyp
- vet (ämneskategori)
- ovr (ämneskategori)