Sökning: onr:"swepub:oai:DiVA.org:uu-239773" >
Porosity Blocking i...
-
Lacey, Matthew J.Uppsala universitet,Strukturkemi
(författare)
Porosity Blocking in Highly Porous Carbon Black by PVdF Binder and Its Implications for the Li-S System
- Artikel/kapitelEngelska2014
Förlag, utgivningsår, omfång ...
-
2014-10-30
-
American Chemical Society (ACS),2014
-
printrdacarrier
Nummerbeteckningar
-
LIBRIS-ID:oai:DiVA.org:uu-239773
-
https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-239773URI
-
https://doi.org/10.1021/jp508137mDOI
Kompletterande språkuppgifter
-
Språk:engelska
-
Sammanfattning på:engelska
Ingår i deldatabas
Klassifikation
-
Ämneskategori:ref swepub-contenttype
-
Ämneskategori:art swepub-publicationtype
Anmärkningar
-
In this work, the influence of cathode binders on the porosity of composite electrodes for lithiumsulfur (LiS) batteries employing high surface area carbon blacks has been closely scrutinized. This has been accomplished by comparison of PVdF with the related copolymer, PVdF-HFP. Analysis of carbon black porosity after addition of binder in NMP solution reveals that PVdF(-HFP) fills pores of almost any size in carbon black, which can effect a severe reduction in pore volume and surface area accessible to the electrolyte in a LiS cell. Noting the different swelling behavior of both binders, the implications of pore filling by the binder on the electrochemistry of LiS cells can be determined. Because of the low swellability of PVdF in dimethoxyethane:dioxolane (DME:DOL)-based electrolytes, access of the electrolyte to the carbon surface area and pore volume is restricted, with potentially severe detrimental effects on the available capacity of the cell. Furthermore, this effect is still clearly significant for common binder loadings and with preinfiltration of sulfur; this study is therefore a clear demonstration that PVdF is an unsuitable choice of binder for the lithiumsulfur system and that alternatives must be considered.
Ämnesord och genrebeteckningar
Biuppslag (personer, institutioner, konferenser, titlar ...)
-
Jeschull, FabianUppsala universitet,Strukturkemi(Swepub:uu)fabje686
(författare)
-
Edström, Kristina,1958-Uppsala universitet,Strukturkemi(Swepub:uu)ked02526
(författare)
-
Brandell, DanielUppsala universitet,Strukturkemi(Swepub:uu)dbr10334
(författare)
-
Uppsala universitetStrukturkemi
(creator_code:org_t)
Sammanhörande titlar
-
Ingår i:The Journal of Physical Chemistry C: American Chemical Society (ACS)118:45, s. 25890-258981932-74471932-7455
Internetlänk
Hitta via bibliotek
Till lärosätets databas