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NMR spectroscopic i...
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Alsoghier, H. M.South Valley Univ, Fac Sci, Chem Dept, Qena 83523, Egypt.;Univ Lisbon, Ctr Quim Estrutural, Inst Super Tecn, Av Rovisco Pais 1, P-1049001 Lisbon, Portugal.
(författare)
NMR spectroscopic investigation of benzothiazolylacetonitrile azo dyes : CR7 substitution effect and semiempirical study
- Artikel/kapitelEngelska2021
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Elsevier,2021
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LIBRIS-ID:oai:DiVA.org:uu-485330
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https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-485330URI
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https://doi.org/10.1016/j.rechem.2020.100088DOI
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Språk:engelska
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Sammanfattning på:engelska
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Ebead et al. had reported in the synthesis and the UV-Visible solvatochromism combined with semiempirical calculations to study the tautomerism of 1,3-benzothiazol-2-ylacetonitrile azo dyes [1]. In this study, 1,3-ben zothiazol-2-ylacetonitrile azo dyes (1-6) have been resynthesized, one and two dimensional H-1 and C-13 NMR, as well as absorption and emission spectra, were collected and interpreted. The obtained results were used to clarify the tautomerization phenomenon of these dyes. Predominantly, these dyes exist in Z-hydrazone form reinforced through intramolecular hydrogen bonding in deuterated chloroform. Substituents (R) in carbon7 (CR7) are the key player of the changes in H-1 and C-13 NMR chemical shifts, also in the absorption and emission wavelengths of benzothiazole azo dyes. Also, the relative photoluminescence quantum yields (PL QY) of these dyes (1-6) were estimated and related to the nature of substituents. Finally, PM6 semiempirical calculations were employed to confirm the preferred geometric structure and experimental NMR, absorption, and emission results.
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Abdellah, M.Uppsala universitet,Institutionen för kemi - Ångström,South Valley Univ, Fac Sci, Chem Dept, Qena 83523, Egypt.
(författare)
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Rageh, H. M.South Valley Univ, Fac Sci, Chem Dept, Qena 83523, Egypt.
(författare)
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Salman, H. M. A.South Valley Univ, Fac Sci, Chem Dept, Qena 83523, Egypt.
(författare)
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Selim, M. A.South Valley Univ, Fac Sci, Chem Dept, Qena 83523, Egypt.
(författare)
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Santos, M. A.Univ Lisbon, Ctr Quim Estrutural, Inst Super Tecn, Av Rovisco Pais 1, P-1049001 Lisbon, Portugal.
(författare)
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Ibrahim, S. A.Assiut Univ, Fac Sci, Chem Dept, Assiut 71516, Egypt.
(författare)
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South Valley Univ, Fac Sci, Chem Dept, Qena 83523, Egypt.;Univ Lisbon, Ctr Quim Estrutural, Inst Super Tecn, Av Rovisco Pais 1, P-1049001 Lisbon, Portugal.Institutionen för kemi - Ångström
(creator_code:org_t)
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Ingår i:RESULTS IN CHEMISTRY: Elsevier32211-7156
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