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Effects of Sr/Ti-ra...
Effects of Sr/Ti-ratio in SrTiO3-based SOFC anodes investigated by the use of cone-shaped electrodes
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- Blennow Tullmar, Peter (författare)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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Kammer Hansen, Kent (författare)
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- Wallenberg, Reine (författare)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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Mogensen, Mogens (författare)
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(creator_code:org_t)
- Elsevier BV, 2006
- 2006
- Engelska.
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Ingår i: Electrochimica Acta. - : Elsevier BV. - 0013-4686. ; 52:4, s. 1651-1661
- Relaterad länk:
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http://dx.doi.org/10... (free)
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- In this work the A-site deficiency limit for undoped SrTiO3, calcined in air or reducing atmosphere, was investigated. XRD and SEM analyses showed that when using the solid-state synthesis route it was difficult to achieve any A-site deficiency. Even very small deviations from unity in the Sr/Ti-ratio resulted in impurity phases. The effects of Sr/Ti-ratio on the performance of SrTiO3 anodes for solid oxide fuel cells (SOFCs) was investigated by impedance spectroscopy with cone-shaped electrodes. The electrocatalytic activity of the SrTiO3 cone samples, with various amount of reduced titanium dioxide phases (Magnéli phases), was investigated for oxidation of H2 at 700 °C. High temperature treatment at 1000 °C, between the measurements at 700 °C, showed that high content of Magnéli phases leads to faster degradation of the activity. The suitability for using cone-shaped electrodes as a tool for investigating electrode materials is discussed.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- Magnéli phases
- Area normalization
- A-site deficiency
- Cone-shaped electrode
- SrTiO3
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
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