Hydrophobically modified ethyl(hydroxyethyl)cellulose as stabilizer and emulsifying agent in macroemulsions

Karlberg, MariaLund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH (författare)

Stability, droplet diameter and viscosity of o/w macroemulsions of olive oil stabilized with lecithin from soybean and different types of polymers have been investigated. The stabilizing polymers were non-ionic cellulose ethers, both with and without hydrophobic groups grafted onto the polymer backbone. Emulsions without polymers showed essentially no stability against creaming. Unmodified polymers provided limited stability, while hydrophobically modified versions of the polymers improved the stability dramatically. The viscosity of emulsions stabilized by hydrophobically modified polymers was significantly increased compared with aqueous solutions of the polymers alone, suggesting network formation including both polymers and emulsion droplets. It was also found that dilution had virtually no effect on the droplet diameters of emulsions stabilized with hydrophobically modified cellulose ethers and that coalescence was effectively opposed. (c) 2005 Elsevier B.V. All rights reserved.

Thuresson, KristerLund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)fk1-kth (författare)
Lindman, BjörnLund University,Lunds universitet,Fysikalisk kemi,Enheten för fysikalisk och teoretisk kemi,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Physical Chemistry,Physical and theoretical chemistry,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH(Swepub:lu)fk1-bli (författare)
Fysikalisk kemiEnheten för fysikalisk och teoretisk kemi (creator_code:org_t)

Ingår i:Colloids and Surfaces A: Physicochemical and Engineering Aspects: Elsevier BV262:1-3, s. 158-1670927-7757

Av författaren/redakt...: Karlberg, Maria; Thuresson, Krist ...; Lindman, Björn

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