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Synthetic applicati...
Synthetic applications of cationic iron and cobalt carbonyl complexes
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Bromfield, Karen M., 1976 (författare)
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Gradén, Henrik, 1968 (författare)
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Ljungdahl, N. (författare)
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visa fler...
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- Kann, Nina, 1964 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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visa färre...
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(creator_code:org_t)
- 2009
- 2009
- Engelska.
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Ingår i: Dalton Transactions. - 1477-9226 .- 1477-9234. ; :26, s. 5051-5061
- Relaterad länk:
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https://research.cha...
Abstract
Ämnesord
Stäng
- Metal carbonyl stabilized cationic species react with a wide range of nucleophiles under mild conditions, and have thus found many synthetic applications. In this Perspective, we describe the utility of iron carbonyl dienyl cations in solution and solid phase parallel synthesis, and in the development of a new synthetic route towards oseltamivir phosphate (Tamiflu). We also discuss the solid phase version of the Nicholas reaction, employing cobalt carbonyl stabilized propargylic cations, and giving access to substituted alkynes.
Ämnesord
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
Nyckelord
- activity
- dicobalt hexacarbonyl
- asymmetric catalytic complexation
- nicholas
- transition-metal-complexes
- solid-phase synthesis
- pauson-khand reaction
- reaction
- organic-synthesis
- potent antiinfluenza
- sonogashira coupling reactions
- neuraminidase inhibitor
- oseltamivir
- complexes
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
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