| 1. |
- Dziejarski, Bartosz, 1995, et al.
(författare)
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CO 2 capture materials: a review of current trends and future challenges
- 2023
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Ingår i: Materials Today Sustainability. - 2589-2347. ; 24
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Forskningsöversikt (refereegranskat)abstract
- Over the last decade, CO2 adsorption technology has quickly gained popularity and is now widely applied in global CCUS projects due to playing an important role in achieving net-zero emissions by 2050. As a result, novel materials, or post-modification methods of those already available have been successively reported to enhance the efficiency of CO2 capture from flue gases. This paper discusses a systematic understanding of fundamental aspects of current research trends in terms of developing selected solid CO2 adsorbent, with a particular emphasis on the upcoming challenges. The candidates are reviewed considering the practical drawbacks of imposed by industrial scale and economics, including carbon-based materials, metal-organic frameworks (MOFs), polymers, zeolites, silica, alumina, metal oxides, amine-based adsorbents, and other composite porous materials. Sustainable sorbents derived from biomass and industrial residues are also studied due to the high need for cost-effective raw materials and their crucial role in the circular economy. Lastly, a techno-economic analysis (TEA) is included to provide the most important criteria that should be considered when adsorbents are implemented on an industrial scale. Consequently, the review is summarized, and recommendations are offered for future research in the advancement of CO2 capture materials. The paper aims to establish a comprehensive theoretical basis of adsorption technologies currently progressed to reduce CO2 emissions, along with highlighting the identification and precise articulation of the most important future research paths that could be beneficial to address over the next years.
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| 2. |
- Dziejarski, Bartosz, 1995, et al.
(författare)
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Current status of carbon capture, utilization, and storage technologies in the global economy: A survey of technical assessment
- 2023
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Ingår i: Fuel. - : Elsevier BV. - 0016-2361. ; 342
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Forskningsöversikt (refereegranskat)abstract
- The latest tremendously rapid expansion of the energy and industrial sector has led to a sharp increase in stationary sources of CO2. Consequently, a lot of concerns have been raised about the prevention of global warming and the achievement of climate mitigation strategies by 2050 with a low-carbon and sustainable future. In view of this, the current state of various aspects of carbon capture, utilization, and storage (CCUS) technologies in general technical assessment were concisely reviewed and discussed. We concentrated on precisely identifying the technology readiness level (TRL), which is beneficial to specifically defining the maturity for each key element of the CCUS system with a commercialization direction paths. In addition, we especially presented and emphasized the importance of CO2 capture types from flue gases and CO2 separation methods. Then, we determined valuable data from the largest R&D projects at various scales. This paper provides a critical review of the literature related to challenges of the CCUS system that must be overcome to raise many low TRL technologies and facilitate their implementation on a commercial scale. Finally, our work aims to guide the further scaling up and establishment of worldwide CO2 emission reduction projects.
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| 3. |
- Dziejarski, Bartosz, 1995, et al.
(författare)
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Insights into Activation Pathways of Recovered Carbon Black (rCB) from End-of-Life Tires (ELTs) by Potassium-Containing Agents
- 2024
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Ingår i: ACS Omega. - 2470-1343. ; In Press
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Tidskriftsartikel (refereegranskat)abstract
- This study explores the conversion of recovered carbon black (rCB) from end-of-life tires (ELTs) into activated carbons (ACs) using potassium-based activators, targeting enhanced textural properties development. The research focuses on the interaction between potassium and rCB, with the aim of understanding the underlying mechanisms of rCB activation. The study investigates several parameters of KOH activation, including the KOH/rCB mass ratio (1:3 to 1:6), activation temperatures (700-900 °C), activation time (1-4 h), and heating rate (5-13 °C/min). It also assesses the effects of different potassium salts (KCl, K2CO3, CH3COOK, and K2C2O4) on porosity and surface characteristics of the rCB/ACs. Furthermore, the role of the physical state of KOH as an activator (solid and gas-solid) was examined, alongside a comparative analysis with NaOH to evaluate the distinct effects of potassium and sodium ions. Optimal conditions were identified at an 800 °C activation temperature, a 7 °C/min heating rate, a 1:5 KOH/rCB ratio, and a 4 h activation period. X-ray diffraction analysis showed the formation of several K-phases, such as K2CO3, K2CO3·1.5H2O, K4(CO3)2·(H2O)3, KHCO3, and K2O. The effectiveness of the potassium salts was ranked as follows: KOH > K2C2O4 > CH3COOK > K2CO3 > KCl, with KOH emerging as the most effective. Notably, the gas-solid reaction of KOH/rCB was indicated as a contributor to the activation process. Additionally, it was concluded that the role of KOH in enhancing the textural properties of rCB was primarily due to the interaction of K+ ions with the graphite-like structure of rCB, compared to the effects observed with NaOH. This research introduces novel insights into the specific roles of different potassium salts and KOH activation conditions in optimizing the textural characteristics of rCB/ACs.
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| 4. |
- Dziejarski, Bartosz, 1995, et al.
(författare)
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Upgrading recovered carbon black (rCB) from industrial-scale end-of-life tires (ELTs) pyrolysis to activated carbons: Material characterization and CO 2 capture abilities
- 2024
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Ingår i: Environmental Research. - 0013-9351 .- 1096-0953. ; 247
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Tidskriftsartikel (refereegranskat)abstract
- The current study presents for the first time how recovered carbon black (rCB) obtained directly from the industrial-scale end-of-life tires (ELTs) pyrolysis sector is applied as a precursor for activated carbons (ACs) with application in CO2 capture. The rCB shows better physical characteristics, including density and carbon structure, as well as chemical properties, such as a consistent composition and low impurity concentration, in comparison to the pyrolytic char. Potassium hydroxide and air in combination with heat treatment (500–900 °C) were applied as agents for the conventional chemical and physical activation of the material. The ACs were tested for their potential to capture CO2. Ultimate and proximate analysis, Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS), Raman spectroscopy, thermogravimetric analysis (TGA), and N2/CO2 gas adsorption/desorption isotherms were used as material characterization methods. Analysis revealed that KOH-activated carbon at 900 °C (AC-900K) exhibited the highest surface area and a pore volume that increased 6 and 3 times compared to pristine rCB. Moreover, the AC-900K possessed a well-developed dual porosity, corresponding to the 22% and 78% of micropore and mesopore volume, respectively. At 0 °C and 25 °C, AC-900K also showed a CO2 adsorption capacity equal to 30.90 cm3/g and 20.53 cm3/g at 1 bar, along with stable cyclic regeneration after 10 cycles. The high dependence of CO2 uptake on the micropore volume at width below 0.7–0.8 nm was identified. The selectivity towards CO2 in relation to N2 reached high values of 350.91 (CO2/N2 binary mixture) and 59.70 (15% CO2/85% N2).
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