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- Holmes, N. P., et al.
(författare)
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Diketopyrrolopyrrole-based polymer:fullerene nanoparticle films with thermally stable morphology for organic photovoltaic applications
- 2017
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Ingår i: MRS Communications. - : Springer Science and Business Media LLC. - 2159-6859 .- 2159-6867. ; 7:1, s. 67-73
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Tidskriftsartikel (refereegranskat)abstract
- Polymer:fullerene nanoparticles (NPs) offer two key advantages over bulk heterojunction (BHJ) films for organic photovoltaics (OPVs), water-processability and potentially superior morphological control. Once an optimal active layer morphology is reached, maintaining this morphology at OPV operating temperatures is key to the lifetime of a device. Here we study the morphology of the PDPP-TNT (poly{3,6-dithiophene-2-yl-2,5-di(2-octyldodecyl)-pyrrolo[3,4-c]pyrrole- 1,4-dione-alt-naphthalene}):PC71BM ([6,6]-phenyl C-71 butyric acid methyl ester) NP system and then compare the thermal stability of NP and BHJ films to the common poly(3-hexylthiophene) (P3HT): phenyl C-61 butyric acid methyl ester (PC61BM) system. We find that material T-g plays a key role in the superior thermal stability of the PDPP-TNT:PC71BM system; whereas for the P3HT:PC61BM system, domain structure is critical.
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2. |
- Horn, M. R., et al.
(författare)
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Polyoxometalates (POMs) : From electroactive clusters to energy materials
- 2021
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Ingår i: Energy & Environmental Science. - : Royal Society of Chemistry. - 1754-5692 .- 1754-5706. ; 14:4, s. 1652-1700
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Tidskriftsartikel (refereegranskat)abstract
- Polyoxometalates (POMs) represent a class of nanomaterials, which hold enormous promise for a range of energy-related applications. Their promise is owing to their "special"structure that gives POMs a truly unique ability to control redox reactions in energy conversion and storage. One such amazing capability is their large number of redox active sites that arises from the complex three-dimensional cluster of metal-oxide ions linked together by oxygen atoms. Here, a critical review on how POMs emerged from being molecular clusters for fundamental studies, to next-generation materials for energy applications is provided. We highlight how exploiting the versatility and activity of these molecules can lead to improved performance in energy devices such as supercapacitors and batteries, and in energy catalyst applications. The potential of POMs across numerous fields is systematically outlined by investigating structure-property-performance relationships and the determinant factors for energy systems. Finally, the challenges and opportunities for this class of materials with respect to addressing our pressing energy-related concerns are identified. This journal is © The Royal Society of Chemistry.
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3. |
- Kunz, Susanna, V, et al.
(författare)
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A simplified approach to thermally activated delayed fluorescence (TADF) bipolar host polymers
- 2022
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Ingår i: Polymer Chemistry. - : Royal Society of Chemistry. - 1759-9954 .- 1759-9962. ; 13:29, s. 4241-4248
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Tidskriftsartikel (refereegranskat)abstract
- Organic Light Emitting Diodes (OLEDs) are a critical part of current consumer electronics, from mobile device displays to solid-state lighting. Thus demand for the development of industrially compatible OLED materials continues to increase. Herein, we introduce a series of solution-processible polymers incorporating a Thermally Activated Delayed Fluorescence (TADF) emitter and a host species in the side chain to finely adjust the charge transport properties. For balanced charge transport, a bipolar host polymer based on carbazole and alpha-carboline was investigated in addition to the commonly employed unipolar host mCP and an electron transporting version thereof. We demonstrate that the combination of unipolar co-hosts on one polymer chain can generate, with less synthetic effort, the same optoelectronic properties as a polymer carrying the corresponding bipolar host molecule as a pendant.
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4. |
- Müller, Christian, 1980, et al.
(författare)
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One-Step Macroscopic Alignment of Conjugated Polymer Systems by Epitaxial Crystallization during Spin-Coating
- 2013
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Ingår i: Advanced Functional Materials. - : Wiley. - 1616-3028 .- 1616-301X. ; 23:19, s. 2368-2377
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Tidskriftsartikel (refereegranskat)abstract
- The one-step preparation of highly anisotropic polymer semiconductor thin films directly from solution is demonstrated. The conjugated polymer poly(3-hexylthiophene) (P3HT) as well as P3HT:fullerene bulk–heterojunction blends can be spin-coated from a mixture of the crystallizable solvent 1,3,5-trichlorobenzene (TCB) and a second carrier solvent such as chlorobenzene. Solidification is initiated by growth of macroscopic TCB spherulites followed by epitaxial crystallization of P3HT on TCB crystals. Subsequent sublimation of TCB leaves behind a replica of the original TCB spherulites. Thus, highly ordered thin films are obtained, which feature square-centimeter-sized domains that are composed of one spherulite-like structure each. A combination of optical microscopy and polarized photoluminescence spectroscopy reveals radial alignment of the polymer backbone in case of P3HT, whereas P3HT:fullerene blends display a tangential orientation with respect to the center of spherulite-like structures. Moreover, grazing-incidence wide-angle X-ray scattering reveals an increased relative degree of crystallinity and predominantly flat-on conformation of P3HT crystallites in the blend. The use of other processing methods such as dip-coating is also feasible and offers uniaxial orientation of the macromolecule. Finally, the applicability of this method to a variety of other semi-crystalline conjugated polymer systems is established. Those include other poly(3-alkylthiophene)s, two polyfluorenes, the low band-gap polymer PCPDTBT, a diketopyrrolopyrrole (DPP) small molecule as well as a number of polymer:fullerene and polymer:polymer blends.
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