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- Bhattacharyya, Shubhankar, et al.
(författare)
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Ether Functionalized Choline Tethered Amino Acid Ionic Liquids for Enhanced CO2 Capture
- 2016
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Ingår i: ACS Sustainable Chemistry and Engineering. - : American Chemical Society (ACS). - 2168-0485. ; 4:10, s. 5441-5449
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Tidskriftsartikel (refereegranskat)abstract
- Amino acid ionic liquids (ILs) are the most interesting and effective for CO2 capture due to their low toxicity, biodegradability and fast reactivity towards CO2. Ionic nature of amino acid ILs can raise an environmental issue if the cation counterpart becomes toxic to the aquatic ecosystems and can become potential atmospheric pollutant. In this regard, choline based ILs are known to be promising scaffolds for the development of less toxic amino acid ILs. However, the existing choline amino acid ILs are highly viscous limiting their applicability as solvents. Ether functionalized choline based amino acid ILs with novel series of less toxic green ILs were explored with reduced viscosity and high CO2 capture capacity. A simple, economic, clean and environmentally benign method was utilized for the synthesis of novel choline based amino acid ILs using a commercially available and economical starting material 2-(dimethylamino)ethanol (deanol, a human dietary food supplement). Reported ILs have low viscosity with high CO2 capture capacity (1.62 mol of CO2 /mol of IL, 4.31 mol of CO2/kg of IL, 19.02 wt.% of CO2). Mechanism of [N1,1,6,2O4][Lys]+CO2 reaction and adduct structure was proposed by means of DFT and NMR.
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- Bhattacharyya, Shubhankar, et al.
(författare)
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High CO2 absorption capacity by chemisorption at cations and anions in choline-based ionic liquids
- 2017
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Ingår i: Physical Chemistry, Chemical Physics - PCCP. - : Royal Society of Chemistry. - 1463-9076 .- 1463-9084. ; 19:46, s. 31216-31226
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Tidskriftsartikel (refereegranskat)abstract
- The effect of CO2 absorption on the aromaticity and hydrogen bonding in ionic liquids is investigated. Five different ionic liquids with choline based cations and aprotic N-heterocyclic anions were synthesized. Purity and structures of the synthesized ionic liquids were characterized by 1H and 13C NMR spectroscopy. CO2 capture performance was studied at 20 °C and 40 °C under three different pressures (1, 3, 6 bar). The IL [N1,1,6,2OH][4-Triz] showed the highest CO2 capture capacity (28.6 wt%, 1.57 mol of CO2 per mol of the IL, 6.48 mol of CO2 per kg of the ionic liquid) at 20 °C and 1 bar. The high CO2 capture capacity of the [N1,1,6,2OH][4-Triz] IL is due to the formation of carbonic acid (–OCO2H) together with carbamate by participation of the –OH group of the [N1,1,6,2OH]+ cation in the CO2 capture process. The structure of the adduct formed by CO2 reaction with the IL [N1,1,6,2OH][4-Triz] was probed by using IR, 13C NMR and 1H–13C HMBC NMR experiments utilizing 13C labeled CO2 gas. 1H and 13C PFG NMR studies were performed before and after CO2 absorption to explore the effect of cation–anion structures on the microscopic ion dynamics in ILs. The ionic mobility was significantly increased after CO2 reaction due to lowering of aromaticity in the case of ILs with aromatic N-heterocyclic anions.
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- Bhattacharyya, Shubhankar, et al.
(författare)
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Insights into the Effect of CO2 Absorption on the Ionic Mobility of Ionic Liquids
- 2016
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Ingår i: Physical Chemistry, Chemical Physics - PCCP. - 1463-9076 .- 1463-9084. ; 18:41, s. 28617-28625
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Tidskriftsartikel (refereegranskat)abstract
- We investigate a comparative effect of CO2 absorption on the ionic mobility of two choline based ionic liquids comprising two different anions such as threonine and imidazole. The synthesized ionic liquids were characterized using 1H and 13C NMR and other spectroscopic techniques. By keeping a common cation and changing the anion from threonine to imidazole both the viscosity and density reduced drastically. We found that [N1,1,6,2OH][Imi] exhibits the highest CO2 capture capacity at 20 °C of 5.27 mol of CO2 per kg of ionic liquid (1.27 mol of CO2 per mol of ionic liquid, 23.26 wt% of CO2) whereas [N1,1,6,2OH][Threo] exhibits 3.6 mol of CO2 per kg of ionic liquid (1.05 mol of CO2 per mol of ionic liquid, 15.87 wt% of CO2). The activation energy for diffusion is calculated using the Vogel-Fulcher-Tamman (VFT) equation in the form of diffusivity. It was found that the activation energy for the diffusion of [N1,1,6,2OH][Threo] is ∼10 times higher than that of [N1,1,6,2OH][Imi]. 1H diffusion NMR data revealed that the diffusivity of [N1,1,6,2OH][Imi] is increased after CO2 absorption whereas a decrease in diffusivity was observed in the case of [N1,1,6,2OH][Threo]. This anomalous behavior of [N1,1,6,2OH][Imi] was further explained by using DFT calculations.
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- Bhattacharyya, Shubhankar, et al.
(författare)
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Melt Stable Functionalized Organosolv and Kraft Lignin Thermoplastic
- 2020
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Ingår i: Processes. - : MDPI. - 2227-9717. ; 8:9
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Tidskriftsartikel (refereegranskat)abstract
- A shift towards an economically viable biomass biorefinery concept requires the use of all biomass fractions (cellulose, hemicellulose, and lignin) for the production of high added-value products. As lignin is often underutilized, the establishment of lignin valorization routes is highly important. In-house produced organosolv as well as commercial Kraft lignin were used in this study. The aim of the current work was to make a comparative study of thermoplastic biomaterials from two different types of lignins. Native lignins were alkylate with two different alkyl iodides to produce ether-functionalized lignins. Successful etherification was verified by FT-IR spectroscopy, changes in the molecular weight of lignin, as well as 13C and 1H Nuclear Magnetic Resonance (NMR). The thermal stability of etherified lignin samples was considerably improved with the T2% of organosolv to increase from 143 °C to up to 213 °C and of Kraft lignin from 133 °C to up to 168 °C, and glass transition temperature was observed. The present study shows that etherification of both organosolv and Kraft lignin with alkyl halides can produce lignin thermoplastic biomaterials with low glass transition temperature. The length of the alkyl chain affects thermal stability as well as other thermal properties.
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- Bhattacharyya, Shubhankar, et al.
(författare)
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Theoretical investigation of banert cascade reaction
- 2018
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Ingår i: Royal Society Open Science. - : Royal Society Publishing. - 2054-5703. ; 5:4
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Tidskriftsartikel (refereegranskat)abstract
- Computational inside of Banert cascade reaction for triazole formation is studied with B3LYP/6-31G(d,p) level of theory. The reaction proceeds mainly by SN2 initial chloride displacement rather than SN2′ -type attack. Furthermore, according to the rate of reaction calculation, SN2 displacement is much faster than SN2′ displacement in the order of 8. The [3,3]-sigmatropic rearrangement for the conversion of propargyl azide into triazafulvene has been proved as the rate-determining step having highest activation energy parameter. Solvent effect on total course of reaction has been found negligible. Furthermore, effects of different density functional theory functionals and functional groups on activation energies of [3,3]-sigmatropic rearrangement of propargyl azide were also studied. BHHLYP, ωB97XD, M062X and BMK calculated ∆G‡ are consistent with B3LYP.
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- Bhattacharyya, Shubhankar, et al.
(författare)
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Thermal stability of choline based amino acid ionic liquids
- 2018
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Ingår i: Journal of Molecular Liquids. - : Elsevier. - 0167-7322 .- 1873-3166. ; 266, s. 597-602
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Tidskriftsartikel (refereegranskat)abstract
- Thermal stability of different choline based amino acid ionic liquids were studied. Both short term as well as long term thermal studies were carried out. Long term thermal studies of all ILs were carried out by isothermal TGA and short term thermal studies were measured by temperature ramped TGA. Isothermal TGA were studied at two different temperatures 100 °C and 150 °C for 500 min. Whereas, short term thermal stability represents as T2%, T5% and T10% which are the temperature at which 2%, 5% and 10% mass loss of ILs were observed. The effect of alkyl side chain on the cation, etherification of the cation as well structural variation of anion on the thermal stability of choline based ILs were investigated. It was observed that thermal characteristics of ILs towards temperature ramped TGA were different compared to isothermal TGA.
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- Filippov, Andrei, PhD, 1957-, et al.
(författare)
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CO2 absorption and ion mobility in aqueous choline-based ionic liquids
- 2019
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Ingår i: Journal of Molecular Liquids. - : Elsevier. - 0167-7322 .- 1873-3166. ; 276, s. 748-752
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Tidskriftsartikel (refereegranskat)abstract
- CO2 absorption and ion mobility are investigated in a series of 50/50 wt% aqueous solutions of choline-based ionic liquids with different cations and anions: [N1,1,4,2OH][Threo], [N1,1,5,2OH][Threo], [N1,1,6,2OH][Threo], [N1,1,5,2OH][β-ala] and [N1,1,5,2OH][Tau]. The process of CO2 absorption was completed in an hour reaching maximum of absorption capacity 0.07–0.10 wt% to ionic liquid (by 0.4–0.6 molar ratios). A rapid CO2 absorption is observed by the formation of solid product as a result of reaction between CO2 molecule and the ionic liquid. Diffusion coefficients of the cation and anion in the mixture are comparable while the diffusivity of water molecules is found to be quite different from the ions. In the process of CO2 absorption, an increase in the diffusivity of ions is observed due to the precipitation of solid products and depletion of ions contents in the liquid phase of the system. 13C NMR measurements of diffusivity of CO2 enriched with 13C isotope showed that a part of the absorbed CO2 remained in the liquid phase being physically and chemically bound to ions. The ionic liquid is re-cycled by evaporating water and releasing CO2 molecules using vacuum and temperature.
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- Filippov, Andrei, et al.
(författare)
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Dynamic Properties of Imidazolium Orthoborate Ionic Liquids Mixed with Polyethylene Glycol Studied by NMR Diffusometry and Impedance Spectroscopy
- 2018
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Ingår i: Magnetic Resonance in Chemistry. - : John Wiley & Sons. - 0749-1581 .- 1097-458X. ; 56:2, s. 113-119
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Tidskriftsartikel (refereegranskat)abstract
- We used 1H pulsed field gradient (PFG) NMR to study the self-diffusion of polyethylene glycol (PEG) with average molecular mass of 200 and ions in mixtures of PEG with imidazolium bis(mandelato)borate (BMB) and imidazolium bis(oxalato)borate (BOB) ionic liquids (ILs). The ionic liquid was mixed with PEG in the concentration range of 0–100 wt%. Within the temperature range of 295 to 353 K, the diffusion coefficient of BMB is slower than that of the imidazolium cation. The diffusion coefficients of PEG, as well as the imidazolium cation and BMB anions, differ under all experimental conditions tested. This demonstrates that the IL in the mixture is present in at least a partially dissociated state. Generally, increasing the concentration of PEG leads to an increase in the diffusion coefficients of PEG and both the ions, and decreases their activation energy for diffusion. NMR chemical shift alteration analysis showed that the presence of PEG changes the chemical shifts of both ions but in different directions. Impedance spectroscopy was used to measure the ionic conductivity of the ionic liquids mixed with PEG.
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- Molaiyan, Palanivel, et al.
(författare)
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Towards greener batteries : sustainable components and materials for next-generation batteries
- 2024
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Ingår i: Green Chemistry. - : Royal Society of Chemistry. - 1463-9262 .- 1463-9270. ; 26:13, s. 7508-7531
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Tidskriftsartikel (refereegranskat)abstract
- Batteries are the main component of many electrical systems, and due to the elevated consumption of electric vehicles and portable electronic devices, they are the dominant and most rapidly growing energy storage technology. Consequently, they are set to play a crucial role in meeting the goal of cutting greenhouse gas emissions to achieve more sustainable societies. In this critical report, a rational basic-to-advanced compilation study of the effectiveness, techno-feasibility, and sustainability aspects of innovative greener manufacturing technologies and processes that deliver each battery component (anodes, cathodes, electrolytes, and separators) is accomplished, aiming to improve battery safety and the circularity of end-products. Special attention is given to biomass-derived anode materials and bio-based separators utilization that indicates excellent prospects considering green chemistry, greener binders, and energy storage applications. To fully reach this potential, one of the most promising ways to achieve sustainable batteries involves biomass-based electrodes and non-flammable and non-toxic electrolytes used in lithium-ion batteries and other chemistries, where the potential of a greener approach is highly beneficial, and challenges are addressed. The crucial obstacles related to the successful fabrication of greener batteries and potential future research directions are highlighted. Bridging the gap between fundamental and experimental research will provide critical insights and explore the potential of greener batteries as one of the frontrunners in the uptake of sustainability and value-added products in the battery markets of the future.
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- Pathak, Uma, et al.
(författare)
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An easy access to thiazolines and thiazines via tandem S-alkylation- cyclodeamination of thioamides/haloamines
- 2011
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Ingår i: Green Chemistry. - : Royal Society of Chemistry (RSC). - 1463-9262 .- 1463-9270. ; 13:7, s. 1648-1651
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Tidskriftsartikel (refereegranskat)abstract
- This is the first report of a facile synthesis of thiazolines and thiazines from a self-catalyzed, water assisted tandem S-alkylation-cyclodeamination reaction of thioamides/haloamines. The reaction is clean and efficient with simple product work-up, and is applicable to a variety of substrates
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- Stamm, Arne, et al.
(författare)
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Pinene-Based Oxidative Synthetic Toolbox for Scalable Polyester Synthesis
- 2021
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Ingår i: JACS Au. - : American Chemical Society (ACS). - 2691-3704. ; 1:11, s. 1949-1960
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Tidskriftsartikel (refereegranskat)abstract
- Generation of renewable polymers is a long-standing goal toward reaching a more sustainable society, but building blocks in biomass can be incompatible with desired polymerization type, hampering the full implementation potential of biomaterials. Herein, we show how conceptually simple oxidative transformations can be used to unlock the inherent reactivity of terpene synthons in generating polyesters by two different mechanisms starting from the same alpha-pinene substrate. In the first pathway, alpha-pinene was oxidized into the bicyclic verbanone-based lactone and subsequently polymerized into star-shaped polymers via ring-opening polymerization, resulting in a biobased semicrystalline polyester with tunable glass transition and melting temperatures. In a second pathway, polyesters were synthesized via polycondensation, utilizing the diol 1-(1'-chydroxyethyl)-3-(2'-hydroxyethyl)-2,2-dimethylcyclobutane (HHDC) synthesized by oxidative cleavage of the double bond of alpha-pinene, together with unsaturated biobased diesters such as dimethyl maleate (DMM) and dimethyl itaconate (DMI). The resulting families of terpenebased polyesters were thereafter successfully cross-Iinked by either transetherification, utilizing the terminal hydroxyl groups of the synthesized verbanone-based materials, or by UV irradiation, utilizing the unsaturation provided by the DMM or DMI moieties within the HHDC-based copolymers. This work highlights the potential to apply an oxidative toolbox to valorize inert terpene metabolites enabling generation of biosourced polyesters and coatings thereof by complementary mechanisms.
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- Tank, Rekha, et al.
(författare)
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Hydrogen peroxide mediated efficient amidation and esterification of aldehydes : Scope and selectivity
- 2011
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Ingår i: Green Chemistry. - : Royal Society of Chemistry (RSC). - 1463-9262 .- 1463-9270. ; 13:12, s. 3350-3354
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Tidskriftsartikel (refereegranskat)abstract
- An efficient method for the amidation and esterification of aldehydes utilizing hydrogen peroxide as an oxidant has been developed. Cyclic amines and primary alcohols selectively reacted with aromatic aldehydes under mild conditions to yield the corresponding amides and esters
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