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- Andersson, Odd E., et al.
(författare)
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Pressure-induced modifications of structural and transport properties in SbCl5 intercalated graphite
- 1992
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Ingår i: Materials Science Forum volumes 91-93, Part I. - Zürich : Trans Tech Publications. - 0878496394 ; , s. 301-306
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Konferensbidrag (refereegranskat)abstract
- The structure and the c-axis resistivity of SbCl5 intercalated graphite have been studied as functions of T and p, over the ranges 40 to 295 K and 0 to 0.7 GPa. Slow cooling or slow application of pressure p > 0.4 GPa lead to states of complete but different crystallization of the intercalate, but after rapid cooling or pressurization any crystallization is incomplete. The resistivity of the high pressure crystallized phase is about 50% lower than that of the low T, low p phase under identical p-T conditions. No significant difference is seen between the behaviour of HOPG-based and single crystal based materials.
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