| 1. |
- Kristanl, Matej, et al.
(författare)
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The Seventh Visual Object Tracking VOT2019 Challenge Results
- 2019
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Ingår i: 2019 IEEE/CVF INTERNATIONAL CONFERENCE ON COMPUTER VISION WORKSHOPS (ICCVW). - : IEEE COMPUTER SOC. - 9781728150239 ; , s. 2206-2241
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Konferensbidrag (refereegranskat)abstract
- The Visual Object Tracking challenge VOT2019 is the seventh annual tracker benchmarking activity organized by the VOT initiative. Results of 81 trackers are presented; many are state-of-the-art trackers published at major computer vision conferences or in journals in the recent years. The evaluation included the standard VOT and other popular methodologies for short-term tracking analysis as well as the standard VOT methodology for long-term tracking analysis. The VOT2019 challenge was composed of five challenges focusing on different tracking domains: (i) VOT-ST2019 challenge focused on short-term tracking in RGB, (ii) VOT-RT2019 challenge focused on "real-time" short-term tracking in RGB, (iii) VOT-LT2019 focused on long-term tracking namely coping with target disappearance and reappearance. Two new challenges have been introduced: (iv) VOT-RGBT2019 challenge focused on short-term tracking in RGB and thermal imagery and (v) VOT-RGBD2019 challenge focused on long-term tracking in RGB and depth imagery. The VOT-ST2019, VOT-RT2019 and VOT-LT2019 datasets were refreshed while new datasets were introduced for VOT-RGBT2019 and VOT-RGBD2019. The VOT toolkit has been updated to support both standard short-term, long-term tracking and tracking with multi-channel imagery. Performance of the tested trackers typically by far exceeds standard baselines. The source code for most of the trackers is publicly available from the VOT page. The dataset, the evaluation kit and the results are publicly available at the challenge website(1).
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| 2. |
- Chen, Jialin, et al.
(författare)
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Hydroxycamptothecin and substratum stiffness synergistically regulate fibrosis of human corneal fibroblasts
- 2023
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Ingår i: ACS Biomaterials Science & Engineering. - : American Chemical Society (ACS). - 2373-9878. ; 9:2, s. 959-967
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Tidskriftsartikel (refereegranskat)abstract
- Corneal fibrosis is a common outcome of inappropriate repair associated with trauma or ocular infection. Altered biomechanical properties with increased corneal stiffness is a feature of fibrosis that cause corneal opacities, resulting in severe visual impairment and even blindness. The present study aims to determine the effect of hydroxycamptothecin (HCPT) and matrix stiffness on transforming growth factor-β1 (TGF-β1)-induced fibrotic processes in human corneal fibroblasts (HTK cells). HTK cells were cultured on substrates with different stiffnesses ("soft", ∼261 kPa; "stiff", ∼2.5 × 103 kPa) and on tissue culture plastic (TCP, ∼106 kPa) and simultaneously treated with or without 1 μg/mL HCPT and 10 ng/mL TGF-β1. We found that HCPT induced decreased cell viability and antiproliferative effects on HTK cells. TGF-β1-induced expression of fibrosis-related genes (FN1, ACTA2) was reduced if the cells were simultaneously treated with HCPT. Substrate stiffness did not affect the expression of fibrosis-related genes. The TGF-β1 induced expression of FN1 on both soft and stiff substrates was reduced if cells were simultaneously treated with HCPT. However, this trend was not seen for ACTA2, i.e., the TGF-β1 induced expression of ACTA2 was not reduced by simultaneous treatment of HCPT in either soft or stiff substrate. Instead, HCPT treatment in the presence of TGF-β1 resulted in increased gene expression of keratocyte phenotype makers (LUM, KERA, AQP1, CHTS6) on both substrate stiffnesses. In addition, the protein expression of keratocyte phenotype makers LUM and ALDH3 was increased in HTK cells simultaneously treated with TGF-β1 and HCPT on stiff substrate as compared to control, i.e., without HCPT. In conclusion, we found that HCPT can reduce TGF-β1-induced fibrosis and promote the keratocyte phenotype in a substrate stiffness dependent manner. Thus, HCPT stimulation might be an approach to stimulate keratocytes in the appropriate healing stage to avoid or reverse fibrosis and achieve more optimal corneal wound healing.
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| 3. |
- He, Haoran, et al.
(författare)
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Linking soil depth to aridity effects on soil microbial community composition, diversity and resource limitation
- 2023
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Ingår i: Catena. - 0341-8162. ; 232
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Tidskriftsartikel (refereegranskat)abstract
- With ongoing climate change, aridity is increasing worldwide, affecting biodiversity and ecosystem function in drylands. However, how the depth-profile microbial community structure and metabolic limitations change along aridity gradients are still poorly explored. Here, 16S rRNA and ITS amplicon sequencing and ecoenzymatic stoichiometry analysis were used to investigate both bacterial and fungal diversities and resource limitations in 1 m depth profiles across a wide aridity gradient (0.51–0.78) in a semiarid region. Results showed a sharp decrease in microbial diversity with soil depth, accompanied by an increase in microbial phosphorus (P) vs. N (nitrogen) limitation and a decrease in microbial carbon (C) vs. nutrient limitation. Aridity led to a strong shift in microbial community composition, but aridity has a threshold effect on microbial resource limitation through impacts on soil pH and C/P or N/P. When the aridity threshold (1-precipitation/evapotranspiration) exceeds 0.65, relationship between aridity and microbial resource demand was decoupled; but at aridity threshold = 0.65, microbial relative C limitation and C-acquiring enzyme activity dropped. These results suggest that aridity might have a stronger influence on microbial community composition, than on diversity, shaped by inherent soil biotic factors (i.e., MBC:MBP or MBN:MBP). These findings suggest that soil microbial diversity or enzymatic stoichiometry may be not necessary to mirror changes in water availability in the drylands, while aridity would be well explained by microbial community composition.
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| 4. |
- Sheng, Renwang, et al.
(författare)
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Material stiffness in cooperation with macrophage paracrine signals determines the tenogenic differentiation of mesenchymal stem cells
- 2023
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Ingår i: Advanced Science. - : John Wiley & Sons. - 2198-3844. ; 10:17
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Tidskriftsartikel (refereegranskat)abstract
- Stiffness is an important physical property of biomaterials that determines stem cell fate. Guiding stem cell differentiation via stiffness modulation has been considered in tissue engineering. However, the mechanism by which material stiffness regulates stem cell differentiation into the tendon lineage remains controversial. Increasing evidence demonstrates that immune cells interact with implanted biomaterials and regulate stem cell behaviors via paracrine signaling; however, the role of this mechanism in tendon differentiation is not clear. In this study, polydimethylsiloxane (PDMS) substrates with different stiffnesses are developed, and the tenogenic differentiation of mesenchymal stem cells (MSCs) exposed to different stiffnesses and macrophage paracrine signals is investigated. The results reveal that lower stiffnesses facilitates tenogenic differentiation of MSCs, while macrophage paracrine signals at these stiffnesses suppress the differentiation. When exposed to these two stimuli, MSCs still exhibit enhanced tendon differentiation, which is further elucidated by global proteomic analysis. Following subcutaneous implantation in rats for 2 weeks, soft biomaterial induces only low inflammation and promotes tendon-like tissue formation. In conclusion, the study demonstrates that soft, rather than stiff, material has a greater potential to guide tenogenic differentiation of stem cells, which provides comprehensive evidence for optimized bioactive scaffold design in tendon tissue engineering.
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| 5. |
- Sun, Weiyi, et al.
(författare)
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Multi-centennial ENSO-like variability response to solar activity during the holocene
- 2024
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Ingår i: CLIMATE DYNAMICS. - 0930-7575 .- 1432-0894.
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Tidskriftsartikel (refereegranskat)abstract
- Previous reconstructions suggest a possible correlation between solar and El Nino-Southern Oscillation (ENSO) on the centennial-millennial time scales, but the mechanism remains controversial. This study conducts Holocene transient simulations and finds a significant 350-500-year cycle of ENSO-like variability during the mid-late Holocene under solar activity forcing, supported by multiple reconstructions. This multi-centennial ENSO-like variability is caused by the solar-forced low-latitude process, not the high-latitude process or internal variability. When solar radiation increases, the subtropical Asian continent-Indian Ocean thermal contrast is enhanced, increasing precipitation over the India and Bay of Bengal, which generates easterly anomaly over the Indo-Pacific warm pool. Increased solar radiation also enhances the evaporation in the cloud-free regions of western North and South Pacific, and the moisture is transported to the Maritime Continent by easterly. This increases precipitation there and strengthens the easterly anomaly over the equatorial western Pacific, which triggers the La Nina-like state. The leading coupling process for the development of La Nina-like state is zonal advective and upwelling feedback, and poleward heat advection further amplifies the equatorial eastern Pacific cooling. Findings from this study suggests that a centennial-scale El Nino-like condition might occur under solar forcings if the forecast predicts a solar minimum at the end of the 21st century.
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| 6. |
- Wang, Fei, et al.
(författare)
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Endothelial cell heterogeneity and microglia regulons revealed by a pig cell landscape at single-cell level
- 2022
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Ingår i: Nature Communications. - : Springer Nature. - 2041-1723. ; 13:1
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Tidskriftsartikel (refereegranskat)abstract
- Pigs are valuable large animal models for biomedical and genetic research, but insights into the tissue- and cell-type-specific transcriptome and heterogeneity remain limited. By leveraging single-cell RNA sequencing, we generate a multiple-organ single-cell transcriptomic map containing over 200,000 pig cells from 20 tissues/organs. We comprehensively characterize the heterogeneity of cells in tissues and identify 234 cell clusters, representing 58 major cell types. In-depth integrative analysis of endothelial cells reveals a high degree of heterogeneity. We identify several functionally distinct endothelial cell phenotypes, including an endothelial to mesenchymal transition subtype in adipose tissues. Intercellular communication analysis predicts tissue- and cell type-specific crosstalk between endothelial cells and other cell types through the VEGF, PDGF, TGF-beta, and BMP pathways. Regulon analysis of single-cell transcriptome of microglia in pig and 12 other species further identifies MEF2C as an evolutionally conserved regulon in the microglia. Our work describes the landscape of single-cell transcriptomes within diverse pig organs and identifies the heterogeneity of endothelial cells and evolutionally conserved regulon in microglia.
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| 7. |
- Gao, Hongyuan, et al.
(författare)
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Monostatic MIMO radar direction finding in impulse noise
- 2021
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Ingår i: Digital Signal Processing: A Review Journal. - : Elsevier BV. - 1051-2004. ; 117
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Tidskriftsartikel (refereegranskat)abstract
- This work considers direction-finding using a monostatic multiple-input multiple-output (MIMO) radar in the presence of impulsive noise. Employing a novel low-order covariance-based exponential kernel function, the proposed maximum likelihood (ML) formulation exploits an introduced quantum whale optimization algorithm (QWOA) to form the direction estimates. The resulting estimates are shown to be robust to the presence of impulsive noise, offering preferable performance as compared to recent related approaches, even in cases when the number of available snapshots is small.
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| 8. |
- Gao, Yan, et al.
(författare)
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Perovskite Hydroxide CoSn(OH)(6) Nanocubes for Efficient Photoreduction of CO2 to CO
- 2018
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Ingår i: ACS Sustainable Chemistry and Engineering. - : AMER CHEMICAL SOC. - 2168-0485. ; 6:1, s. 781-786
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Tidskriftsartikel (refereegranskat)abstract
- Perovskite hydroxide CoSn(OH)(6) nanoparticles were synthesized and used for the first time in the photocatalytic reduction of CO2 to CO. Under mild reaction conditions and using [Ru(bpy)(3)](PF6)(2) as the photosensitizer, a high photocatalytic efficiency of 19.3 mu mol for CO evolution with a high selectivity of 86.46% was obtained. The photocatalytic TEOA activity and CO selectivity were further improved by adding weak Bronsted acids, as proton sources, to the system.
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| 9. |
- Li, Yingkui, et al.
(författare)
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Timing and extent of Quaternary glaciations in the Tianger Range, eastern Tian Shan, China, investigated using Be-10 surface exposure dating
- 2014
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Ingår i: Quaternary Science Reviews. - : Elsevier BV. - 0277-3791 .- 1873-457X. ; 98, s. 7-23
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Tidskriftsartikel (refereegranskat)abstract
- Reconstructing glacial chronologies with consistent methods is critical for efforts to examine the timing and pattern of past climate change. Cosmogenic Be-10 surface exposure dating has been widely used to constrain the timing of glacial events on the Tibetan Plateau and in Central Asia. However, few such studies have been conducted in the Chinese Tian Shan and available Be-10 ages from this region have only provided evidence for glacial events during the global Last Glacial Maximum (gLGM) and Lateglacial. Here, we present 45 Be-10 surface exposure ages from glacial landforms in the Ala and Daxi valleys, two formerly glaciated valleys draining the Tianger Range, eastern Tian Shan. Combined with previously published Be-10 surface exposure ages from the Daxi Valley in the source area of the Urumqi River, the new ages record five major glacial events during Marine Oxygen Isotope Stages (MIS) 6 or older, 4, 3, 2, and 1 (during the Little Ice Age, LIA). Landforms from glacial events since MIS 2 are found on the northern slope of the Tianger Range (Daxi Valley), whereas evidence for the older glacial events is only preserved on its southern slope (Ala Valley). This disparity may be caused by different preservation- and micro-climatic conditions on the northern and southern slopes of this mountain range, due to differences in gradient and aspect. The LIA glacial advances are apparently the only Holocene glacial event recorded in this area. Earlier Holocene glacial events were probably so restricted in extent that they were destroyed by subsequent LIA advances.
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| 10. |
- Lifton, Nathaniel, et al.
(författare)
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Constraints on the late Quaternary glacial history of the Inylchek and Sary-Dzaz valleys from in situ cosmogenic Be-10 and Al-26, eastern Kyrgyz Tian Shan
- 2014
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Ingår i: Quaternary Science Reviews. - : Elsevier BV. - 0277-3791 .- 1873-457X. ; 101, s. 77-90
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Tidskriftsartikel (refereegranskat)abstract
- Paleoclimatic constraints from regions at the confluence of major climate systems are particularly important in understanding past climate change. Using geomorphic mapping based on remote sensing and field investigations, combined with in situ cosmogenic Be-10 and Al-26 dating of boulders associated with glacial landforms, we investigate the chronology of past glaciation in the Inylchek and Sary-Dzaz valleys in the eastern Kyrgyz Tian Shan, a tectonically active area with some of the highest peaks in the world outside of the Himalayas. Cosmogenic Be-10 and (26) Al exposure ages of boulders on moraines record up to five glacial advances including: Lateglacial age lateral moraine remnants and meltwater channels in the upper Inylchek Valley; Last Glacial Maximum (LGM, Marine Oxygen Isotope Stage [MIS] 2) moraines in the Sary-Dzaz Valley and in a terminal moraine complex at the west end of the Inylchek Valley, overriding older moraines; an MIS 4 or 5 moraine remnant above the Inylchek terminal moraine complex; and an older high moraine remnant down-valley from the confluence of the Inylchek and Sary-Dzaz valleys. The evidence for glacial extent in this study is consistent with a limited ice expansion hypothesis for Tian Shan glaciation. Published results from the western and central Kyrgyz Tian Shan do not show evidence for significant LGM glacier expansion, which in combination with the results presented here, indicate a spatial variation in glacier records along the Tian Shan. This may reflect either paleoclimatic gradients or the impact of local physiographic conditions on responses to regional climate change, or both.
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| 11. |
- Long, Yanan, et al.
(författare)
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Observable variations in human sex ratio at birth
- 2021
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Ingår i: PloS Computational Biology. - : Public Library of Science (PLoS). - 1553-734X .- 1553-7358. ; 17:12
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Tidskriftsartikel (refereegranskat)abstract
- The human sex ratio at birth (SRB), defined as the ratio between the number of newborn boys to the total number of newborns, is typically slightly greater than 1/2 (more boys than girls) and tends to vary across different geographical regions and time periods. In this large-scale study, we sought to validate previously-reported associations and test new hypotheses using statistical analysis of two very large datasets incorporating electronic medical records (EMRs). One of the datasets represents over half (∼ 150 million) of the US population for over 8 years (IBM Watson Health MarketScan insurance claims) while another covers the entire Swedish population (∼ 9 million) for over 30 years (the Swedish National Patient Register). After testing more than 100 hypotheses, we showed that neither dataset supported models in which the SRB changed seasonally or in response to variations in ambient temperature. However, increased levels of a diverse array of air and water pollutants, were associated with lower SRBs, including increased levels of industrial and agricultural activity, which served as proxies for water pollution. Moreover, some exogenous factors generally considered to be environmental toxins turned out to induce higher SRBs. Finally, we identified new factors with signals for either higher or lower SRBs. In all cases, the effect sizes were modest but highly statistically significant owing to the large sizes of the two datasets. We suggest that while it was unlikely that the associations have arisen from sex-specific selection mechanisms, they are still useful for the purpose of public health surveillance if they can be corroborated by empirical evidences.
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| 12. |
- Luo, Shijian, et al.
(författare)
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RoamFab : A Design Tool for Reconfiguring Parameterized Mechanisms to 3D Models With Structural Optimization
- 2023
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Ingår i: International Journal of Human-Computer Interaction. - : Informa UK Limited. - 1044-7318 .- 1532-7590. ; 39:19, s. 3702-3716
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Tidskriftsartikel (refereegranskat)abstract
- Creating personalized 3D printing objects has become increasingly popular with the advance in end-user modeling tools and fabrication techniques. However, it remains challenging for novice makers to design and fabricate functional objects with mechanical motion such as linear or rotational. To empower users to add mechanical movements to their models for particular needs, we first investigate the commonly used 3D printable mechanisms and parameterize four mechanical primitives. We then provide a computational approach to reconfigure the mechanical primitives to user-provided 3D models, with an underlying structural optimization procedure according to a specified bending force. We further showcase a set of design examples and conduct a user study to demonstrate the potential of our approach in creating personalized functional artifacts.
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| 13. |
- Shen, Qian, et al.
(författare)
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The Genome of Artemisia annua Provides Insight into the Evolution of Asteraceae Family and Artemisinin Biosynthesis
- 2018
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Ingår i: Molecular Plant. - : Cell Press. - 1674-2052 .- 1752-9867. ; 11:6, s. 776-788
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Tidskriftsartikel (refereegranskat)abstract
- Artemisia annua, commonly known as sweet wormwood or Qinghao, is a shrub native to China and has long been used for medicinal purposes. A. annua is now cultivated globally as the only natural source of a potent anti-malarial compound, artemisinin. Here, we report a high-quality draft assembly of the 1.74-gigabase genome of A. annua, which is highly heterozygous, rich in repetitive sequences, and contains 63 226 protein-coding genes, one of the largest numbers among the sequenced plant species. We found that, as one of a few sequenced genomes in the Asteraceae, the A. annua genome contains a large number of genes specific to this large angiosperm clade. Notably, the expansion and functional diversification of genes encoding enzymes involved in terpene biosynthesis are consistent with the evolution of the artemisinin biosynthetic pathway. We further revealed by transcriptome profiling that A. annua has evolved the sophisticated transcriptional regulatory networks underlying artemisinin biosynthesis. Based on comprehensive genomic and transcriptomic analyses we generated transgenic A. annua lines producing high levels of artemisinin, which are now ready for large-scale production and thereby will help meet the challenge of increasing global demand of artemisinin.
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| 14. |
- Wang, Jing, et al.
(författare)
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Impact of centennial-scale solar activity reduction on the weakened Asian monsoon event at 9.2 ka BP
- 2023
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Ingår i: Palaeogeography, Palaeoclimatology, Palaeoecology. - 0031-0182. ; 628
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Tidskriftsartikel (refereegranskat)abstract
- The weakened Asian monsoon event at 9.2 ka has been documented in many proxy-based reconstructions, but its underlying causes are uncertain. In this study, we investigated this event from a regional monsoon perspective by analysing simulations of Holocene transient solar activity forcing using the Community Earth System Model and high-resolution proxies. Our results revealed two separate periods of decreasing precipitation in the western North Pacific (WNP) and South Asian (SA) monsoons from 9.5 to 9.2 ka, each lagging behind two remarkable weakening events (0.38 and 0.21 W m−2) in solar forcing. However, there was no significant change in East Asian summer monsoon precipitation at 9.2 ka based on our experiment. Moisture budget analysis indicated that the dynamic effects term (i.e., anomalous descending motion) figured prominently in decreasing WNP and SA monsoon precipitation. Such a change was affected by an anomalous WNP anticyclone, which was maintained by the ‘wind-evaporation-sea surface temperature’ feedback during the decay phase of the centennial-scale El Niño-like event. The development of centennial El Niño-like conditions was caused by a reduction in solar irradiance. Reduced solar irradiance induced cooling over northern Australia, generating anomalous zonal sea level pressure gradients and westerlies over the tropical Pacific, ultimately resulting in the development of an El Niño-like pattern.
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| 15. |
- Wang, Yanan, et al.
(författare)
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SKIN+ : Fabricating Soft Fluidic User Interfaces for Enhancing On-Skin Experiences and Interactions
- 2018
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Ingår i: CHI EA '18, Extended Abstracts of the 2018 CHI Conference on Human Factors in Computing Systems. - New York, NY, USA : Association for Computing Machinery (ACM). - 9781450356213
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Konferensbidrag (refereegranskat)abstract
- Human skin is the largest organ on our body not only senses and external environment. A growing number of researchers devote themselves to design seamless interfaces directly on skin. In this late-breaking work, we propose a novel way for creating dynamic 2.5D skin textures, called SKIN+, a soft fluidic mini-scale user interface by introducing fluidic actuation. We have created four swatches with different pre-defined textures, topologies and structures to explore how this fluidic actuation system can benefit on-skin experiences and interactions. Our work details the intriguing experiences and interactions and future applications of on-skin wearables. Our work also extends the expressiveness, aesthetics and design space of soft fluidic interface as skin decoration and beauty technology.
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| 16. |
- Wei, Yanan, et al.
(författare)
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A universal method for constructing high efficiency organic solar cells with stacked structures
- 2021
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Ingår i: Energy & Environmental Science. - : ROYAL SOC CHEMISTRY. - 1754-5692 .- 1754-5706. ; 14:4, s. 2314-2321
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Tidskriftsartikel (refereegranskat)abstract
- The construction of organic solar cells with stacked structures by the sequential deposition (SD) of donor and acceptor films has great potential in industrial production, as it demonstrates little dependence on the ratio of donor and acceptor materials, solvents, and additives. Herein, we present an eco-friendly solvent protection (ESP) method for the fabrication of high-performance OSCs with stacked structures. Several non-aromatic and non-halogenated solvents are employed as protective agents to build SD devices with a configuration of indium tin oxide (ITO)/poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS Clevios P VP Al 4083)/donor/protective solvent/acceptor/perylene diimide functionalized with amino N-oxide (PDINO)/Al, which shows that n-octane is the optimal choice for SD devices. Nine different SD systems including the fullerene and nonfullerene ones present comparable photovoltaic performance to their BC counterparts, which proves the universality of this ESP method. Significantly, the device of ITO/PEDOT:PSS/D18/N3/PDINO/Al with n-octane as the protective solvent achieves a maximum PCE of 17.52%, which is the record efficiency of SD devices. Furthermore, a protective factor (delta) is proposed to demonstrate the quantitative relationship between delta and PCE after experimental and theoretical investigation, which presents an idea to understand the mechanism and provides a guideline for solvent choices.
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| 17. |
- Xiao, Tianxiao, et al.
(författare)
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Autonomous self-healing hybrid energy harvester based on the combination of triboelectric nanogenerator and quantum dot solar cell
- 2024
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Ingår i: Nano Energy. - : Elsevier BV. - 2211-2855 .- 2211-3282. ; 125
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Tidskriftsartikel (refereegranskat)abstract
- Realization of multi-source energy harvesting with one single device would maximize power output. Thus, it is emerging as a promising strategy towards renewable energy generation and has attracted worldwide attention in the past decades. Capable of capturing mechanical energy that is ubiquitous in the ambient environment, triboelectric nanogenerator (TENG) has been considered a novel yet effective source towards next-generation energy harvesting. In this work, a flexible hybrid energy harvester (HEH) is developed via the rational integration of autonomous self-healing TENG and high bending-stable lead sulfide quantum dot (PbS QD) solar cell, enabling independent electricity generation by two different mechanisms. The single-electrode mode TENG component with self-healing is realized by a polydimethylsiloxane/Triton X-100 (PDMS/TX100) mixture as the dielectric layer and the shared gold (Au) electrode, which generates 0.39 µA of output current (Iout), 24.6 V of output voltages (Vout), 15.4 nC of transfer charges (Qsc), and 7.80 mW m−2 of output power peak density. The thin-film solar cell component is based on a PbS QD layer as the light absorber with a planar structure fabricated under low-cost and compatible conditions, achieving 22.8 mA cm−2 of short-circuit current density (Jsc) and 4.92% of power conversion efficiency (PCE). As a proof of concept, an electronic watch is successfully powered by harnessing ambient mechanical and solar energy with a hybridized energy cell. This approach will offer more opportunities to construct a versatile platform towards remote monitoring and smart home systems.
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| 18. |
- Yao, Ya'nan, et al.
(författare)
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Highly efficient photocatalytic reduction of CO2 and H2O to CO and H-2 with a cobalt bipyridyl complex
- 2018
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Ingår i: Journal of Energy Challenges and Mechanics. - : ELSEVIER SCIENCE BV. - 2056-9386. ; 27:2, s. 502-506
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Tidskriftsartikel (refereegranskat)abstract
- The development of efficient molecular catalysts for visible-light driven CO2 reduction, based on abundant materials, is necessary to meet energy demands and address environment problems. In this work, a Co(bpy)(2)Cl-2 catalyst was developed and showed high efficiency and durability for the photocatalytic reduction of CO2 and protons. Yields of CO and H-2 as high as 62.3 and 69.9 mu mol were achieved and the turnover numbers (TONs) reached 6230 and 6990, respectively, under light irradiation (lambda > 420 nm) for 4 h, indicating that the mixture gases could be a candidate as syngas. The apparent quantum yield was determined to be 2.1% for CO. Mechanistic studies revealed oxidative quenching of the photosensitizer Ru(bpy)(3)Cl-2 by the catalyst. The photocatalytic performance, flexible synthesis and non-noble metal catalyst in our system show great promise for the practical application of Co(bpy)(2)Cl-2 to photocatalytic reduction of CO2.
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| 19. |
- Ye, Lu, et al.
(författare)
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Assembly of highly efficient photocatalytic CO2 conversion systems with ultrathin two-dimensional metal-organic framework nanosheets
- 2018
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Ingår i: Applied Catalysis B. - : ELSEVIER SCIENCE BV. - 0926-3373 .- 1873-3883. ; 227, s. 54-60
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Tidskriftsartikel (refereegranskat)abstract
- An ultrathin two-dimensional Zn porphyrin-based metal-organic framework (Zn-MOF nanosheets) is developed and used for the first time in photoreduction of CO2 to CO. Consequently, two novelty noble-metal-free hybrid photocatalytic systems are established and displayed outstanding photocatalytic activity and selectivity for CO evolution under mild photocatalytic reaction conditions. The insight revealed Zn-MOF nanosheets as photo sensitizer displays a better charge transport ability and longer lifetime of the photogenerated electron-hole pairs than the Zn-MOF bulk, which are confirmed by photoelectrochemical impedance and photoluminescence (PL) measurements. These studies show that the development of noble-metal-free photocatalytic systems and various MOF-based materials for photocatalytic applications are promising.
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| 20. |
- Zhang, Min, et al.
(författare)
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Multidimensional factors affecting care needs in daily living among community-dwelling older adults : A structural equation modelling approach
- 2021
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Ingår i: Journal of Nursing Management. - : John Wiley & Sons. - 0966-0429 .- 1365-2834. ; 29:5, s. 1207-1219
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Tidskriftsartikel (refereegranskat)abstract
- Aims: To develop a model illustrating the factors that can influence care needs in daily living (CNDL) of older adults and the pathways between these. Background: The care needs in community-dwelling older adults have increased sharply. A better understanding of the elderly's CNDL would thus help policymakers define which types of support and services should be given. Methods: A multicentre study with structural equation modelling was conducted in this study. We recruited 3,448 community-dwelling older adults in China by using a stratified random cluster sampling technique. Results: Physical and mental health was the strongest predictor of CNDL. Both age and living situation had positive effects on CNDL, while economic factors, social support and family support were the major risk factors for CNDL. Conclusion: The presented model provides a better understanding of how to address CNDL in the targeted population. The older adults who are the oldest, low-income, non-empty nesters, and with poor self-rated health or the signs of loneliness should be firstly targeted for daily assistance. Implications for Nursing Management: Using this model could provide health authorities and managers with the information of distinguishing between the priority group and the strategies for easing the caregiving burden in older adults care, and thus improving resource utilization.
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| 21. |
- Zhang, Xin, et al.
(författare)
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High-Performance All-Small-Molecule Organic Solar Cells Enabled by Regio-Isomerization of Noncovalently Conformational Locks
- 2022
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Ingår i: Advanced Functional Materials. - : WILEY-V C H VERLAG GMBH. - 1616-301X .- 1616-3028. ; 32:19
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Tidskriftsartikel (refereegranskat)abstract
- The power conversion efficiencies (PCEs) of organic solar cells (OSCs) have surpassed 19% thanks to the innovation of polymer donors and molecular acceptors. However, the batch-to-batch variations in polymer materials are detrimental to the reproducibility of the device performance. In comparison, small-molecule donors (SMDs) possess some unique advantages, such as well-defined molecular weights, easy purification, and excellent batch-to-batch repeatability. Herein, a pair of regioisomeric SMDs (BT-O1 and BT-O2) has been synthesized with alkoxy groups as S center dot center dot center dot O noncovalently conformational locks (NoCLs) at the inner and outer position, respectively. Theoretical and experimental results reveal that the regioisomeric effect has a significant influence on the light-harvest ability, energy levels, molecular geometries, internal reorganization energy, and packing behaviors for the two SMDs. As a result, BT-O2-based binary device shows an impressive PCE of 13.99%, much higher than that of BT-O1 based one (4.07%), due to the better-aligned energy level, more balanced charge transport, less charge recombination, lower energy loss, and more favorable phase separation. Furthermore, the fullerene derivative PC71BM is introduced into BT-O2:H3 as the third component to achieve a notable PCE of 15.34% (certified 14.6%). Overall, this work reveals that NoCLs is a promising strategy to achieve high-performance SMDs for all-small-molecule OSCs.
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| 22. |
- Zhang, Xin, et al.
(författare)
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Side-Chain Engineering for Enhancing the Molecular Rigidity and Photovoltaic Performance of Noncovalently Fused-Ring Electron Acceptors
- 2021
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Ingår i: Angewandte Chemie International Edition. - : WILEY-V C H VERLAG GMBH. - 1433-7851 .- 1521-3773. ; 60:32, s. 17720-17725
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Tidskriftsartikel (refereegranskat)abstract
- Side-chain engineering is an effective strategy to regulate the solubility and packing behavior of organic materials. Recently, a unique strategy, so-called terminal side-chain (T-SC) engineering, has attracted much attention in the field of organic solar cells (OSCs), but there is a lack of deep understanding of the mechanism. Herein, a new noncovalently fused-ring electron acceptor (NFREA) containing two T-SCs (NoCA-5) was designed and synthesized. Introduction of T-SCs can enhance molecular rigidity and intermolecular pi-pi stacking, which is confirmed by the smaller Stokes shift value, lower reorganization free energy, and shorter pi-pi stacking distance in comparison to NoCA-1. Hence, the NoCA-5-based device exhibits a record power conversion efficiency (PCE) of 14.82 % in labs and a certified PCE of 14.5 %, resulting from a high electron mobility, a short charge-extraction time, a small Urbach energy (E-u), and a favorable phase separation.
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