1. |
- Buyanova, Irina A, et al.
(författare)
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Effects of Ga doping on optical and structural properties of ZnO epilayers
- 2009
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Ingår i: Superlattices and Microstructures. - : Elsevier BV. - 0749-6036 .- 1096-3677. ; 45:4-5, s. 413-420
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Tidskriftsartikel (refereegranskat)abstract
- Effects of Ga incorporation on electrical, structural and optical properties of ZnO epilayers are systematically studied by employing structural and optical characterization techniques combined with electrical and secondary ion mass spectrometry measurements. A non-monotonous dependence of free electron concentrations on Ga content is observed and is attributed to defect formation and phase separation. The former process is found to dominate for Ga concentrations of around 2-3x1020 cm-3. corresponding defects are suggested to be responsible for a broad red emission, which peaks at around 1.8 eV at K. Characteristic properties of this emission are well accounted for by assuming intracenter transitions at a deep center, of which the associated Huang-Rhys factor and mean phonon energy are determined. For higher Ga doping levels, the phase separation is found to be significant. It is that under these conditions only a minor fraction of incorporated Ga atoms form shallow donors, which leads to the observed dramatic decrease of carrier concentration.
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2. |
- Lim, W., et al.
(författare)
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Migration and Luminescence Enhancement Effects of Deuterium in ZnO/ZnCdO Quantum Wells
- 2008
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 92, s. 032103-
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Tidskriftsartikel (refereegranskat)abstract
- ZnO/ZnCdO/ZnO multiple quantum well samples grown on sapphire substrates by molecular beam epitaxy and annealed in situ were exposed to D2 plasmas at 150 °C. The deuterium showed migration depths of ~0.8 µm for 30 min plasma exposures, with accumulation of 2H in the ZnCdO wells. The photoluminescence (PL) intensity from the samples was increased by factors of 5 at 5 K and ~20 at 300 K as a result of the deuteration, most likely due to passivation of competing nonradiative centers. Annealing up to 300 °C led to increased migration of 2H toward the substrate but no loss of deuterium from the sample and little change in the PL intensity. The initial PL intensities were restored by annealing at >=400 °C as 2H was evolved from the sample (~90% loss by 500 °C). By contrast, samples without in situ annealing showed a decrease in PL intensity with deuteration. This suggests that even moderate annealing temperatures lead to degradation of ZnCdO quantum wells.
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3. |
- Luo, Ziyu, et al.
(författare)
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An Efficient Deep-Subwavelength Second Harmonic Nanoantenna Based on Surface Plasmon-Coupled Dilute Nitride GaNP Nanowires
- 2021
-
Ingår i: Nano Letters. - : AMER CHEMICAL SOC. - 1530-6984 .- 1530-6992. ; 21:8, s. 3426-3434
-
Tidskriftsartikel (refereegranskat)abstract
- High-index semiconductor nanoantennae represent a powerful platform for nonlinear photon generation. Devices with reduced footprints are pivotal for higher integration capacity and energy efficiency in photonic integrated circuitry (PIC). Here, we report on a deep subwavelength nonlinear antenna based on dilute nitride GaNP nanowires (NWs), whose second harmonic generation (SHG) shows a 5-fold increase by incorporating similar to 0.45% of nitrogen (N), in comparison with GaP counterpart. Further integrating with a gold (Au) thin film-based hybrid cavity achieves a significantly boosted SHG output by a factor of similar to 380, with a nonlinear conversion efficiency up to 9.4 x 10(-6) W-1. In addition, high-density zinc blende (ZB) twin phases were found to tailor the nonlinear radiation profile via dipolar interference, resulting in a highly symmetric polarimetric pattern well-suited for coupling with polarization nano-optics. Our results manifest dilute nitride nanoantenna as promising building blocks for future chip-based nonlinear photonic technology.
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4. |
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5. |
- Buyanova, Irina, 1960-, et al.
(författare)
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Effects of hydrogen on the optical properties of ZnCdO/ZnO quantum wells grown by molecular beam epitaxy
- 2008
-
Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 92, s. 261912-
-
Tidskriftsartikel (refereegranskat)abstract
- Temperature-dependent cw- and time-resolved photoluminescence (PL), as well as optically detected magnetic resonance (ODMR) measurements are employed to evaluate effects of deuterium (2H) doping on optical properties of ZnCdO/ZnO quantum well structures grown by molecular beam epitaxy. It is shown that incorporation of 2H from a remote plasma causes a substantial improvement in radiative efficiency of the investigated structures. Based on transient PL measurements, the observed improvements are attributed to efficient passivation by hydrogen of competing nonradiative recombination centers via defects. This conclusion is confirmed from the ODMR studies.
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6. |
- Buyanova, Irina, 1960-, et al.
(författare)
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Optical characterization of Zn(1-x)Cd(x)O alloys grown by molecular-beam epitaxy
- 2006
-
Ingår i: 210th ECS Meeting Volume 3, Issue 5. - : The Electrochemical Society. ; , s. 391-398
-
Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- We have carried out comprehensive optical studies to evaluate structural and bandgap properties of Zn1-xCdxO alloys with x{less than or equalto}0.17 grown by molecular beam epitaxy. High crystalline quality ofthe alloys was concluded from cathodoluminescence measurements. Based on absorptionand reflectance measurements, the compositional dependence of the bandgap energyof ZnCdO, estimated without taking into account excitonic effects, wasfound to follow the trend Eg(x)=3.28-2.23x+0.45x2. Degradation in the alloyquality due to possible phase separation was found to causedeviations from this trend, evident from a more rapid redshift of the absorption edge. Effects of Cd incorporation onthe variation of the bandgap energies with temperature are alsodiscussed.
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7. |
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8. |
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9. |
- Dagnelund, Daniel, 1980-, et al.
(författare)
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Effect of growth conditions on grown-in defect formation and luminescence efficiency in GaInNP epilayers grown by molecular-beam epitaxy.
- 2008
-
Ingår i: Physica status solidi (c)Special Issue: E-MRS 2007 Spring Meeting – Symposium F and Conference on Photonic Materials. - Weinheim : Wiley-VCH Verlagsgesellschaft. ; , s. 460-463
-
Konferensbidrag (refereegranskat)abstract
- A detailed study of the impact of different growth conditions (i.e. ion bombardment, nitrogen flow and In content) on the defect formation in Ga(In)NP epilayers grown on GaP substrates by solid-source molecular beam epitaxy is performed. Reduced nitrogen ion bombardment during the growth is shown to significantly reduce formation of defects acting as competing recombination centers, such as a Ga interstitial defect and other unidentified defects revealed by optically detected magnetic resonance. Further, high nitrogen flow is found to be even more effective than the ion bombardment in introducing the defects. The incorporation of In by 5.1% is, on the other hand, found not to affect the introduction of defects. The results provide a useful insight into the formation mechanism of the defects that will hopefully shed light on a control of the defect introduction in the alloys by optimizing growth conditions.
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10. |
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11. |
- Dagnelund, Daniel, et al.
(författare)
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Effect of postgrowth hydrogen treatment on defects in GaNP
- 2011
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Ingår i: APPLIED PHYSICS LETTERS. - : American Institute of Physics. - 0003-6951 .- 1077-3118. ; 98:14, s. 141920-
-
Tidskriftsartikel (refereegranskat)abstract
- Effect of postgrowth hydrogen treatment on defects and their role in carrier recombination in GaNP alloys is examined by photoluminescence (PL) and optically detected magnetic resonance. We present direct experimental evidence for effective activation of several defects by low-energy subthreshold hydrogen treatment (andlt;= 100 eV H ions). Among them, two defect complexes are identified to contain a Ga interstitial. Possible mechanisms for the H-induced defect activation and creation are discussed. Carrier recombination via these defects is shown to efficiently compete with the near band-edge PL, explaining the observed degraded optical quality of the alloys after the H treatment.
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12. |
- Dagnelund, Daniel, 1980-, et al.
(författare)
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Formation of grown-in defects in molecular beam epitaxial Ga(In)NP : effects of growth conditions and post-growth treatments
- 2008
-
Ingår i: Journal of Applied Physics. - : AIP Publishing. - 0021-8979 .- 1089-7550. ; 103, s. 063519-
-
Tidskriftsartikel (refereegranskat)abstract
- Effects of growth conditions and post-growth treatments, such as presence of N ions, N2 flow, growth temperature, In alloying, and postgrowth rapid thermal annealing (RTA), on formation of grown-in defects in Ga(In)NP prepared by molecular beam epitaxy are studied in detail by the optically detected magnetic resonance (ODMR) technique. Several common residual defects, such as two Ga-interstitial defects (i.e., Gai-A and Gai-B) and two unidentified defects with a g factor around 2 (denoted by S1 and S2), are closely monitored. Bombardment of impinging N ions on grown sample surface is found to facilitate formation of these defects. Higher N2 flow is shown to have an even more profound effect than a higher number of ions in introducing these defects. Incorporation of a small amount of In (e.g., 5.1%) in GaNP seems to play a minor role in the formation of the defects. In GaInNP with 45% of In; however, the defects were found to be abundant. Effect of RTA on the defects is found to depend on initial configurations of Gai-related defects formed during the growth. In the alloys where the Gai-A and Gai-B defects are absent in the as-grown samples (i.e., GaNP grown at a low temperature of 460 °C), the concentrations of the two Gai defects are found to increase after postgrowth RTA. This indicates that the defects originally introduced in the as-grown alloys have been transformed into the more thermally stable Gai-A and Gai-B during RTA. On the other hand, when the Gai-A and Gai-B are readily abundant (e.g., at higher growth temperatures (>=500 °C), RTA leads to a slight reduction of the Gai-A and Gai-B ODMR signals. The S2 defect is also shown to be thermally stable upon the RTA treatment.
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13. |
- Dagnelund, Daniel, 1980-, et al.
(författare)
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Optically detected cyclotron resonance studies of InxGa1-xNyAs1-y/GaAs quantum wells sandwiched between type-II AlAs/GaAs superlattices.
- 2007
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Ingår i: Journal of Applied Physics. - : AIP Publishing. - 0021-8979 .- 1089-7550. ; 101, s. 073705-
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Tidskriftsartikel (refereegranskat)abstract
- We report on our results from a systematic study of layered structures containing an InGaNAs/GaAs single quantum well (SQW) enclosed between staggered type II AlAs/GaAs superlattices (SL), by the photoluminescence (PL) and optically detected cyclotron resonance (ODCR) techniques. Besides the ODCR signal known to originate from electrons in GaAs, the predominant ODCR peak is shown to be related to carriers with a two-dimensional character and a cyclotron resonance effective mass of m*[approximate](0.51-0.56)m0. The responsible carriers are ascribed to electrons on the ellipsoidal equienergy surface at the AlAs X point of the Brillouin zone within the SL, based on results from angular and spectral dependences of the ODCR signal. No ODCR signal related to the InGaNAs SQW was detected, presumably due to low carrier mobility despite the high optical quality. Multiple absorption of photons with energy below the band gap energy of the SL and the GaAs barriers was observed, which bears implication on the efficiency of light-emitting devices based on these structures.
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14. |
- Dagnelund, Daniel, et al.
(författare)
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Phosphorus-related interfacial defect complex at a GaP/GaNP heterojunction
- 2010
-
Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- For full exploration of dilute nitrides in device applications, a better understanding and control of defects located at interfaces involving e.g. Ga(In)NP are required. In this work we report on the first identification of a point defect situated at an interface between two semiconductors: GaNP and GaP. The defect is concluded to be a complex involving a P antisite or a P interstitial in its core, partnered with a neighboring impurity/defect aligned along a <111> direction, from detailed angular dependence studies of the optically detected magnetic resonance (ODMR) spectra at both X- and Q-band microwave frequencies. The principal g and A values, g┴=2.013, g║=2.002, A┴=130x10-4 cm-1 and A║=330x10-4 cm-1, are obtained from a spin Hamiltonian analysis. The interface nature of the defect is clearly evident from the absence of the ODMR lines originating from two out of four equivalent <111> orientations. Defect formation is shown to be facilitated by severe nitrogen ion bombardment under non-equilibrium growth conditions during solid-source molecular beam epitaxy and the defect is thermally stable upon post-growth thermal annealing.
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15. |
- Dagnelund, Daniel, 1980-, et al.
(författare)
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Spin resonance spectroscopy of grown-in defects in Ga(In)NP alloys
- 2008
-
Ingår i: 7th International Conference on Physics of Light-Matter Coupling in Nanostructures, 2007. - : Elsevier Ltd.. ; , s. 620-625
-
Konferensbidrag (refereegranskat)abstract
- We employ the optically detected magnetic resonance (ODMR) technique to study and identify important grown-in defects in Ga(In)NP grown by molecular-beam epitaxy (MBE). Several types of defects were revealed from ODMR studies. The dominant defects were found to be related to Ga interstitials, evident form their characteristic hyperfine interaction arising from the spin interaction between the electron and the Ga nucleus. Some other as yet unidentified intrinsic defects were also found to be commonly present in the alloys. The effects of growth conditions (ion bombardment, N2 gas flow, etc.) and post-growth rapid thermal annealing on the formation of these defects were studied in detail, shedding light on the formation mechanism of defects.
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16. |
- Lei, Ming, et al.
(författare)
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Double deep Q-learning network-based path planning in UAV-assisted wireless powered NOMA communication networks
- 2021
-
Ingår i: 2021 IEEE 94TH VEHICULAR TECHNOLOGY CONFERENCE (VTC2021-FALL). - : Institute of Electrical and Electronics Engineers (IEEE). - 9781665413688 - 9781665413695 ; , s. 1-5
-
Konferensbidrag (refereegranskat)abstract
- This paper studies an unmanned aerial vehicle (UAV)-enabled wireless power communication networks (WPCN-s), where the UAV provides energy for mobile user nodes (M-UNs) and receives information from M-UNs. The movement of M-UN complies with a Gauss-Markov random model. To ensure acceptable quality-of-service (QoS), we consider dynamically planning the flight path of the UAV according to the movements of M-UNs. Since the flight time of UAV is restricted by limited energy, nonorthogonal multiple access (NOMA) is adopted to access a large number of M-UNs for simultaneous information transmission. Based on the above considerations, we aim to maximize the throughput via path planning of the UAV, subject to the QoS requirements of M-UNs and the UAV's energy constraint. To handle the challenges brought by dynamically changing channels to solving the problem, we propose a QoS-based double deep Q-learning network (DDQN). Numerical simulation results show that, compared with the conventional algorithms, the proposed framework achieves higher throughput.
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17. |
- Lei, Ming, et al.
(författare)
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Joint power control and user scheduling for backbone-assisted industrial wireless networks with successive interference cancellation
- 2022
-
Ingår i: Telecommunications Systems. - : SPRINGER. - 1018-4864 .- 1572-9451. ; 81:1, s. 41-52
-
Tidskriftsartikel (refereegranskat)abstract
- In a backbone-assisted industrial wireless network (BAIWN), the technology of successive interference cancellation (SIC) based non-orthogonal multiple access (NOMA) provides potential solutions for improving the delay performance. Previous work emphasizes minimizing the transmission delay by user scheduling without considering power control. However, power control is beneficial for SIC-based NOMA to exploit the power domain and manage co-channel interference to simultaneously serve multiple user nodes with the high spectral and time resource utilization characteristics. In this paper, we consider joint power control and user scheduling to study the scheduling time minimization problem (STMP) with given traffic demands in BAIWNs. Specifically, STMP is formulated as an integer programming problem, which is NP-hard. To tackle the NP-hard problem, we propose a conflict graph-based greedy algorithm, to obtain a sub-optimal solution with low complexity. As a good feature, the decisions of power control and user scheduling can be made by the proposed algorithm only according to the channel state information and traffic demands. The experimental results show that compared with the other methods, the proposed method effectively improves the delay performance regardless of the channel states or the network scales.
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18. |
- Puttisong, Yuttapoom, et al.
(författare)
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Defect-enabled Room-temperature Spin Functionality in Ga(In)NAs
- 2012
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- Efficient generation, maintaining, manipulation and detection of electron spin polarization and coherence at room-temperature (RT) in semiconductors is a prerequisite for the success of future semiconductor spintronics. Potential spintronic devices are expected to be based on fundamental building blocks such as spin filters (or spin injectors or spin aligners), spin amplifiers and spin detectors. During the past decade spin filters and spin detectors have been a main focal point of intense research efforts in the field of semiconductor spintronics that have led to many innovative approaches and encouraging developments. In contrast, experimental developments in spin amplifiers have been extremely limited. At present, realization of efficient RT spin functionality remains to be a great challenge and a hotly pursued research topic.In this work, we explore a new and unconventional approach of defect-enabled spin functionality in a non-magnetic semiconductor without requiring a magnetic layer or external magnetic fields. We demonstrated efficient defect-engineered spin filtering in Ga(In)NAs, which is capable of generating a remarkably high spin polarization degree (> 40%) of conduction electrons at RT. The highest spin polarization achieved to date by using this approach is up to 90 %. We also proposed a conceptually new spin amplifier by defect engineering and provided the first experimental demonstration of an efficient RT spin amplifier based on Ga(In)NAs with a spin gain up to 2700%! Such a spin amplifier is shown to be capable of amplifying a fast-modulating input spin signal while truthfully maintaining its time variation of the spin-encoded information, and is predicted to remain functional up to 1 GHz. By taking advantage of the spin amplification effect, we further showed that Ga(In)NAs can be employed as an efficient RT spin detector, with spin detection efficiency well exceeding 100%. Applications of such a spin-functional semiconductor material could potentially provide an attractive and viable solution to the current and important issues on RT spin injection, spin amplification and spin detection in semiconductors for future spintronics.
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19. |
- Puttisong, Yuttapoom, et al.
(författare)
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Electron spin filtering by thin GaNAs/GaAs multiquantum wells
- 2010
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 96:5, s. 052104-
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Tidskriftsartikel (refereegranskat)abstract
- Effectiveness of the recently discovered defect-engineered spin-filtering effect is closely examined in GaNAs/GaAs multiquantum wells (QWs) as a function of QW width. In spite of narrow well widths of 3-9 nm, rather efficient spin filtering is achieved at room temperature. It leads to electron spin polarization larger than 18% and an increase in photoluminescence intensity by 65% in the 9 nm wide QWs. A weaker spin filtering effect is observed in the narrower QWs, mainly due to a reduced sheet concentration of spin-filtering defects (e.g., Ga-i interstitial defects).
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20. |
- Puttisong, Yuttapoom, et al.
(författare)
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Room-temperature spin injection and spin loss across a GaNAs/GaAs interface
- 2011
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Ingår i: Applied Physics Letters. - : American Institute of Physics. - 0003-6951 .- 1077-3118. ; 98:1, s. 012112-
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Tidskriftsartikel (refereegranskat)abstract
- Recently discovered effect of spin-filtering and spin amplification in GaNAs enables us to reliably obtain detailed information on the degree of spin loss during optical spin injection across a semiconductor heterointerface at room temperature. Spin polarization of electrons injected from GaAs into GaNAs is found to be less than half of what is generated in GaNAs by optical orientation. We show that the observed reduced spin injection efficiency is not only due to spin relaxation in GaAs, but more importantly due to spin loss across the interface due to structural inversion asymmetry and probably also interfacial point defects.
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21. |
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22. |
- Stehr, Jan Eric, et al.
(författare)
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Defects in N, O and N, Zn implanted ZnO bulk crystals
- 2013
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Ingår i: Journal of Applied Physics. - : American Institute of Physics (AIP). - 0021-8979 .- 1089-7550. ; 113:10, s. 103509-
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Tidskriftsartikel (refereegranskat)abstract
- Comprehensive characterization of defects formed in bulk ZnO single crystals co-implanted with N and Zn as well as N and O atoms is performed by means of optically detected magnetic resonance (ODMR) complemented by Raman and photoluminescence (PL) spectroscopies. It is shown that in addition to intrinsic defects such as Zn vacancies and Zn interstitials, several N-related defects are formed in the implanted ZnO. The prevailed configuration of the defects is found to depend on the choices of the co-implants and also the chosen annealing ambient. Specifically, co-implantation with O leads to the formation of (i) defects responsible for local vibrational modes at 277, 511, and 581 cm−1; (ii) a N-related acceptor with the binding energy of 160 ± 40 meV that is involved in the donor-acceptor pair emission at 3.23 eV; and (iii) a deep donor and a deep NO acceptor revealed from ODMR. Activation of the latter defects is found to require post-implantation annealing in nitrogen ambient. None of these defects are detected when N is co-implanted with Zn. Under these conditions, the dominant N-induced defects include a deep center responsible for the 3.3128 eV PL line, as well as an acceptor center of unknown origin revealed by ODMR. Formation mechanisms of the studied defects and their role in carrier recombination are discussed.
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23. |
- Tian, Chen, et al.
(författare)
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Functional Failure Behavior of Submerged Entry Nozzle during the Continuous Casting Process of the Bearing Steel GCr15
- 2024
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Ingår i: Steel Research International. - : John Wiley & Sons. - 1611-3683 .- 1869-344X. ; 95:8
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Tidskriftsartikel (refereegranskat)abstract
- The submerged entry nozzle (SEN) is an indispensable functional structural ceramic in the current continuous casting production. The stability and safety of the SEN is very important during the casting process. In this article, the functional failure of the SEN during the continuous casting process of the bearing steel GCr15 is studied. The results show that the functional failure of the SEN during the bearing steel GCr15 casting process is caused by the clogging inside the SEN which is led by the low cleanliness and the high impurities n the molten steel. The clogging in the SEN can be divided into solidified steel area, loose area, dense area, and surface area. To improve the castability of bearing steel or other high-cleanliness steel, it is necessary to strengthen the refining process and treatment effect, strengthen the sealing and the effect of the protective casting of the molten steel, and moderate optimization of nozzle materials or the application of external fields on the SEN.
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24. |
- Wang, Xingjun, 1972-, et al.
(författare)
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Band gap properties of Zn1−xCdxO alloys grown by molecular-beam epitaxy
- 2006
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 89, s. 151909-
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Tidskriftsartikel (refereegranskat)abstract
- Optical absorption and reflectance measurements are performed to evaluate compositional and temperature dependences of band gap energies of Zn1−xCdxO alloys grown by molecular-beam epitaxy. The compositional dependence of the band gap energy, determined by taking into account excitonic contributions, is shown to follow the trend Eg(x) = 3.37−2.82x+0.95x2. Incorporation of Cd was also shown to somewhat slow down thermal variation of the band gap energies, beneficial for future device applications.
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25. |
- Wang, Xingjun, et al.
(författare)
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Dominant recombination centers in Ga(In)NAs alloys: Ga interstitials
- 2009
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Ingår i: Applied Physics Letters. - : American Institute of Physics. - 0003-6951 .- 1077-3118. ; 95, s. 241904-
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Tidskriftsartikel (refereegranskat)abstract
- Opticallydetected magnetic resonance measurements are carried out to study formationof Ga interstitial-related defects in Ga(In)NAs alloys. The defects, whichare among dominant nonradiative recombination centers that control carrier lifetimein Ga(In)NAs, are unambiguously proven to be common grown-in defectsin these alloys independent of the employed growth methods. Thedefects formation is suggested to become thermodynamically favorable because ofthe presence of nitrogen, possibly due to local strain compensation.
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26. |
- Wang, Xingjun, 1972-, et al.
(författare)
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Effects of grown-in defects on electron spin polarization in dilute nitride alloys
- 2008
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Ingår i: 7th International Conference on Nitride Semiconductors ICNS-7,2007. - phys. stat. sol. (c) vol. 5 : WILEYVCH Verlag GmbH & Co. KGaA, Weinheim. ; , s. 1529-
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Konferensbidrag (refereegranskat)abstract
- Strong electron spin polarization in GaNAs epilayers and multiple quantum well structures is observed upon optical orientation at room temperature. The effect is explained in terms of spin dependent recombination (SDR) involving deep paramagnetic defects formed upon N incorporation in GaNAs. Concentration of the corresponding defects is shown to be enhanced during growth at low temperatures but is suppressed by post-growth annealing. Optically detected magnetic resonance (ODMR) measurements performed in the studied structures reveal two paramagnetic defects participating in carrier recombination. One of them is identified as a complex involving AsGa antisite. Correlation between concentrations of the defects monitored via ODMR and in optical orientation measurements is observed which suggests that the same defects may be involved in both processes.
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27. |
- Wang, Xingjun, et al.
(författare)
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Effects of P implantation and post-implantation annealing on defect formation in ZnO
- 2012
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Ingår i: Journal of Applied Physics. - : American Institute of Physics (AIP). - 0021-8979 .- 1089-7550. ; 111:4, s. 043520-
-
Tidskriftsartikel (refereegranskat)abstract
- Photoluminescence (PL) and optically detected magnetic resonance (ODMR) techniques are utilized to examine the effects of P implantation and post-implantation annealing on defect formation in ZnO single crystals. From ODMR, the main defects created by ion implantation include oxygen and zinc vacancies as a well as a deep donor labeled as PD. The formation of the PD defect is likely promoted by the presence of P as it could only be detected in the P-containing ZnO. The V-O and PD centers are found to exhibit low thermal stability and can be annealed out at 800 degrees C. On the other hand, a new set of defects, such as Z, T, and D* centers, is detected after annealing. Based on measured spectral dependences of the ODMR signals, the V-O, V-Zn, and PD centers are shown to participate in spin-dependent recombination processes related to red emissions, whereas the Z, T, and D* centers are involved in radiative recombination over a wide spectral range of 1.55-2.5 eV. From the PL measurements, combined effects of implantation and annealing also lead to appearance of a new PL band peaking at similar to 3.156 eV, likely due to donor-acceptor-pair recombination. The formation of the involved deep acceptor is concluded to be facilitated by the presence of P.
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28. |
- Wang, Xingjun, 1972-, et al.
(författare)
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Effects of stoichiometry on defect formation in ZnO epilayers grown by molecular-beam epitaxy : An optically detected magnetic resonance study
- 2008
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Ingår i: Journal of Applied Physics. - : AIP Publishing. - 0021-8979 .- 1089-7550. ; 103:2, s. 023712-
-
Tidskriftsartikel (refereegranskat)abstract
- Photoluminescence (PL) and optically detected magnetic resonance are employed to study effects of nonstoichiometry during the growth on defect formation in ZnO epilayers grown by molecular-beam epitaxy (MBE). Several defects are revealed via monitoring the yellow PL emission (∼2.17 eV) and their magnetic resonance signatures are obtained. The defects are concluded to be common for the MBE growth and are facilitated during the off-stoichiometric growth conditions, especially under excess of oxygen. © 2008 American Institute of Physics.
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29. |
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30. |
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31. |
- Wang, Xingjun, et al.
(författare)
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Efficient Spin Filter Based on Non-Magnetic Semiconductor GaNAs
- 2009
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Ingår i: Integrated Photonics and Nanophotonics Research and Applications/Nonlinear Optics/Slow and Fast Light. - 9781557528735 ; , s. IWD4-
-
Konferensbidrag (refereegranskat)abstract
- We provide experimental demonstration of a novel defect-engineered, efficient and switchable spin filter from GaNAs to generate, amplify and detect electron spin polarization at room temperature without a magnetic material or external magnetic fields.
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32. |
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33. |
- Wang, Xingjun, 1972-, et al.
(författare)
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Generating strong electron spin polarization at room temperature in GaNAs via spin-dependent recombination
- 2008
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Ingår i: 5th International Conference on Physics and Applications of Spin-related Phenomena in Semiconductors PASPS V,2008.
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)abstract
- The issues of generating and maintaining carrier spin polarization in semiconductors have attracted intense research efforts, not only due to their importance for future applications in spintronics but also due to the intriguing physics underpinning spin-dependent phenomena. Entering the family of semiconductors that exhibit attractive spin-dependent properties, Ga(In)NAs was most recently found to exhibit strong spin polarization of conducting electrons at room temperature upon N incorporation with an extremely long apparent spin lifetime. In this work we have uncovered the origin of the astonishing effect as being due to strong spin dependent recombination (SDR) via defects, by a combination of optical orientation and optically detected magnetic resonance (ODMR) studies. We were able to identify Ga self-interstitials and an As antisite complex to be the dominant defects participating in the SDR process. The involvement of these defects were unambiguously established by their unique spin-resonance signatures derived from the hyperfine interaction between the localized unpaired electron spin and nuclear spins (I=3/2) of the As and Ga atom - the core of the defects. These defects dominate in carrier capture and recombination leading to the observed strong dynamic polarization of electron spins. Further confirmation was found by the effects of growth conditions and post-growth treatments on the defect density that were closely correlated with the electron spin polarization.
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34. |
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35. |
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36. |
- Wang, Xingjun, et al.
(författare)
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Oxygen and zinc vacancies in as-grown ZnO single crystals
- 2009
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Ingår i: JOURNAL OF PHYSICS D-APPLIED PHYSICS. - : IOP Publishing. - 0022-3727 .- 1361-6463. ; 42:17, s. 175411-
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Tidskriftsartikel (refereegranskat)abstract
- Oxygen and zinc vacancies are unambiguously shown to be formed in as-grown ZnO bulk crystals grown from melt without being subjected to irradiation, from electron paramagnetic resonance (EPR) and optically detected magnetic resonance (ODMR) studies. Concentrations of the defects in their paramagnetic charge states V-O(+) and V-Zn(-) are estimated to be similar to 2 x 10(14) cm(-3) and similar to 10(15) cm(-3), respectively. The V-Zn(-) defect is concluded to act as a deep acceptor and to exhibit large Jahn-Teller distortion by 0.8 eV. The energy level of the defect corresponding to the (2-/-) transition is E-v + 1.0 eV. The isolated Zn vacancy is found to be an important recombination centre and is concluded to be responsible for the red luminescence centred at around 1.6 eV. On the other hand, the oxygen vacancy seems to be less important in carrier recombination as it could be detected only in EPR but not in ODMR measurements. Neither isolated V-Zn(-) nor V-O(+) centres participate in the so-called green emission. It is also shown that whereas the concentrations of both defects can be reduced by post-growth annealing, the Zn vacancy exhibits higher thermal stability. The important role of residual contaminants such as Li in the annealing process is underlined.
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37. |
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38. |
- Wang, Xingjun, et al.
(författare)
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Room-temperature defect-engineered spin filter based on a non-magnetic semiconductor.
- 2009
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Ingår i: Nature Materials. - : Springer Science and Business Media LLC. - 1476-1122 .- 1476-4660. ; 8:3, s. 198-202
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Tidskriftsartikel (refereegranskat)abstract
- Generating, manipulating and detecting electron spin polarization and coherence at room temperature is at the heart of future spintronics and spin-based quantum information technology. Spin filtering, which is a key issue for spintronic applications, has been demonstrated by using ferromagnetic metals, diluted magnetic semiconductors, quantum point contacts, quantum dots, carbon nanotubes, multiferroics and so on. This filtering effect was so far restricted to a limited efficiency and primarily at low temperatures or under a magnetic field. Here, we provide direct and unambiguous experimental proof that an electron-spin-polarized defect, such as a Ga(i) self-interstitial in dilute nitride GaNAs, can effectively deplete conduction electrons with an opposite spin orientation and can thus turn the non-magnetic semiconductor into an efficient spin filter operating at room temperature and zero magnetic field. This work shows the potential of such defect-engineered, switchable spin filters as an attractive alternative to generate, amplify and detect electron spin polarization at room temperature without a magnetic material or external magnetic fields.
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39. |
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40. |
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41. |
- Zhang, Bin, et al.
(författare)
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Anomalously Strong Second‐Harmonic Generation in GaAs Nanowires via Crystal‐Structure Engineering
- 2021
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Ingår i: Advanced Functional Materials. - Weinheim, Germany : Wiley-V C H Verlag GMBH. - 1616-301X .- 1616-3028. ; 31:36
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Tidskriftsartikel (refereegranskat)abstract
- GaAs-based semiconductors are highly attractive for diverse nonlinear photonic applications, owing to their non-centrosymmetric crystal structure and huge nonlinear optical coefficients. Nanostructured semiconductors, for example, nanowires (NWs), offer rich possibilities to tailor nonlinear optical properties and further enhance photonic device performance. In this study, it is demonstrated highly efficient second-harmonic generation in subwavelength wurtzite (WZ) GaAs NWs, reaching 2.5 × 10−5 W−1, which is about seven times higher than their zincblende counterpart. This enhancement is shown to be predominantly caused by an axial built-in electric field induced by spontaneous polarization in the WZ lattice via electric field-induced second-order nonlinear susceptibility and can be controlled optically and potentially electrically. The findings, therefore, provide an effective strategy for enhancing and manipulating the nonlinear optical response in subwavelength NWs by utilizing lattice engineering.
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42. |
- Zhang, Bin, et al.
(författare)
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Effect of exciton transfer on recombination dynamics in vertically nonuniform GaAsSb epilayers
- 2019
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Ingår i: Applied Physics Letters. - : AMER INST PHYSICS. - 0003-6951 .- 1077-3118. ; 114:25
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Tidskriftsartikel (refereegranskat)abstract
- Low-temperature photoluminescence (PL), photoreflectance (PR), and temperature dependent time-resolved PL spectroscopies are employed to investigate optical emission processes and exciton dynamics in graded GaAsSb epilayers. The nonuniformity in the Sb composition along the growth direction is disclosed by low-temperature PL and PR measurements. Furthermore, significant differences in PL dynamics are found at low temperatures for the PL emissions originating from spatial regions with the low and high Sb compositions, with a fast decay and a slow rise at the early stage of the PL transient, respectively. This finding is attributed to exciton transfer from the low Sb region to the high Sb region. The obtained results are important for a general understanding of optical transitions and exciton/carrier dynamics in material systems with a graded alloy composition.
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43. |
- Zhang, Xingjun, et al.
(författare)
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Data De-Duplication with Adaptive Chunking and Accelerated Modification Identifying
- 2016
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Ingår i: Computing and informatics. - : Slovak Academy of Sciences Institute of Informatics. - 1335-9150. ; 35:3, s. 586-614
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Tidskriftsartikel (refereegranskat)abstract
- The data de-duplication system not only pursues the high de-duplication rate, which refers to the aggregate reduction in storage requirements gained from de-duplication, but also the de-duplication speed. To solve the problem of random parameter-setting brought by Content Defined Chunking (CDC), a self-adaptive data chunking algorithm is proposed. The algorithm improves the de-duplication rate by conducting pre-processing de-duplication to the samples of the classified files and then selecting the appropriate algorithm parameters. Meanwhile, FastCDC, a kind of content-based fast data chunking algorithm, is adopted to solve the problem of low de-duplication speed of CDC. By introducing de-duplication factor and acceleration factor, FastCDC can significantly boost de-duplication speed while not sacrificing the de -duplication rate through adjusting these two parameters. The experimental results demonstrate that our proposed method can improve the de -duplication rate by about 5 %, while FastCDC can obtain the increase of de -duplication speed by 50 % to 200 % only at the expense of less than 3 % de duplication rate loss.
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44. |
- Zhao, F, et al.
(författare)
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Electron spin control in dilute nitride semiconductors
- 2009
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Ingår i: JOURNAL OF PHYSICS-CONDENSED MATTER. - : IOP Publishing. - 0953-8984 .- 1361-648X. ; 21:17, s. 174211-
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Tidskriftsartikel (refereegranskat)abstract
- We report on a study of spin-dependent recombination processes (SDR) for conduction band electrons on deep paramagnetic centers in a series of GaAs1-yNy epilayers by time-resolved optical orientation experiments. We demonstrate that this dilute nitride compound can be used as an effective electron spin filter under a polarized optical excitation of appropriate intensity. This optimum intensity can moreover be controlled by adjusting the nitrogen composition in the layer.
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