1. |
- Kazmi, Bilal, et al.
(författare)
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Thermodynamic and economic assessment of cyano functionalized anion based ionic liquid for CO2 removal from natural gas integrated with, single mixed refrigerant liquefaction process for clean energy
- 2022
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Ingår i: Energy. - : Pergamon Press. - 0360-5442 .- 1873-6785. ; 239
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Tidskriftsartikel (refereegranskat)abstract
- The study proposes a novel integrated process in which ionic liquid is utilized to control carbon dioxide (CO2) emissions from the natural gas combined with a single mixed refrigerant-based liquefaction process to assist safe transportation over long distances providing a sustainable and cleaner energy. Commercially amines are utilized for CO2 sequestration, but amines entail energy-intensive regeneration with elevated process costs. The present study offers a solvent screening mechanism based on important parameters such as heat of dissolution, viscosity, selectivity, working capacity, vapor pressure, corrosivity, and toxicity. The selected solvents' performance is computed by sensitivity analysis suggesting imidazolium-based cation 1-hexyl-3-methylimidazolium[Hmim] functionalized with tricyanomethanide(tcm) as anion a potential natural gas sweetening solvent in comparison with commercially used solvent monoethanoloamine(MEA), conventional ILs 1-butyl-3-methylimidazolium hexa-fluorophosphate [Bmim][Pf(6)] and 1-butyl-3-methylimidazolium methyl sulfate [Bmim][MeSO4]. The obtained sweet gas is liquefied using a single mixed refrigerant-based process providing 0.99 mol fraction of liquefied CH4 with less overall specific compression power requirement of 0.41 kW/kg of natural gas. Moreover, an exergy analysis demonstrates that the [Hmim][tcm] based process has lower total exergy destruction of 7.49 x 10(3) kW and is found to utilize less overall specific energy consumption 0.49 kWh/kg of NG in contrast to other studied solvents. Furthermore, a detailed economic analysis establishes [Hmim][tcm]-based CO2 integrated with liquefaction technology offers 50.7%, 74.4%, and 85.8% of total annualized cost (TAC) savings compared with the MEA-amim][Pf(6)]-, and [Bmim][MeSO4], respectively. Hence, [Hmim][tcm] for CO2 removal and integration with liquefaction process will incur unit cost based on the total annualized cost to be $2.2 x 10(4)/kmol of purified NG.
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2. |
- Van Bavel, Jay J., et al.
(författare)
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National identity predicts public health support during a global pandemic
- 2022
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Ingår i: Nature Communications. - : Nature Portfolio. - 2041-1723. ; 13:1
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Tidskriftsartikel (refereegranskat)abstract
- Understanding collective behaviour is an important aspect of managing the pandemic response. Here the authors show in a large global study that participants that reported identifying more strongly with their nation reported greater engagement in public health behaviours and support for public health policies in the context of the pandemic. Changing collective behaviour and supporting non-pharmaceutical interventions is an important component in mitigating virus transmission during a pandemic. In a large international collaboration (Study 1, N = 49,968 across 67 countries), we investigated self-reported factors associated with public health behaviours (e.g., spatial distancing and stricter hygiene) and endorsed public policy interventions (e.g., closing bars and restaurants) during the early stage of the COVID-19 pandemic (April-May 2020). Respondents who reported identifying more strongly with their nation consistently reported greater engagement in public health behaviours and support for public health policies. Results were similar for representative and non-representative national samples. Study 2 (N = 42 countries) conceptually replicated the central finding using aggregate indices of national identity (obtained using the World Values Survey) and a measure of actual behaviour change during the pandemic (obtained from Google mobility reports). Higher levels of national identification prior to the pandemic predicted lower mobility during the early stage of the pandemic (r = -0.40). We discuss the potential implications of links between national identity, leadership, and public health for managing COVID-19 and future pandemics.
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3. |
- Ali, Amjad, et al.
(författare)
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Effect of Manganese Catalysts on the Performance of Anodes in Direct Carbon Fuel Cells
- 2022
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Ingår i: ACS Applied Energy Materials. - : AMER CHEMICAL SOC. - 2574-0962. ; 5:6, s. 6878-6885
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Tidskriftsartikel (refereegranskat)abstract
- The efficiency of direct carbon fuel cells is higher than that of solid oxide fuel cells. The direct carbon fuel cell transforms chemical energy into electrical energy. In this work, the La0.4Sr0.6MnxTi1-xO3-delta (x = 0.02, 0.04, 0.06, 0.08) anode material has been synthesized by the combustion method to examine the device performance. X-ray analysis confirmed the single-perovskite cubic structure with an average crystalline size of 80 nm. An electrical conductivity of 2.1 S cm-1 and fuel cell performance of 100 mW cm-2 at 600 degrees C are measured with sub-bituminous fuel. Theoretical results describe the minor contribution of manganese (Mn) in the valence band and the major one in the conduction band, and with minimum energy, the Mn electrons may jump in the conduction band. Moreover, density functional theory confirmed that with an increase in the Mn concentration, Mn and Ti energy states appear at the Fermi level, which reveals that the conductivity of the compound has improved, agreeing with the experimental results that the Mn concentration led to the enhancement of the conductivity.
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4. |
- Elbeltagi, Ahmed, et al.
(författare)
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Data intelligence and hybrid metaheuristic algorithms-based estimation of reference evapotranspiration
- 2022
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Ingår i: Applied water science. - : Springer. - 2190-5487 .- 2190-5495. ; 12:7
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Tidskriftsartikel (refereegranskat)abstract
- For developing countries, scarcity of climatic data is the biggest challenge, and model development with limited meteorological input is of critical importance. In this study, five data intelligent and hybrid metaheuristic machine learning algorithms, namely additive regression (AR), AR-bagging, AR-random subspace (AR-RSS), AR-M5P, and AR-REPTree, were applied to predict monthly mean daily reference evapotranspiration (ET0). For this purpose, climatic data of two meteorological stations located in the semi-arid region of Pakistan were used from the period 1987 to 2016. The climatic dataset includes maximum and minimum temperature (Tmax, Tmin), average relative humidity (RHavg), average wind speed (Ux), and sunshine hours (n). Sensitivity analysis through regression methods was applied to determine effective input climatic parameters for ET0 modeling. The results of performed regression analysis on all input parameters proved that Tmin, RHAvg, Ux, and n were identified as the most influential input parameters at the studied station. From the results, it was revealed that all the selected models predicted ET0 at both stations with greater precision. The AR-REPTree model was located furthest and the AR-M5P model was located nearest to the observed point based on the performing indices at both the selected meteorological stations. The study concluded that under the aforementioned methodological framework, the AR-M5P model can yield higher accuracy in predicting ET0 values, as compared to other selected algorithms.
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5. |
- Raza, Ali, et al.
(författare)
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Misconceptions of Reference and Potential Evapotranspiration: A PRISMA-Guided Comprehensive Review
- 2022
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Ingår i: Hydrology. - : MDPI. - 2306-5338. ; 9:9
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Forskningsöversikt (refereegranskat)abstract
- One of the most important parts of the hydrological cycle is evapotranspiration (ET). Accurate estimates of ET in irrigated regions are critical to the planning, control, and regulation of agricultural natural resources. Accurate ET estimation is necessary for agricultural irrigation scheduling. ET is a nonlinear and complex process that cannot be calculated directly. Reference evapotranspiration (RET) and potential evapotranspiration (PET) are two primary forms of ET. The ideas, equations, and application areas for PET and RET are different. These two terms have been confused and used interchangeably by researchers. Therefore, terminology clarification is necessary to ensure their proper use. The research indicates that PET and RET concepts have a long and distinguished history. Thornthwaite devised the original PET idea, and it has been used ever since, although with several improvements. The development of RET, although initially confused with that of PET, was formally defined as a standard method. In this study, the Preferred Reporting Item for Systematic reviews and Meta-Analysis (PRISMA) was used. Equations for RET estimation were retrieved from 44 research articles, and equations for PET estimation were collected from 26 studies. Both the PET and RET equations were divided into three distinct categories: temperature-based, radiation-based, and combination-based. The results show that, among temperature-based equations for PET, Thornthwaite's (1948) equation was mentioned in 12,117 publications, whereas among temperature-based equations for RET, Hargreaves and Samani's (1985) equation was quoted in 3859 studies. Similarly, Priestley (1972) had the most highly cited equation in radiation-based PET equations (about 6379), whereas Ritchie (1972) had the most highly cited RET equations (around 2382) in radiation-based equations. Additionally, among combination-based PET equations, Penman and Monteith's (1948) equations were cited in 9307 research studies, but the equations of Allen et al. (1998) were the subject of a significant number of citations from 23,000 publications. Based on application, PET is most often applied in the fields of hydrology, meteorology, and climatology, whereas RET is more frequently utilized in the fields of agronomy, agriculture, irrigation, and ecology. PET has been used to derive drought indices, whereas RET has been employed for single crop and dual crop coefficient approaches. This work examines and describes the ideas and methodologies, widely used equations, applications, and advanced approaches associated with PET and RET, and discusses future enhancements to increase the accuracy of ET calculation to attain accurate agricultural irrigation scheduling. The use of advanced tools such as remote sensing and satellite technologies, in addition to machine learning algorithms, will help to improve the accuracy of PET and RET estimates. Researchers will be able to distinguish between PET and RET in the future with the use of the study's results.
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6. |
- Saeed, Aamer, et al.
(författare)
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Identification of novel C-2 symmetric Bis-Azo-Azamethine molecules as competitive inhibitors of mushroom tyrosinase and free radical scavengers : synthesis, kinetics, and molecular docking studies
- 2022
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Ingår i: Journal of Biomolecular Structure and Dynamics. - : Taylor & Francis. - 0739-1102 .- 1538-0254. ; 40:10, s. 4419-4428
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Tidskriftsartikel (refereegranskat)abstract
- Tyrosinase is a multi-copper enzyme found in plants, animals and microorganisms, plays a critical role in the melanogenesis and browning process critical to cosmetics and food industries. Many natural, semi-synthetic and synthetic inhibitors have been discovered. To this end, a small library of symmetrical Bis-Azo-Azamethine hybrids 5a–j was synthesized and characterized through spectroscopic and analytical data and explored for mushroom tyrosinase and free radical scavenging activity. All of the molecules 5a–j explicated better potential compared to the standard Kojic acid. On the whole, compound 5i having IC50 value 0.002 ± 0.004 µM was found to be the most potent derivative. The Kinetic studies were performed for 5i and indicating the mode of inhibition in a competitive manner. Structure Activity Relationship (SAR) analysis and docking studies were carried out. Thus compound 5i bearing bulky naphthyl groups was most potent and, The molecular docking indicated formation of two hydrogen bonds with Arg268 and one hydrophobic interaction with Glu322. The carbonyl oxygen of 5i interacts with Arg268 and form two hydrogen bonds having lengths 2.44 and 2.62 Å, respectively. In the same way, compounds 5a–j were appraised for DPPH free radical scavenging ability and five of them 5d, 5e, 5h, 5i and 5j were found to exhibit higher % scavenging potency compared with vitamin C, as the standard. Interesting compound 5i was again the most potent in the series. The current investigation points towards the role of naphthyl group in design of new inhibitors of melanogenesis and the antioxidants with improved efficacy.
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7. |
- Taqvi, Syed Ali Ammar, et al.
(författare)
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Simultaneous fault diagnosis based on multiple kernel support vector machine in nonlinear dynamic distillation column
- 2022
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Ingår i: Energy Science & Engineering. - : John Wiley & Sons. - 2050-0505. ; 10:3, s. 814-839
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Tidskriftsartikel (refereegranskat)abstract
- Although numerous works have been done, most of the studies in fault diagnosis are limited to single fault type at a time. Majority of the works reported in the literature do not extend the diagnosis of the root cause of the fault for simultaneous faults specifically in the distillation column. However, an industrial system is susceptible to more than one fault at a time, which may or may not be interrelated. These faults not only reduce the diagnosis performance but also increase the computational complexity of the diagnosis algorithm. In this work, therefore, a multiple kernel support vector machine (MK-SVM) algorithm is proposed to diagnose simultaneous faults in the distillation column. In the developed MK-SVM algorithm, multilabel approach based on various kernel functions has been utilized for the classification of simultaneous faults. Dynamic simulation of a pilot-scale distillation column using Aspen Plus(R) is used for generating data in normal and faulty operation. Eight different fault types are considered, including valve sticking at reflux and reboiler, tray upsets, loss of feed flow, feed composition, and feed temperature changes. In the classification of simultaneous faults, a combination of two, three, and four faults is introduced for the performance evaluation of the proposed MK-SVM algorithm. The result showed that the proposed MK-SVM has a high fault detection rate (FDR) of 99.51% and a very low misclassification rate (MR) of 0.49%. The MK-SVM-based classification is better with the F1 score of >97% for all combinations of faults. Moreover, it is observed that the proposed MK-SVM shows better fault diagnosis for single, multiple, and simultaneous faults as compared to other established machine-learning algorithms.
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8. |
- Usman, Muhammad, et al.
(författare)
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Evaluation of the chronic intoxication of fluoride on human serum metabolome using untargeted metabolomics
- 2022
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Ingår i: Arabian Journal of Chemistry. - : Elsevier BV. - 1878-5352 .- 1878-5379. ; 15:7
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Tidskriftsartikel (refereegranskat)abstract
- Drinking water is the main source of fluoride intake for the human body and its regulated consumption helps in decreasing dental caries. However, excessive fluoride consumption over a prolonged time period causes fluorosis disease which adversely affects many tissues and organs of the body. This paper describes the evaluation of chronic intoxication of fluoride on human serum metabolome. The untargeted metabolomics approach using UPLC-QTOF-MS/MS is applied for metabolomic profiling, whereas the estimation of fluoride in serum samples was carried out using the ion-selective electrode (ISE). Fluoride concentration was found to be 0.16–1.25 mg/L in serum samples of 39 fluorosis patients and 0.008–0.045 mg/L in 20 healthy samples. A total of 47 metabolites were identified based on the high-resolution mass spectrometry analysis. A volcano plot was generated to discriminate features that are significantly different between the fluorosis and healthy groups at the probability of 0.05 and fold change ≥ 2. Among all identified metabolites, intensities of ten differential identified metabolites including inosine, α-linolenic acid, guanosine, octanoyl-L-carnitine, His-Trp, phytosphingosine, lauroyl-L-carnitine, hydrocortisone, deoxyinosine and dodecanedioic acid have been found altered in disease samples compared to healthy controls. Major pathways identified based on these metabolites include energy metabolism, fatty acid oxidation, purine degradation pathway, elevated protein degradation, and increased ω-6 fatty acid linoleate signatures were observed.
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