| 1. |
- Anantha, Krishnan Hariramabadran, et al.
(author)
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Correlative Microstructure Analysis and In Situ Corrosion Study of AISI 420 Martensitic Stainless Steel for Plastic Molding Applications
- 2017
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In: Journal of the Electrochemical Society. - : Electrochemical Society. - 0013-4651 .- 1945-7111. ; 164:4, s. C85-C93
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Journal article (peer-reviewed)abstract
- In this work, the corrosion behavior of tempered AISI 420 martensitic stainless steel (MSS) was studied by in-situ atomic force microscopy (AFM) in 0.1M NaCl and correlated with the microstructure. Thermocalc simulation, dilatometry, and X-ray diffraction (XRD) were performed to investigate phase transformation which showed the formation of M3C, M7C3, and M23C6 type of carbides and also retained austenite. Optical microscopy, scanning electron microscopy (SEM), and AFM characterization revealed undissolved carbides and tempering carbides in the martensitic matrix. Volta potential mapping measured by scanning Kelvin probe force microscopy (SKPFM) indicated higher electrochemical (practical) nobility of the carbides with respect to the martensitic matrix whereas regions adjacent to carbides showed lower nobilities due to chromium depletion. Open circuit potential and cyclic potentiodynamic polarization measurements showed metastable corrosion activities associated with a weak passive behavior and a risk for localized corrosion along certain carbide boundaries. In-situ AFM measurements revealed selective dissolution of certain carbide interphases and martensitic inter-lath regions indicating higher propensity to localized corrosion.
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| 2. |
- Anantha, Krishnan Hariramabadran, et al.
(author)
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Experimental and modelling study of the effect of tempering on the susceptibility to environment-assisted cracking of AISI 420 martensitic stainless steel
- 2019
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In: Corrosion Science. - : PERGAMON-ELSEVIER SCIENCE LTD. - 0010-938X .- 1879-0496. ; 148, s. 83-93
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Journal article (peer-reviewed)abstract
- The resistance to environment-assisted cracking (EAC) of AISI 420 martensitic stainless steel (MSS) was investigated in 0.3 M NaCl solution (room temperature) at constant loads for 30 days. The steel tempered at 250 degrees C was superior to the 500 degrees C-temper, which showed corrosion pits favouring cracking. The fracture surface showed faceted grains, cleavage, striations, and inter- and transgranular cracks, suggesting a mixed stress corrosion cracking (SCC) and hydrogen embrittlement (HE) mechanism as the cause for EAC. Finite element modelling (FEM) indicated strain/stress localization at the mouth of deep pits and at the wall of shallow pits, displaying the favoured locations for pit-to-crack transition.
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| 3. |
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| 4. |
- Rehan, Arbab, et al.
(author)
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Effect of Austenitization and Tempering on the Microstructure and Mechanical Properties of a 5 wt% Cr Cold Work Tool Steel
- 2016
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In: Steel Research International. - : Wiley. - 1611-3683 .- 1869-344X. ; 12:1 December, s. 1609-1618
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Journal article (peer-reviewed)abstract
- The effects of austenitization and tempering temperatures for a 5 wt% Cr cold work tool steel are studied with an aim of understanding the influence on microstructure and mechanical properties. Microstructures are characterized with scanning electron microscopy and light optical microscopy. Retained austenite contents and martensite start temperatures are measured by X-ray diffraction and dilatometry, respectively. Hardness, impact toughness, and compressive yield strength are also determined. When the austenitization temperature is increased from 1020 or 1050 to 1075 °C, followed by tempering at 525 °C, significant hardness is gained while there is no increase in compressive yield strength. Higher austenitization temperatures also produce larger amounts of retained austenite. At the same time, the impact toughness is reduced due to coarsening of the martensitic microstructure. When the steel is tempered at 200 °C, a higher impact toughness and a higher volume fraction of retained austenite are observed. Retained austenite is not found after tempering at temperatures of 525 °C or above. It is concluded that the best combination of mechanical properties is achieved by austenitization at 1020 or 1050 °C followed by tempering at 525 °C.
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| 5. |
- Rehan, Arbab
(author)
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Effect of heat treatment on microstructure and mechanical properties of a 5 wt.% Cr cold work tool steel
- 2019
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Doctoral thesis (other academic/artistic)abstract
- This work presents investigations related to phase transformations occurring inthe 5 wt.% Cr cold work tool steel Caldie during hardening and tempering treatments. The influence of austenitisation temperature, cooling rate, sub-zero cooling, isothermal treatment during cooling, tempering temperature and holding time on the microstructure and mechanical properties were investigated.The hardened microstructure of the investigated steel consisted of a mixture ofplate and lath martensite, minor amounts of bainite, blocky and thin retained austenite and M7C3 carbides. Increasing austenitisation temperature from 1020°Cto 1050°C was found useful as it provided higher hardness, good compressive strength and sufficient toughness. However, a further increase to 1075°C resulted in large prior austenite grains which produced coarse martensite containing somewhat increased carbon content. This was found to reduce the impacttoughness of the steel. Significant amounts of retained austenite were present after tempering for 2x2 h between 200°C and 500°C while tempering at 525°C or higher, reduced retained austenite content to below 2%. During holding at tempering temperature carbides precipitated in martensite and possibly in retained austenite. The retained austenite was thereby destabilised and transformed to martensite on cooling. This fresh martensite was tempered by following tempering treatments. It was concluded that tempering at 525°C for 2x2 h was suitable to achieve a good combination of hardness, compressive strength and impact toughness. Retained austenite was also found to transform during holding at 600°C for longer times. Initially, carbides formed in the austenite and after some time transformation of retained austenite to ferrite and carbides took place. Results were used to discuss alternative heat treatment procedures for the 5wt.% Cr cold work tool steel Caldie and some changes of current heat treatment recommendations were suggested.
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| 6. |
- Rehan, Arbab, et al.
(author)
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Effects of Austenitisation Temperature and Multiple Tempering on the Microstructure and Impact Toughness of a 5 wt. % Cr Cold Work Tool Steel
- 2016
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In: 10th TOOL Conference, Tool, conference proceedings. - : 10th TOOL Conference. ; , s. 1-10
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Conference paper (other academic/artistic)abstract
- The microstructure and properties of a 5 wt.% Cr cold work tool steel were studied after austenitisation at 1020°C, 1050°C or 1075°C followed by single, double and triple tempering treatments at 525°C. The microstructures were investigated with scanning electron microscopy and X-ray diffraction and phase transformations were studied by dilatometry. Furthermore, hardness and Charpy un-notched and V-notched impact toughness testing was performed and results were correlated to observed microstructures. With higher austenitisation temperature, the martensite and bainite start temperatures were lowered resulting in microstructures containing a higher volume fraction of retained austenite. Retained austenite transformed into martensite on cooling from the tempering temperature. Specimens that were austenitised at 1050°C or 1075°C and tempered twice contained fresh martensite. Applying a third tempering was therefore required to guarantee a fully tempered microstructure. The second tempering resulted in an increase of the un-notched impact energy while the third tempering did not have a pronounced effect. A triple tempering procedure could be preferable when austenitising at high temperatures to avoid undesirable fresh martensite in the tool microstructure.
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| 7. |
- Rehan, Arbab, et al.
(author)
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Retained Austenite Transformation during Heat Treatment of a 5 Wt Pct Cr Cold Work Tool Steel
- 2017
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In: Metallurgical and Materials Transactions. A. - : Springer Science and Business Media LLC. - 1073-5623 .- 1543-1940. ; 48A:11, s. 5233-5243
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Journal article (peer-reviewed)abstract
- Retained austenite transformation was studied for a 5 wt pct Cr cold work tool steel tempered at 798 K and 873 K (525 degrees C and 600 degrees C) followed by cooling to room temperature. Tempering cycles with variations in holding times were conducted to observe the mechanisms involved. Phase transformations were studied with dilatometry, and the resulting microstructures were characterized with X-ray diffraction and scanning electron microscopy. Tempering treatments at 798 K (525 degrees C) resulted in retained austenite transformation to martensite on cooling. The martensite start (M-s) and martensite finish (M-f) temperatures increased with longer holding times at tempering temperature. At the same time, the lattice parameter of retained austenite decreased. Calculations from the Ms temperatures and lattice parameters suggested that there was a decrease in carbon content of retained austenite as a result of precipitation of carbides prior to transformation. This was in agreement with the resulting microstructure and the contraction of the specimen during tempering, as observed by dilatometry. Tempering at 873 K (600 degrees C) resulted in precipitation of carbides in retained austenite followed by transformation to ferrite and carbides. This was further supported by the initial contraction and later expansion of the dilatometry specimen, the resulting microstructure, and the absence of any phase transformation on cooling from the tempering treatment. It was concluded that there are two mechanisms of retained austenite transformation occurring depending on tempering temperature and time. This was found useful in understanding the standard tempering treatment, and suggestions regarding alternative tempering treatments are discussed. (C) The Author(s) 2017.
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