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Preparation and characterization of functionalized cellulose nanocrystals

Boujemaoui, Assya (author)
KTH,Fiber- och polymerteknologi
Mongkhontreerat, Surinthra (author)
KTH,Fiber- och polymerteknologi
Malmström, Eva (author)
KTH,Fiber- och polymerteknologi
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Carlmark, Anna (author)
KTH,Fiber- och polymerteknologi
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 (creator_code:org_t)
Elsevier, 2015
2015
English.
In: Carbohydrate Polymers. - : Elsevier. - 0144-8617 .- 1879-1344. ; 115, s. 457-464
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • In this work, a series of functional nanocrystals (F-CNCs) was successfully produced by an efficient preparation method, combining acid hydrolysis and Fischer esterification with various organic acids. Functionalities such as ATRP initiators, double bonds, triple bonds, and thiols could be incorporated on CNCs. Surface modification was confirmed by FT-IR, XPS, and elemental analysis. Physical properties of FC-NCs were assessed by AFM, XRD and TGA. Moreover, ATRP initiator functionalized CNCs were utilized to graft poly(methyl methacrylate) via ATRP, thiol functionalized CNCs were reacted with Ellman's reagent to determine the thiol content and dye disperse red 13 was attached to alkyne functionalized CNCs to estimate the propiolate content. The herein presented method is a highly versatile and straightforward procedure for the preparation of F-CNCs which is believed to be a better alternative for the commonly utilized, extensive, multistep, and time consuming post functionalization methods.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Kemiteknik -- Polymerteknologi (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Chemical Engineering -- Polymer Technologies (hsv//eng)

Keyword

Acid hydrolysis
Cellulose nanocrystals
Esterification
Functionalization
Functional organic acid

Publication and Content Type

ref (subject category)
art (subject category)

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Royal Institute of Technology

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