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The Chemical and El...
The Chemical and Electronic Structure of Metal/Conjugated Polymer Interfaces : A Joint Theoretical and Experimental Study
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- Lazzaroni, R. (author)
- Service de Chimie des Maririaux Nouveaux Département des Matériaux et Procédés Universitt de Mons-Hainaw, Mons, Belgium
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- Fredriksson, C. (author)
- Service de Chimie des Maririaux Nouveaux Département des Matériaux et Procédés Universitt de Mons-Hainaw, Mons, Belgium
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- Brédas, J. L. (author)
- Service de Chimie des Maririaux Nouveaux Département des Matériaux et Procédés Universitt de Mons-Hainaw, Mons, Belgium
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- Dannetun, Per (author)
- Linköpings universitet,Institutionen för fysik, kemi och biologi,Tekniska fakulteten
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- Boman, Magnus (author)
- Linköpings universitet,Institutionen för fysik, kemi och biologi,Tekniska fakulteten
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- Stafström, Sven (author)
- Linköpings universitet,Institutionen för fysik, kemi och biologi,Tekniska fakulteten
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- Salaneck, William R. (author)
- Linköpings universitet,Institutionen för fysik, kemi och biologi,Tekniska fakulteten
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(creator_code:org_t)
- Dordrecht : Springer Netherlands, 1993
- 1993
- English.
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In: Intrinsically Conducting Polymers. - Dordrecht : Springer Netherlands. - 9780792324560 - 9789048143160 - 9789401719520 ; , s. 135-146
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Abstract
Subject headings
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- We investigate the interface between aluminum and several prototypical conjugaced systems wich a combined experimental and theoretical approach. The experiments consist of following the evolution of the polymer surface during the early stages of aluminum deposition, with X-ray and Ultraviolet Photoe!ectron Spectroscopies (XPS, UPS). In parallel, we perform quantum chemical calculacions on mode! oligomer systems interacting with one to four Al atoms. Aluminum is found to internet strongly with the polymer chain. Al·carbon covalenc boods an: formed along the polymer backbone; the chain geomeuy is deeply modified and the π electron conjugation can be dramatically reduced.
Subject headings
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Publication and Content Type
- ref (subject category)
- kap (subject category)
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