Sökning: onr:"swepub:oai:DiVA.org:liu-161852" > Impact of Singly Oc...
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000 | 04857naa a2200517 4500 | |
001 | oai:DiVA.org:liu-161852 | |
003 | SwePub | |
008 | 191118s2019 | |||||||||||000 ||eng| | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-1618522 URI |
024 | 7 | a https://doi.org/10.1021/acsami.9b124412 DOI |
040 | a (SwePub)liu | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Riera-Galindo, Sergiu Linköpings universitet,Laboratoriet för organisk elektronik,Tekniska fakulteten4 aut0 (Swepub:liu)serri80 |
245 | 1 0 | a Impact of Singly Occupied Molecular Orbital Energy on the n-Doping Efficiency of Benzimidazole Derivatives |
264 | c 2019-09-20 | |
264 | 1 | b AMER CHEMICAL SOC,c 2019 |
338 | a electronic2 rdacarrier | |
500 | a Funding Agencies|Swedish Foundation for Strategic Research, VINNOVA [2015-04859]; Swedish Research CouncilSwedish Research Council [2016-03979]; AForsk [18-313]; Advanced Functional Materials Center at Linkoping University [2009-00971]; Regione LombardiaRegione Lombardia; Fondazione CariploFondazione Cariplo; SmartMatLab Centre project [2014-42639194]; Finnish Cultural FoundationFinnish Cultural Foundation; Universita degli Studi di Milano (Piano Sostegno alla Ricerca 2018 LINEA 2 Azione A-Giovani Ricercatori) | |
520 | a We investigated the impact of singly occupied molecular orbital (SOMO) energy on the n-doping efficiency of benzimidazole derivatives. By designing and synthesizing a series of new air-stable benzimidazole-based dopants with different SOMO energy levels, we demonstrated that an increase of the dopant SOMO energy by only similar to 0.3 eV enhances the electrical conductivity of a benchmark electron-transporting naphthalenediimide-bithiophene polymer by more than 1 order of magnitude. By combining electrical, X-ray diffraction, and electron paramagnetic resonance measurements with density functional theory calculations and analytical transport simulations, we quantitatively characterized the conductivity, Seebeck coefficient, spin density, and crystallinity of the doped polymer as a function of the dopant SOMO energy. Our findings strongly indicate that charge and energy transport are dominated by the (relative) position of the SOMO level, whereas morphological differences appear to play a lesser role. These results set molecular-design guidelines for next-generation n-type dopants. | |
650 | 7 | a NATURVETENSKAPx Fysikx Den kondenserade materiens fysik0 (SwePub)103042 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Physical Sciencesx Condensed Matter Physics0 (SwePub)103042 hsv//eng |
653 | a n-type dopants; DMBI; SOMO energy; electron transfer; n-doped polymers | |
700 | 1 | a Orbelli Biroli, Alessiou CNR, Italy4 aut |
700 | 1 | a Forni, Alessandrau CNR, Italy4 aut |
700 | 1 | a Puttisong, Yuttapoomu Linköpings universitet,Biomolekylär och Organisk Elektronik,Tekniska fakulteten4 aut0 (Swepub:liu)yutpu33 |
700 | 1 | a Tessore, Francescau Univ Milan, Italy4 aut |
700 | 1 | a Pizzotti, Maddalenau Univ Milan, Italy4 aut |
700 | 1 | a Pavlopoulou, Eleniu Univ Bordeaux, France4 aut |
700 | 1 | a Solano, Eduardou ALBA Synchrotron Light Source, Spain4 aut |
700 | 1 | a Wang, Suhaou Linköpings universitet,Fysik och elektroteknik,Tekniska fakulteten4 aut0 (Swepub:liu)suhwa83 |
700 | 1 | a Wang, Gangu Linköpings universitet,Laboratoriet för organisk elektronik,Tekniska fakulteten4 aut0 (Swepub:liu)ganwa98 |
700 | 1 | a Ruoko, Tero-Petriu Linköpings universitet,Laboratoriet för organisk elektronik,Tekniska fakulteten4 aut0 (Swepub:liu)terru30 |
700 | 1 | a Chen, Weiminu Linköpings universitet,Biomolekylär och Organisk Elektronik,Tekniska fakulteten4 aut0 (Swepub:liu)weich55 |
700 | 1 | a Kemerink, Martijnu Linköpings universitet,Komplexa material och system,Tekniska fakulteten4 aut0 (Swepub:liu)marke89 |
700 | 1 | a Berggren, Magnusu Linköpings universitet,Laboratoriet för organisk elektronik,Tekniska fakulteten4 aut0 (Swepub:liu)magbe98 |
700 | 1 | a di Carlo, Gabrieleu Univ Milan, Italy4 aut |
700 | 1 | a Fabiano, Simoneu Linköpings universitet,Fysik och elektroteknik,Tekniska fakulteten4 aut0 (Swepub:liu)simfa84 |
710 | 2 | a Linköpings universitetb Laboratoriet för organisk elektronik4 org |
773 | 0 | t ACS Applied Materials and Interfacesd : AMER CHEMICAL SOCg 11:41, s. 37981-37990q 11:41<37981-37990x 1944-8244x 1944-8252 |
856 | 4 | u https://liu.diva-portal.org/smash/get/diva2:1370880/FULLTEXT01.pdfx primaryx Raw objecty fulltext:postprint |
856 | 4 | u https://hal.archives-ouvertes.fr/hal-02888890/file/Eleni-and-coll_Benzimidazoles_dopants_FINAL_ACS-AMI_2019.pdf |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-161852 |
856 | 4 8 | u https://doi.org/10.1021/acsami.9b12441 |
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