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Influence of contin...
Influence of continuous magnetic field on the separation of ephedrine enantiomers by molecularly imprinted polymers
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- R. Guerreiro, Antonio (författare)
- Cranfield University, Silsoe MK45 4DT, Beds, England
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- Korkhov, Vadim (författare)
- Latvian State University, Institute Polymer Mat, LV-1006 Riga, Latvia
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- Mijangos, Irene (författare)
- Cranfield University, Silsoe MK45 4DT, Beds, England
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- V. Piletska, Elena (författare)
- Cranfield University, Silsoe MK45 4DT, Beds, England
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- Rodins, Juris (författare)
- Latvian State University, Institute Polymer Mat, LV-1006 Riga, Latvia
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- P. F. Turner, Anthony (författare)
- Cranfield University, UK
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- A. Piletsky, Sergey (författare)
- Cranfield University, Silsoe MK45 4DT, Beds, England
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(creator_code:org_t)
- Elsevier Science B.V., Amsterdam. 2008
- 2008
- Engelska.
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Ingår i: Biosensors & bioelectronics. - : Elsevier Science B.V., Amsterdam.. - 0956-5663 .- 1873-4235. ; 23:7, s. 1189-1194
- Relaterad länk:
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http://dspace.lib.cr...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- A set of polymers was imprinted with (-)-ephedrine using UV initiation, under the influence of a constant external magnetic field with intensities ranging from 0 to 1.55T Synthesised materials were characterised by X-ray crystallography, infrared spectroscopy, swelling and surface area. Recognition properties were assessed by the ability to discriminate between (+) and (-)-ephedrine and by Scatchard analyses on chromatographic mode. It was shown that polymer morphology and recognition properties are affected by the magnetic field. This resulted in considerable improvements in the chromatographic resolution of ephedrine enantiomers by materials synthesised under the influence of magnetic field. Apparently the magnetic field improved the ordering of the polymer structure and facilitated the formation of more uniform imprinting sites. (c) 2007 Elsevier B.V. All rights reserved.
Nyckelord
- molecularly imprinted polymers; magnetic field polymerisation
- TECHNOLOGY
- TEKNIKVETENSKAP
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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