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Formation of a Novel Polymeric Cadmium(II) Complex Bridged by Sulfur and Thiocyanato Ions

Li, Shengli (author)
Department of Chemistry, Anhui University, China
Wu, Jieying (author)
Department of Chemistry, Anhui University, China
Zhang, Xuanjun (author)
Department of Chemistry, Anhui University, China
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Tian, Yupeng (author)
Department of Chemistry, Anhui University, China
Jiang, Minhua (author)
State Key Laboratory of Crystal Materials, Shandong University, China
Chen, Zuyao (author)
Department of Applied Chemistry, University of Science and Technology of China
Usman, Anwar (author)
X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia
Fun, Hoong-Kun (author)
X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia
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 (creator_code:org_t)
Chemical Society of Japan, 2003
2003
English.
In: Chemistry Letters. - : Chemical Society of Japan. - 0366-7022 .- 1348-0715. ; 32:8, s. 748-749
  • Journal article (peer-reviewed)
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  • The title complex, {[N(CH3)4]2[Cd(SCN)2S]}n, was prepared by self-assembling from the reaction of a methanol/water (volume ratio, 1/1) solution containing cadmium(II) thiocyanate with equivalent amount of tetramethylammonium thiocyanate. The result of single X-ray determination for the complex reveals that a novel polymeric cadmium(II) complex bridged by sulfur and thiocyanato ions was obtained, which formed a two-dimensional (2D) structure.

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