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Preparation of size...
Preparation of size-controllable monodispersed carbon@silica core-shell microspheres and hollow silica microspheres
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- Ju, Minhua (author)
- State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University
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- Li, Yupeng (author)
- State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing Tech University
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- Yu, Liang (author)
- Luleå tekniska universitet,Kemiteknik
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- Wang, Chongqing (author)
- State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing
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- Zhang, Lixiong (author)
- State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing
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(creator_code:org_t)
- Elsevier, 2017
- 2017
- English.
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In: Microporous and Mesoporous Materials. - : Elsevier. - 1387-1811 .- 1873-3093. ; 247, s. 75-85
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- Size-controllable monodispersed carbon@silica core-shell microspheres and hollow silica microspheres were prepared in a simple homemade T-type mixer by polymerization of furfuryl alcohol (FA) and hydrolysis of TEOS in H2SO4 water phase microdroplets to obtain polyfurfuryl alcohol (PFA)@silica microspheres, followed by carbonization and calcination. The FA and TEOS diffuse into the water phase from an oil phase. The flow rates of oil and water phase were 4 and 2 ml h−1, respectively. It was found that the concentration of FA has a more significant effect on the diameter of carbon@silica core-shell microspheres than TEOS due to the template effect of the PFA core. However, the diameter of the hollow silica microspheres was influenced by the concentration of TEOS more significantly. The obtained core-shell microspheres and hollow silica microspheres have large surface area of 555 and 769 m2 g−1, respectively. The hollow silica microspheres have both microporous and mesoporous structure, and the percentage of mesoporous volume was as high as 89%. In addition, based on the study results, a rational formation process of the carbon@silica core-shell microsphere and hollow silica microspheres was assumed.
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Kemiska processer (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Chemical Process Engineering (hsv//eng)
Keyword
- Chemical Technology
- Kemisk teknologi
Publication and Content Type
- ref (subject category)
- art (subject category)
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