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Selective Adsorptio...
Selective Adsorption of CO2 on Zeolites NaK-ZK‑4 with Si/Al of 1.8−2.8
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- Cheung, Ocean (författare)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK),Uppsala University, Sweden
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- Bacsik, Zoltan (författare)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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- Fil, Nicolas (författare)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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- Krokidas, Panagiotis (författare)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK),National Centre for Scientific Research “Demokritos”, Greece
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- Wardecki, Dariusz (författare)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK),Chalmers University of Technology, Sweden; University of Warsaw, Poland
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- Hedin, Niklas (författare)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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(creator_code:org_t)
- 2020-09-25
- 2020
- Engelska.
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Ingår i: ACS Omega. - : American Chemical Society (ACS). - 2470-1343. ; 5:39, s. 25371-25380
- Relaterad länk:
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https://doi.org/10.1...
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https://pubs.acs.org...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Zeolites with appropriately narrow pore apertures can kinetically enhance the selective adsorption of CO2 over N2. Here, we showed that the exchangeable cations (e.g., Na+ or K+) on zeolite ZK-4 play an important role in the CO2 selectivity. Zeolites NaK ZK-4 with Si/Al = 1.8–2.8 had very high CO2 selectivity when an intermediate number of the exchangeable cations were K+ (the rest being Na+). Zeolites NaK ZK-4 with Si/Al = 1.8 had high CO2 uptake capacity and very high CO2-over-N2 selectivity (1190). Zeolite NaK ZK-4 with Si/Al = 2.3 and 2.8 also had enhanced CO2 selectivity with an intermediate number of K+ cations. The high CO2 selectivity was related to the K+ cation in the 8-rings of the α-cage, together with Na+ cations in the 6-ring, obstructing the diffusion of N2 throughout the zeolite. The positions of the K+ cation in the 8-ring moved slightly (max 0.2 Å) toward the center of the α-cage upon the adsorption of CO2, as revealed by in situ X-ray diffraction. The CO2-over-N2 selectivity was somewhat reduced when the number of K+ cations approached 100%. This was possibly due to the shift in the K+ cation positions in the 8-ring when the number of Na+ was going toward 0%, allowing N2 diffusion through the 8-ring. According to in situ infrared spectroscopy, the amount of chemisorbed CO2 was reduced on zeolite ZK-4s with increasing Si/Al ratio. In the context of potential applications, a kinetically enhanced selection of CO2 could be relevant for applications in carbon capture and bio- and natural gas upgrading.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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