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Lewis Acid-Catalyze...
Lewis Acid-Catalyzed Ring-Opening Alcoholysis of Cyclohexene Oxide : The Role of Open Metal Sites in the Bi(III)-based Metal-Organic Framework SU-101
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Obeso, Juan L. (author)
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Flores, J. Gabriel (author)
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Flores, Catalina V. (author)
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Rios-Escobedo, Reyna (author)
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Aguilar-Pliego, Julia (author)
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- Inge, A. Ken, 1984- (author)
- Stockholms universitet,Institutionen för material- och miljökemi (MMK)
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de los Reyes, José Antonio (author)
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Peralta, Ricardo A. (author)
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Ibarra, Ilich A. (author)
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Leyva, Carolina (author)
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(creator_code:org_t)
- 2023
- 2023
- English.
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In: ChemCatChem. - 1867-3880 .- 1867-3899. ; 15:13
- Related links:
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https://doi.org/10.1...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- SU-101 was screened for the acid-catalyzed ring-opening alcoholysis of cyclohexene oxide. Results indicated access to open metal sites within SU-101, a fundamental requirement (Lewis acid Bi+3 sites) for this reaction. In addition, SU-101 exhibited high chemical stability, demonstrated by retaining its crystalline structure after the reaction. The cyclohexene conversion was estimated to be 99.8, 96.8, and 14.3 % at 40 °C for methanol, ethanol, and propanol, respectively. Also, SU-101 demonstrated an outstanding catalytic cyclability performance for five cycles without losing catalytic activity.
Subject headings
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Kemiska processer (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Chemical Process Engineering (hsv//eng)
Keyword
- alcoholysis
- heterogeneous catalysis
- Lewis acids
- metal-organic frameworks
- open-metal sites
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Obeso, Juan L.
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Flores, J. Gabri ...
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Flores, Catalina ...
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Rios-Escobedo, R ...
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Aguilar-Pliego, ...
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Inge, A. Ken, 19 ...
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show more...
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de los Reyes, Jo ...
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Peralta, Ricardo ...
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Ibarra, Ilich A.
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Leyva, Carolina
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show less...
- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Chemical Science ...
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and Organic Chemistr ...
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- ENGINEERING AND TECHNOLOGY
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ENGINEERING AND ...
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and Chemical Enginee ...
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and Chemical Process ...
- Articles in the publication
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ChemCatChem
- By the university
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Stockholm University