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A tri-continuous me...
A tri-continuous mesoporous material IBN-9 with the silica pore wall following a hexagonal minimal surface
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Han, Yu (författare)
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- Zhang, Daliang (författare)
- Stockholms universitet,Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi
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Chng, Leng Leng (författare)
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- Sun, Junliang (författare)
- Stockholms universitet,Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi
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Zhao, Lan (författare)
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- Zou, Xiaodong (författare)
- Stockholms universitet,Institutionen för fysikalisk kemi, oorganisk kemi och strukturkemi
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Ying, Jackie Y. (författare)
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(creator_code:org_t)
- 2009-04-06
- 2009
- Engelska.
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Ingår i: Nature Chemistry. - : Springer Science and Business Media LLC. - 1755-4349 .- 1755-4330. ; 1, s. 123-127
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Ordered porous materials with unique pore structures and pore sizes in the mesoporous range (2–50 nm) have many applications in catalysis, separation and drug delivery. Extensive research has resulted in mesoporous materials with onedimensional, cage-like and bi-continuous pore structures. Three families of bi-continuous mesoporous materials have been made, with two interwoven but unconnected channels, corresponding to the liquid crystal phases used as templates. Here we report a three-dimensional hexagonal mesoporous silica, IBN-9, with a tri-continuous pore structure that is synthesized using a specially designed cationic surfactant template. IBN-9 consists of three identical continuous interpenetrating channels, which are separated by a silica wall that follows a hexagonal minimal surface. Such a tri-continuous mesostructure was predicted mathematically, but until now has not been observed in real materials. Keywords: mesoporous structure, electron microscopy, self-assembly
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