Biaryl phosphite-oxazolines from hydroxyl aminoacid derivatives: highly efficient modular ligands for Ir-catalyzed hydrogenation of alkenes

• High enantioselectivities and activities are achieved in the Ir-catalyzed hydrogenation of several unfunctionalized olefins using modular biaryl phosphite-oxazoline ligands from hydroxyl aminoacid derivatives, the presence of a biaryl phosphite group is crucial to this success.

Subject headings

NATURVETENSKAP  -- Kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

Keyword

reduction

hydrogenation

diastereoselective syntheses

enantioselective syntheses (incl. cis/trans-isomerism)

polyphenylalkane derivatives

carboxylic acid esters (benzene compounds)

alcohols (benzene compounds)

Chemistry

Kemi

Publication and Content Type

ref (subject category)

art (subject category)