Mn2FeSbO6 : A ferrimagnetic ilmenite and an antiferromagnetic perovskite

• Due to its polymorphism, Mn2FeSbO6 can be synthesized at high pressures and temperatures as a ferrimagnetic ilmenite or an antiferromagnetic perovskite. The structural phase transformation is discussed in detail, and magnetic structures are proposed for both phases. The high-pressure Mn2FeSbO6 polymorph is a rare example of A(2)B'B '' O-6 perovskite with solely Mn cations on the A site. Fe and Sb cations are ordered on the B sites. Theoretical calculations for the perovskite phase suggest a complex magnetic structure, holding an electronic polarization.

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Teknisk fysik med inriktning mot fasta tillståndets fysik

Engineering Science with specialization in Solid State Physics

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