One-pot Synthesis of MoO3-x Nanosheets for Supercapacitor Applications

• Molybdenum oxide nanosheets are interesting materials for energy storage, catalysis, and gas sensor applications.1 However, they are traditionally prepared via a variety of approaches which require the use of high temperature or organic solvents.2,3 Herein, we report the synthesis of MoO3-x nanosheets (where x denotes oxygen vacancy) via a one-step water based exfoliation strategy using bulk molybdenum oxides precursors.4 Scanning and transmission electron microscopy show that the MoO3-x has a typical nanosheet morphology with a few nanometer thickness. The MoO3-x nanosheets display localized surface plasmon resonance (LSPR), which can be enhanced by modifying the morphology and the amount of oxygen vacancies (x) using chemical and/or photochemical treatments.The aqueous suspension of the MoO3-x nanosheets was drop-cast onto carbon paper and this material was then used as binder free electrodes for supercapacitor applications. The electrodes showed promising performance regarding capacitance and rate capability in acidified sodium sulphate solutions. The facile green synthesis of MoO3-x nanosheets coupled with their significant photochemical and electrochemical properties pave the way for the use of the nanosheets in a variety of applications.References:(1)        de Castro, I. A.; Datta, R. S.; Ou, J. Z.; Castellanos-Gomez, A.; Sriram, S.; Daeneke, T.; Kalantar-zadeh, K. Molybdenum Oxides - From Fundamentals to Functionality. Adv. Mater. 2017, 29 (40), 1701619.(2)        Xiao, X.; Song, H.; Lin, S.; Zhou, Y.; Zhan, X.; Hu, Z.; Zhang, Q.; Sun, J.; Yang, B.; Li, T.; Jiao, L.; Zhou, J.; Tang, J.; Gogotsi, Y. Scalable Salt-Templated Synthesis of Two-Dimensional Transition Metal Oxides. Nat. Commun. 2016, 7, 11296.(3)        Alsaif, M. M. Y. A.; Field, M. R.; Daeneke, T.; Chrimes, A. F.; Zhang, W.; Carey, B. J.; Berean, K. J.; Walia, S.; van Embden, J.; Zhang, B.; Latham, K.; Kalantar-zadeh, K.; Ou, J. Z. Exfoliation Solvent Dependent Plasmon Resonances in Two-Dimensional Sub-Stoichiometric Molybdenum Oxide Nanoflakes. ACS Appl. Mater. Interfaces 2016, 8 (5), 3482–3493.(4)      Etman A. S.; Abdelhamid H. N.; Yuan Y.; Wang L.; Zou X.; Sun J. Facile Water Based Strategy for Synthesizing MoO3-x Nanosheets: Efficient Visible Light Photocatalyst for Dye Degradation. ACS Omega. in Press.

Ämnesord

NATURVETENSKAP  -- Kemi -- Oorganisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)

Nyckelord

synthesis

MoO3-x

nanosheets

supercapacitor

Chemistry with specialization in Inorganic Chemistry

Kemi med inriktning mot oorganisk kemi

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