Proof for trivalent Sc ions in Sc-2 @ C-84 from high-energy spectroscopy

• The electronic structure and the valency of the Sc ions in the endohedral dimetallofullerene Sc-2 @ C-84 with D-2d symmetry are probed using high-energy spectroscopy. Comparison of the Sc 2p --> 3d x-ray-absorption spectrum with calculated ionic multiplet

Keyword

X-RAY-ABSORPTION; DIMETALLOFULLERENE SC-2-AT-C-84; ELECTRONIC-STRUCTURE; FULLERENE CAGES; METALLOFULLERENE; LA-AT-C-82; TM-AT-C-82; SYMMETRY; SPECTRA; METALS

Publication and Content Type

ref (subject category)

art (subject category)