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Synthesis of a mini...
Synthesis of a miniaturized [FeFe] hydrogenase model system
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- Esmieu, Charlene (författare)
- Uppsala universitet,Molekylär biomimetik,CNRS, LCC, 205 Route Narbonne,BP 44099, F-31077 Toulouse 4, France
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- Guo, Meiyuan (författare)
- Uppsala universitet,Teoretisk kemi
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- Redman, Holly J. (författare)
- Uppsala universitet,Molekylär biomimetik
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- Lundberg, Marcus, 1974- (författare)
- Uppsala universitet,Teoretisk kemi
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- Berggren, Gustav (författare)
- Uppsala universitet,Molekylär biomimetik
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(creator_code:org_t)
- 2019
- 2019
- Engelska.
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Ingår i: Dalton Transactions. - : ROYAL SOC CHEMISTRY. - 1477-9226 .- 1477-9234. ; 48:7, s. 2280-2284
- Relaterad länk:
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https://doi.org/10.1...
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https://uu.diva-port... (primary) (Raw object)
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https://pubs.rsc.org...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- The reaction occurring during artificial maturation of [FeFe] hydrogenase has been recreated using molecular systems. The formation of a miniaturized [FeFe] hydrogenase model system, generated through the combination of a [4Fe4S] cluster binding oligopeptide and an organometallic Fe complex, has been monitored by a range of spectroscopic techniques. A structure of the final assembly is suggested based on EPR and FTIR spectroscopy in combination with DFT calculations. The capacity of this novel H-cluster model to catalyze H-2 production in aqueous media at mild potentials is verified in chemical assays.
Ämnesord
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Teoretisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Theoretical Chemistry (hsv//eng)
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