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  • Yano, Junko (author)

Where water is oxidized to dioxygen: : Structure of the photosynthetic Mn4Ca cluster

  • Article/chapterEnglish2006

Publisher, publication year, extent ...

  • AMER ASSOC ADVANCEMENT SCIENCE,2006
  • printrdacarrier

Numbers

  • LIBRIS-ID:oai:DiVA.org:uu-514179
  • https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-514179URI
  • https://doi.org/10.1126/science.1128186DOI

Supplementary language notes

  • Language:English
  • Summary in:English

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  • Subject category:ref swepub-contenttype
  • Subject category:art swepub-publicationtype

Notes

  • The oxidation of water to dioxygen is catalyzed within photosystem II ( PSII) by a Mn4Ca cluster, the structure of which remains elusive. Polarized extended x-ray absorption fine structure (EXAFS) measurements on PSII single crystals constrain the Mn4Ca cluster geometry to a set of three similar high-resolution structures. Combining polarized EXAFS and x-ray diffraction data, the cluster was placed within PSII, taking into account the overall trend of the electron density of the metal site and the putative ligands. The structure of the cluster from the present study is unlike either the 3.0 or 3.5 angstrom - resolution x-ray structures or other previously proposed models.

Subject headings and genre

Added entries (persons, corporate bodies, meetings, titles ...)

  • Kern, Jan (author)
  • Sauer, Kenneth (author)
  • Latimer, Matthew J. (author)
  • Pushkar, Yulia (author)
  • Biesiadka, Jacek (author)
  • Loll, Bernhard (author)
  • Saenger, Wolfram (author)
  • Messinger, Johannes,1963-Max Planck Institute for Bioorganic Chemistry(Swepub:uu)johme269 (author)
  • Zouni, Athina (author)
  • Yachandra, Vittal K. (author)
  • Max Planck Institute for Bioorganic Chemistry (creator_code:org_t)

Related titles

  • In:Science: AMER ASSOC ADVANCEMENT SCIENCE314:5800, s. 821-8250036-80751095-9203

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