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The All-Seeing Eye ...
The All-Seeing Eye of Resonant Auger Electron Spectroscopy : A Study on Aqueous Solution Using Tender X-rays
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- Miteva, Tsveta (author)
- Paris-Sorbonne University
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- Kryzhevoi, Nikolai V. (author)
- Heidelberg University
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- Sisourat, Nicolas (author)
- Paris-Sorbonne University
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- Nicolas, Christophe (author)
- Synchrotron SOLEIL
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- Pokapanich, Wandared (author)
- Nakhon Phanom University
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- Saisopa, Thanit (author)
- Suranaree University of Technology
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- Songsiriritthigul, Prayoon (author)
- Suranaree University of Technology
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- Rattanachai, Yuttakarn (author)
- Rajamangala University of Technology Isan
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- Dreuw, Andreas (author)
- Heidelberg University
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- Wenzel, Jan (author)
- Heidelberg University
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- Palaudoux, Jérôme (author)
- Paris-Sorbonne University
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- Öhrwall, Gunnar (author)
- Lund University,Lunds universitet,MAX IV-laboratoriet,MAX IV Laboratory
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- Püttner, Ralph (author)
- Free University of Berlin
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- Cederbaum, Lorenz S. (author)
- Heidelberg University
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- Rueff, Jean Pascal (author)
- Synchrotron SOLEIL,Paris-Sorbonne University
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- Céolin, Denis (author)
- Synchrotron SOLEIL
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(creator_code:org_t)
- 2018-07-18
- 2018
- English 6 s.
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In: Journal of Physical Chemistry Letters. - : American Chemical Society (ACS). - 1948-7185. ; 9:15, s. 4457-4462
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Abstract
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- X-ray absorption and Auger electron spectroscopies are demonstrated to be powerful tools to unravel the electronic structure of solvated ions. In this work for the first time, we use a combination of these methods in the tender X-ray regime. This allowed us to address electronic transitions from deep core levels, to probe environmental effects, specifically in the bulk of the solution since the created energetic Auger electrons possess large mean free paths, and moreover, to obtain dynamical information about the ultrafast delocalization of the core-excited electron. In the considered exemplary aqueous KCl solution, the solvated isoelectronic K+ and Cl- ions exhibit notably different Auger electron spectra as a function of the photon energy. Differences appear due to dipole-forbidden transitions in aqueous K+ whose occurrence, according to the performed ab initio calculations, becomes possible only in the presence of solvent water molecules.
Subject headings
- NATURVETENSKAP -- Fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences (hsv//eng)
Publication and Content Type
- art (subject category)
- ref (subject category)
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- By the author/editor
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Miteva, Tsveta
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Kryzhevoi, Nikol ...
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Sisourat, Nicola ...
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Nicolas, Christo ...
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Pokapanich, Wand ...
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Saisopa, Thanit
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Songsiriritthigu ...
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Rattanachai, Yut ...
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Dreuw, Andreas
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Wenzel, Jan
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Palaudoux, Jérôm ...
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Öhrwall, Gunnar
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Püttner, Ralph
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Cederbaum, Loren ...
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Rueff, Jean Pasc ...
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Céolin, Denis
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Physical Science ...
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Journal of Physi ...
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Lund University