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Polyfluorenes Bearing N,N-Dimethylpiperidinium Cations on Short Spacers for Durable Anion Exchange Membranes
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- Allushi, Andrit (author)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Mansouri Bakvand, Pegah (author)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH
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- Jannasch, Patric (author)
- Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,LTH profilområde: Energiomställningen,LTH profilområden,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH,LTH Profile Area: The Energy Transition,LTH Profile areas,Faculty of Engineering, LTH
- (creator_code:org_t)
- 2023-01-17
- 2023
- English.
- In: Macromolecules. - : American Chemical Society (ACS). - 0024-9297 .- 1520-5835. ; 56:3, s. 1165-1176
- Journal article (peer-reviewed)
Abstract
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- Alicyclic quaternary ammonium cations having all the β-protons in a strain-free ring structure are in general highly base resistant, and are thus very attractive to employ for anion exchange membrane (AEM) applications. However, tethering cations such as N,N-dimethylpiperidinium (DMP) to polymer backbones without introducing any weak links is quite challenging. In the present study, we have attached pairs of piperidine rings in their 4-position to fluorene and 2,7-diphenylfluorene via methylene bridges using straightforward SN2 reactions. These fluorenes were subsequently utilized as monomers in polyhydroxyalkylations to prepare poly(fluorene alkylene)s with different contents of the piperidine groups. AEMs were cast after quaternizing the piperidine groups to introduce DMP and spirocyclic 6-azonia-spiro-[5,5]undecane-6-ium (ASU) cations, respectively. The AEMs reached very high hydroxide ion conductivities, 100-156 mS cm-1 at 80 ºC, in the ion exchange capacity (IEC) range 1.8-2.4 mequiv. g-1. X-ray scattering showed ionomer peaks indicating ionic clustering with a characteristic distance d = 2.0-2.9 nm depending on IEC. The AEMs displayed high thermal stability, up to ~250 ºC, and 1H NMR data indicated no degradation after storage in 5 M aq. NaOH during 168 h at 90 ºC. However, degradation started under very severe conditions (10 M, 90 °C) with ~75% of the total ionic loss in all the AEMs assigned to Hofmann β-elimination. The overall results show that fluorene-based AEMs carrying DMP and ASU cations via methylene bridges display an attractive combination of ionic phase separation, thermal and chemical stability, and hydroxide conductivity.
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Polymerteknologi (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Polymer Technologies (hsv//eng)
- NATURVETENSKAP -- Kemi -- Polymerkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Polymer Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
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