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The robust catalyst...
The robust catalysts (Ni1-x-Mo-x/doped ceria and Zn1-x-Mo-x/doped ceria, x=0.1 and 0.3) for efficient natural gas reforming in solid oxide fuel cells
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- Naseer, Amtul (författare)
- COMSATS University Islamabad
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- Hussain, Murid (författare)
- COMSATS University Islamabad
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- Shakir, Imran (författare)
- King Saud University,University of California at Los Angeles (UCLA)
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- Abbas, Qaisar (författare)
- Durham University
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- Yilmaz, Duygu, 1987 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Zahra, Marriam (författare)
- COMSATS University Islamabad
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- Raza, Rizwan, 1980 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- Elsevier BV, 2020
- 2020
- Engelska.
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Ingår i: Electrochimica Acta. - : Elsevier BV. - 0013-4686. ; 361
- Relaterad länk:
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http://dro.dur.ac.uk...
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https://research.cha...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Nickel is a promising catalyst in Solid Oxide fuel cell (SOFC) due to its electrocatalytic performance, however, the practical utilization of Ni-based materials is hindered by the undesirable carbon deposition during methane decomposition. Herein, molybdenum is incorporated into the Ni- and Zn-based cermets (Ni1-x-Mo-x/GDC and Zn1-x-Mo-x/GDC, x = 0.1 and 0.3) to enhance electrocatalytic properties and avoid the carbon deposition during cell operation. The desired composites are synthesized by the impregnation method and adopted as anode in SOFCs. The catalytic activity for methane oxidation has been significantly improved due to the introduction on Mo, which hindered the carbon deposition due to higher graphitization and abundant active sites accessible to fuel. The detailed Raman spectroscopy and conductivity analysis revealed that addition of Mo reduced the amount of deposited carbon and enhanced the electrical conductivity. By using natural gas, as a fuel, the as-prepared Mo-doped Ni-GDC rendered a maximum power density of 690 mW cm(-2) at 600 degrees C. It is worth mentioning that the achieved stable power density is one of the best in existing literature. The current study presents a novel strategy to improve the catalytic behavior of electrode materials and demonstrate the optimal performance at low operating temperature. (C) 2020 Elsevier Ltd. All rights reserved.
Ämnesord
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Annan kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Other Chemical Engineering (hsv//eng)
Nyckelord
- Carbon deposition
- Solid oxide fuel cell
- Mo doping
- Natural gas
Publikations- och innehållstyp
- art (ämneskategori)
- ref (ämneskategori)
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