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Radical Additions o...
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Mahmoudkhani, Amir H.
(författare)
Radical Additions of Bis(trimethylsilyl)phosphite to Vinyltrimethylsilane and Vinyltriethoxysilane: Crystal Structure of 2-Trimethylsilylethylphosphonic Acid
- Artikel/kapitelEngelska2003
Förlag, utgivningsår, omfång ...
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2010-10-27
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Informa UK Limited,2003
Nummerbeteckningar
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LIBRIS-ID:oai:research.chalmers.se:8b2c2533-8c8d-4d1a-94e1-58c546d64bc9
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https://doi.org/10.1080/713744570DOI
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https://research.chalmers.se/publication/3627URI
Kompletterande språkuppgifter
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Språk:engelska
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Sammanfattning på:engelska
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Ämneskategori:art swepub-publicationtype
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Ämneskategori:ref swepub-contenttype
Anmärkningar
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Organosilicon-phosphonate compounds with the general formula (R)n(RO)3mnSi(CH2)mP(O)(OSiR'3)2 are designed for application as novel materials for surface treatments and modifications. A solvothermal method based on the reaction of bis(trimethylsilyl)phosphite with vinyltrimethylsilane and vinyltriethoxysilane in the presence of a peroxide in benzene solvent was used to synthesize the silyl-substituted esters of organosilicon-phosphonate compounds. 2-Trimethylsilylethanephosphonic acid was prepared from its bis(trimethylsilyl) ester by alcoholysis. The crystal structure of the acid consists of two-dimensional arrays built up from the (P--)O--H···O--P hydrogen bonds.
Ämnesord och genrebeteckningar
Biuppslag (personer, institutioner, konferenser, titlar ...)
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Langer, Vratislav,1949Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)langer
(författare)
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Lindqvist, Oliver,1943Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)oliver
(författare)
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Chalmers tekniska högskola
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:Phosphorus, Sulfur and Silicon and the Related Elements: Informa UK Limited178:10, s. 2159-21681042-65071563-5325
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