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Hydrotreatment of l...
Hydrotreatment of lignin dimers over NiMoS-USY: effect of silica/alumina ratio
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- Salam, Muhammad Abdus, 1983 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Cheah, You Wayne, 1993 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Ho, Hoang Phuoc, 1983 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Olsson, Louise, 1974 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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- Creaser, Derek, 1966 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- 2021
- 2021
- Engelska.
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Ingår i: Sustainable Energy and Fuels. - : Royal Society of Chemistry (RSC). - 2398-4902. ; 5:13, s. 3445-3457
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https://pubs.rsc.org...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Sulfides of NiMo over a series of commercial ultra-stable Y zeolites were studied in an autoclave reactor to elucidate the effect of silica/alumina ratio (SAR = 12, 30, and 80) on the cleavage of etheric C-O (beta-O-4) and C-C (both sp(3)-sp(2) and sp(2)-sp(2)) linkages present in native/technical lignin and lignin derived bio-oils. 2-Phenethyl phenyl ether (PPE), 4,4-dihydroxydiphenylmethane (DHDPM), and 2-phenylphenol, (2PP) were examined as model dimers at 345 degrees C and 50 bar of total pressure using dodecane as the solvent. The etheric C-O hydrogenolysis activity was found to be in the order NiMoY30 > NiMoY12 > NiMoY80, despite a high initial rate of C-O cleavage over NiMoY12 owing to its high acid density. A high degree of hydrodeoxygenation (HDO) and hydrocracking reactions were observed with NiMoY30 yielding >80% of deoxygenated products of which similar to 58% are benzene, toluene, and ethylbenzenes. A similar experiment with DHDPM showed the rapid cleavage of the methylene-linked C-C dimer (sp(3)-sp(2)) to phenols and cresols even with the low acid density (high SAR) catalyst, NiMoY80. Direct hydrocracking of the recalcitrant 5-5 ' linkage in 2PP is very slow, however, it cleaved via a cascade of HDO, ring-hydrogenation, and hydrocracking reactions. A high degree of hydrogenolysis and hydrocracking occurs over NiMoY30 due to suitable balance between acidity and pore accessibility, enhanced proximity between acidic and deoxygenation sites leading to a slightly higher dispersion of Ni promoted MoS2 crystallites. Overall, the product spectrum consisted of a high yield of deoxygenated products. The carbon content on the recovered catalyst was in the range of 3-7 wt%. These results pave the way for effective catalysts to break recalcitrant linkages present in lignin to obtain a hydrocarbon-rich liquid transportation fuel. An experiment with Kraft lignin over NiMoY30 shows good selectivity for deoxygenated aromatics and cycloalkanes in the liquid phase.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Kemiska processer (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Chemical Process Engineering (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Kemiteknik -- Annan kemiteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Chemical Engineering -- Other Chemical Engineering (hsv//eng)
- NATURVETENSKAP -- Kemi -- Organisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Organic Chemistry (hsv//eng)
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