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A preliminary study...
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Vera, C. M.Phenomenex Australia, Pty Ltd, Lane Cove, NSW 2067, Australia
(författare)
A preliminary study on the selectivity of linear polynuclear aromatic hydrocarbons in SFC using phenyl-type stationary phases
- Artikel/kapitelEngelska2015
Förlag, utgivningsår, omfång ...
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Elsevier,2015
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printrdacarrier
Nummerbeteckningar
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LIBRIS-ID:oai:DiVA.org:kau-37302
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https://urn.kb.se/resolve?urn=urn:nbn:se:kau:diva-37302URI
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https://doi.org/10.1016/j.microc.2015.02.011DOI
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Språk:engelska
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Sammanfattning på:engelska
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Ämneskategori:ref swepub-contenttype
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Ämneskategori:art swepub-publicationtype
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The retention behaviour of a homologous series of polyaromatic hydrocarbons was evaluated on two phenyl-type stationary phases in reversed phase supercritical fluid chromatography (SFC). These phases were the Synergi polar-RP phase and the Cosmosil 5PBB phase, both of which are polar end-capped and incorporate an ether in a propyl chain that tethers the phenyl ring to the silica surface. The Cosmosil 5PBB phase also has five bromine atoms on the phenyl ring. The retention capacity of the Cosmosil column was substantially greater than the Synergi column. However, selectivity on the Cosmosil column was effectively independent of the acetonitrile modifier composition in the CO2 mobile phase, whereas, selectivity on the Synergi column was greatly affected by the acetonitrile modifier in the CO2 mobile phase. The results from this study showed that selectivity and retention studies in HPLC cannot be used to predict selectivity and retention behaviour in SFC. (C) 2015 Elsevier B.V. All rights reserved.
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Biuppslag (personer, institutioner, konferenser, titlar ...)
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Shock, D.Phenomenex Australia, Pty Ltd, Lane Cove, NSW 2067, Australia
(författare)
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Dennis, G. R.Australian Centre for Research on Separation Science, School of Science and Health, University of Western Sydney, Penrith, NSW 2751, Australia
(författare)
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Samuelsson, JörgenKarlstads universitet,Institutionen för ingenjörs- och kemivetenskaper (from 2013),Interact(Swepub:kau)jaorsamu
(författare)
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Enmark, MartinKarlstads universitet,Institutionen för ingenjörs- och kemivetenskaper (from 2013)(Swepub:kau)martenma
(författare)
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Fornstedt, Torgny,1957-Karlstads universitet,Institutionen för ingenjörs- och kemivetenskaper (from 2013),Interact(Swepub:kau)torgforn
(författare)
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Shalliker, R. AndrewKarlstads universitet,Institutionen för ingenjörs- och kemivetenskaper (from 2013),Australian Centre for Research on Separation Science, School of Science and Health, University of Western Sydney, Penrith, NSW 2751, Australia(Swepub:kau)andrshal
(författare)
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Phenomenex Australia, Pty Ltd, Lane Cove, NSW 2067, AustraliaAustralian Centre for Research on Separation Science, School of Science and Health, University of Western Sydney, Penrith, NSW 2751, Australia
(creator_code:org_t)
Sammanhörande titlar
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Ingår i:Microchemical journal (Print): Elsevier121, s. 136-1400026-265X1095-9149
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