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In Situ and Operand...
In Situ and Operando Characterizations of Metal Halide Perovskite and Solar Cells : Insights from Lab-Sized Devices to Upscaling Processes
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- Szostak, Rodrigo (author)
- University of Campinas (UNICAMP), BRA; Brazilian Synchrotron Light Laboratory (LNLS), Brazilian Center for Research in Energy and Materials (CNPEM), BRA
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- de Souza Gonçalves, Agnaldo (author)
- University of Campinas (UNICAMP), BRA
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- Nei de Freitas, Jilian (author)
- Center for Information Technology Renato Archer (CTI), BRA
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- Marchezi, Paulo E. (author)
- Karlstads universitet,Institutionen för ingenjörsvetenskap och fysik (from 2013),University of Campinas (UNICAMP), BRA
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- Lopes de Araújo, Francineide (author)
- University of Campinas (UNICAMP), BRA
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- Tolentino, Helio Cesar Nogueira (author)
- Brazilian Synchrotron Light Laboratory (LNLS), Brazilian Center for Research in Energy and Materials (CNPEM), BRA
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- Toney, Michael F. (author)
- University of Colorado, USA
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- das Chagas Marques, Francisco (author)
- University of Campinas (UNICAMP), BRA
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- Nogueira, Ana Flavia (author)
- University of Campinas (UNICAMP), BRA
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(creator_code:org_t)
- 2023-03-06
- 2023
- English.
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In: Chemical Reviews. - : American Chemical Society (ACS). - 0009-2665 .- 1520-6890. ; 123:6, s. 3160-3236
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- The performance and stabi l i t y of metal halide perovskite sola r cells strongly depend on precursor materials and deposition methods adopted during the perovskite layer preparation. There are often a number of different formation pathways available when preparing perovskite films. Since the precise pathway and intermediary mechanisms affect the resulting properties of the cells, in situ studies have been conducted to unravel t h e mechanisms involved in the formation and evolution of perovskite phases. These studies contributed to the development of procedures to improve the structural, morphological, and optoelectronic properties of the films and to move beyond spin-coating, with the use of scalable techniques. To explore the performance and degradation of devices, operando studies have been conducted on solar cells subjected to normal operating conditions, or stressed with humidity, high temperatures, and light radiation. This review presents an update of studies conducted in situ using a wide range of structural, imaging, and spectroscopic techniques, involving the formation/ degradation of halide perovskites. Operando studies are also addressed, emphasizing the latest degradation results for perovskite solar cells. These works demonstrate the importance of in situ and operando studies to achieve the level of stabi l i t y required for scale-up and consequent commercial deployment of these cells.
Subject headings
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Keyword
- Physics
- Fysik
Publication and Content Type
- ref (subject category)
- art (subject category)
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