Donor-acceptor polymer complex formation in solution confirmed by spectroscopy and atomic-scale modelling

• In all-polymer solar cells, high performance is attributed to the fine-grained morphology of the film in the active layer. However, the mechanism by which this fine-grained morphology is achieved remains unknown. Polymeric non-fullerene acceptors have the potential to restrict the self-aggregation, typical of non-fullerene small molecule acceptors. Here we employed a blend of the polymeric acceptor PF5-Y5 and the donor polymer PBDB-T to investigate the balance between molecular interactions in solution. Temperature-dependent absorption spectra show evidence of temperature-induced disaggregation of both donor and acceptor polymers, where the donor polymer disaggregation depends on the solvent polarity. Concentration-dependent fluorescence spectra of blend solutions display blue-shifted acceptor emission upon dilution, similar to that observed in acceptor solutions, and a decreased tendency for charge transfer from donor to acceptor upon dilution. Excitation spectra of dilute blend solutions contain an increased contribution to the long-wavelength acceptor emission, as compared to pure acceptor solutions, from a chromophore that absorbs in a region where the donor does not absorb. These observations can be explained by donor-acceptor complexation in dilute blend solutions, that is stabilized in more polar solvents. Moreover, the near IR-region of the absorption spectrum could be matched with the calculated electronic excitations of donor-acceptor complexes of PBDB-T and PF5-Y5 oligomers. The results corroborate that the interaction between segments of the donor and acceptor polymer chains favours the formation of donor-acceptor charge transfer complexes, stabilized by hybridization of the molecular orbitals, which reduces the electronic energy. The proposed donor-acceptor complex formation competes with the donor and acceptor self-aggregation and is influenced by the solvent environment. These pre-formed donor-acceptor complexes in low-concentration solutions can be expected to have important consequences on the film morphology of all-polymer blends. The results from this joint experimental-theoretical spectroscopy study provide insights that can guide the design of compatible donor and acceptor polymers for future high-performance organic solar cells.

Ämnesord

NATURVETENSKAP  -- Kemi -- Polymerkemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Polymer Chemistry (hsv//eng)

NATURVETENSKAP  -- Kemi -- Teoretisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Theoretical Chemistry (hsv//eng)

Nyckelord

Kemi

Chemistry

Materials Science

Materialvetenskap

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