id:"swepub:oai:DiVA.org:kth-14969"
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- Yang, X. C. (author)
Axial ligand exchange reaction on ruthenium phthalocyanines
- Article/chapterEnglish2005
Publisher, publication year, extent ...
- 2005
- printrdacarrier
Numbers
- LIBRIS-ID:oai:DiVA.org:kth-14969
- https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-14969URI
- https://doi.org/10.1142/S1088424605000319DOI
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- Language:English
- Summary in:English
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Notes
- QC 20100525
- Bis(4-methylpyridine)phthalocyaninato ruthenium(II) has been synthesized. It was proved by single-crystal X-ray diffraction that the central Ru(II) atom is bonded to six N atoms in an elongated octahedral configuration, and the axial ligands have a significantly longer Ru-N bond distance, 2.101(4) angstrom, than the independent pyrrol Ru-N bond, 1.99 angstrom. Therefore, the axial ligands can be exchanged by other ligands. The ligand exchange reactions with diethyl pyridyl-4-phosphonate and diethyl pyridylmethyl-4-phosphonate were studied in high boiling-point solvents at elevated temperatures, ca 160 degrees C. Mono-ligand as well as double-ligand replaced complexes were obtained. The complexes have been isolated by column chromatography. These complexes have potential applications, such as in dye sensitized solar cells.
Subject headings and genre
- ruthenium phthalocyanines
- axial ligand exchange
- dye sensitized solar cells
- nanocrystalline tio2 films
- soluble metallophthalocyanines
- ir sensitization
- solar-cells
- efficient
- electrode
- bond
Added entries (persons, corporate bodies, meetings, titles ...)
- Kritikos, M. (author)
- Akermark, B. (author)
- Sun, Licheng C. (author)
Related titles
- In:Journal of Porphyrins and Phthalocyanines9:4, s. 248-2551088-42461099-1409
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