L773:1434 1948 OR L773:1099 1948 OR L773:0162 0134
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- Forcato, M. (author)
Chiral, enantiopure aluminum(III) and titanium(IV) azatranes
- Article/chapterEnglish2006
Publisher, publication year, extent ...
- 2006-02-21
- Wiley,2006
- printrdacarrier
Numbers
- LIBRIS-ID:oai:DiVA.org:kth-15533
- https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-15533URI
- https://doi.org/10.1002/ejic.200500657DOI
Supplementary language notes
- Language:English
- Summary in:English
Part of subdatabase
- SwePubSwePub
Classification
Notes
- QC 20100525
- Al-III and Ti-IV complexes of C-3-symmetric tetradentate trisamidoamme ligands with trigonal bipyramidal coordination geometry, containing chlorine or dialkylamido groups, or with a free coordination site in the apical position, have been synthesised by salt metathesis and amine elimination. Products with threefold symmetry were generally obtained for tetravalent titanium, whereas for the aluminium complexes either asymmetric structures with two of the three podand arms taking part in coordination to the metal or symmetric arrangements possessing the full threefold symmetry were formed depending on the steric properties of the ligands.
Subject headings and genre
- aluminum
- chirality
- N ligands
- titanium
- tripodal ligands
- tripodal amido complexes
- early transition-metals
- direct alpha-arylation
- aryl chlorides
- triamidoamine ligands
- crystal-structures
- structural-characterization
- coordination chemistry
- group-13 azatranes
- tungsten complexes
Added entries (persons, corporate bodies, meetings, titles ...)
- Lake, F. (author)
- Blazquez, M. M. (author)
- Renner, P. (author)
- Crisma, M. (author)
- Gade, L. H. (author)
- Licini, G. (author)
- Moberg, ChristinaKTH,Organisk kemi(Swepub:kth)u1dmzdbd (author)
- KTHOrganisk kemi (creator_code:org_t)
Related titles
- In:European Journal of Inorganic Chemistry: Wiley:5, s. 1032-10401434-19481099-19481099-0682
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