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Alkali-metal ion co...
Alkali-metal ion coordination in uranyl(VI) poly-peroxide complexes in solution. Part 1 : the Li+, Na+ and K+ - peroxide-hydroxide systems
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Zanonato, Pier Luigi (författare)
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Di Bernardo, Plinio (författare)
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Vallet, Valerie (författare)
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- Szabo, Zoltan (författare)
- KTH,Organisk kemi
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- Grenthe, Ingmar (författare)
- KTH,Kemi
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(creator_code:org_t)
- 2015
- 2015
- Engelska.
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Ingår i: Dalton Transactions. - : Royal Society of Chemistry (RSC). - 1477-9226 .- 1477-9234. ; 44:4, s. 1549-1556
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- The alkali metal ions Li+, Na+ and K+ have a profound influence on the stoichiometry of the complexes formed in uranyl(VI)-peroxide-hydroxide systems, presumably as a result of a templating effect, resulting in the formation of two complexes, M[(UO2)(O-2)(OH)](2)(-) where the uranyl units are linked by one peroxide bridge, mu-eta(2)-eta(2), with the second peroxide coordinated "end-on", eta(2), to one of the uranyl groups, and M[(UO2)(O-2)(OH)](4)(3-), with a four-membered ring of uranyl ions linked by mu-eta(2)-eta(2) peroxide bridges. The stoichiometry and equilibrium constants for the reactions: M+ + 2UO(2)(2+) + 2HO(2)(-) + 2H(2)O -> M[(UO2)(O-2)(OH)] 2 - + 4H(+) (1) and M+ + 4UO(2)(2+) + 4HO(2)(-) + 4H(2)O -> M[(UO2)(O-2)(OH)](4)(3-) + 8H(+) (2) have been measured at 25 degrees C in 0.10 M (tetramethyl ammonium/M+)NO3 ionic media using reaction calorimetry. Both reactions are strongly enthalpy driven with large negative entropies of reaction; the observation that Delta H(2) approximate to 2 Delta H(1) suggests that the enthalpy of reaction is approximately the same when peroxide is added in bridging and "end-on" positions. The thermodynamic driving force in the reactions is the formation of strong peroxide bridges and the role of M+ cations is to provide a pathway with a low activation barrier between the reactants and in this way "guide" them to form peroxide bridged complexes; they play a similar role as in the synthesis of crown-ethers. Quantum chemical (QC) methods were used to determine the structure of the complexes, and to demonstrate how the size of the M+-ions affects their coordination geometry. There are several isomers of Na[(UO2)(O-2)(OH)](2)(-) and QC energy calculations show that the ones with a peroxide bridge are substantially more stable than the ones with hydroxide bridges. There are isomers with different coordination sites for Na+ and the one with coordination to the peroxide bridge and two uranyl oxygen atoms is the most stable one.
Ämnesord
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Nyckelord
- Water Exchange-Reaction
- Basis-Sets
- Chemical-Equilibria
- Free-Energy
- Solvation
- Pseudopotentials
- Hydrogen
- Atoms
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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