Catalysed low temperature H-2 release from nitrogen heterocycles

• In an experimental and computational study, nitrogen- and oxygen-containing heterocycles were compared with carbocycles as liquid substrates for hydrogen release with heterogeneous catalysts. Heteroatom substitution, particularly by nitrogen, favours low temperature H-2 release; indoline was fully dehydrogenated in less than 30 min with Pd/C at 110 degrees C.

Nyckelord

molecular-orbital methods

noble-metal catalysts

carbon nanotubes

dehydrogenation

hydrogen

storage

complexes

evolution

energies

alcohols

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ref (ämneskategori)

art (ämneskategori)