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Reaction mechanism ...
Reaction mechanism of direct episulfidation of caryophyllene and humulene
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Ashitani, Tatsuya (författare)
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- Borg-Karlson, Anna-Karin (författare)
- KTH,Organisk kemi
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Fujita, Koki (författare)
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Nagahama, Shizuo (författare)
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(creator_code:org_t)
- Informa UK Limited, 2008
- 2008
- Engelska.
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Ingår i: Natural Product Research. - : Informa UK Limited. - 1478-6419 .- 1478-6427. ; 22:6, s. 495-498
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Direct episulfidations of caryophyllene or humulene with elemental sulfur were examined by means of gas chromatography. Caryophyllene-6,7-episulfide was formed at an early stage in a reaction of the caryophyllene and elemental sulfur at 120C. Caryophyllene-3,6-sulfide and polymer compounds were formed after the episulfidation. Formations of the these compounds were related to the disappearance of the caryophyllene-6,7-episulfide. Isomerization from the caryophyllene to isocaryophyllene was also observed during the reaction. In the reaction of humulene with elemental sulfur, humulene-6,7-episulfide was initially produced and then converted to humulene-9,10-episulfide. It was assumed that the polymer compound in the reaction of humulene with sulfur was related to the disappearance of the both humulene episulfides.
Publikations- och innehållstyp
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- art (ämneskategori)
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