WFRF:(Li Bing Hui)
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- Zhang, Xiang (author)
Intramolecularly two-centered cooperation catalysis for the synthesis of cyclic carbonates from CO2 and epoxides
- Article/chapterEnglish2008
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- Elsevier BV,2008
- printrdacarrier
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- LIBRIS-ID:oai:DiVA.org:kth-17945
- https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-17945URI
- https://doi.org/10.1016/j.tetlet.2008.09.035DOI
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- Language:English
- Summary in:English
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Notes
- QC 20100525
- A catalyst systern containing an electrophilic center and a sterically hindered nUcleophilic center in one molecule was applied to the cycloaddition reaction of CO2 and epoxides. This intramolecularly two-centered cooperation catalyst showed activity even at a high [epoxide]/[catalyst] ratio up to 50000 under mild conditions such as solvent-free, ambient temperature, and low CO2 pressure. The reaction of CO2 with (S)-propylene oxide at 80 degrees C in the presence of the bifunctional catalyst gives (S)-propylene carbonate in 96% ee with retention of stereochemistry.
Added entries (persons, corporate bodies, meetings, titles ...)
- Jia, Yin-Bao (author)
- Lu, Xiao-Bing (author)
- Li, Bo (author)
- Wang, Hui (author)
- Sun, LichengKTH,Organisk kemi(Swepub:kth)u1umfd9h (author)
- KTHOrganisk kemi (creator_code:org_t)
Related titles
- In:Tetrahedron Letters: Elsevier BV49:46, s. 6589-65920040-40391359-8562
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- Royal Institute of Technology
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